• Title/Summary/Keyword: surface transition

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Surface Segregation and Order of FeCo Alloy (FeCo 합금의 표면 편석과 질서도)

  • Han, Wone-Keun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.3
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    • pp.240-244
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    • 2010
  • The surface segregation and surface order near the order-disorder phase transition of FeCo alloy was studied through Monte Carlo simulation of an Ising type model Hamiltonian. The results showed that the proper choice of Hamiltonian parameters could reproduce the recent observation of surface order above the transition temperature and that the field term played dominant role.

Effect of wet/dry transition on the atmospheric corrosion of Zn (아연의 대기부식에 미치는 주기적 침적/건조 효과)

  • Kim, Ki-Tae
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1998.05a
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    • pp.3-3
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    • 1998
  • The atmospheric corrosIOn properties of Zinc (Zn) under wet/dry transition of $H_20$ film were investigated in this study. The atmospheric corrosion of metal is usually occurred as a result of repetitious thickness transition (so called wet/dry transition) of liquid phase which is covering the metal surface. Corrosion potential and the polarization behaviour of Zn during liquid film thickness transition were measured by Kelvin probe method which IS using vibrating reference electrode without touching the liquid film. The oxidized states of Zn as a result of successive wet/dry transition were also investigated by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results show that the corrosion potential and the corrosIOn rate of Zn both are increasing during drying. However, the corrOSIon rate is decreasing again when the Zn surface is completely dried while the corrosion potential still remains high. This behaviour can be explained by the polarization behaviour change of Zn according to the $H_20$ film thickness change. The completely dried surface is consisted mostly with Zn and ZnO phases. After a number of cycles of wet/dry transition, however, the oxidized Zn phase of ${\varepsilon}-Zn(OH)_2$, which has rather voluminous and defected structure, were found.

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Synthesis and Surface Characterization of Transition Metal Doped Mesoporous Silica Catalysts for Decomposition of N2O (N2O 분해를 위한 전이금속이 도핑된 메조포러스 실리카 촉매의 합성과 표면 특성에 관한 연구)

  • Lee, Kamp-Du;Noh, Min-Soo;Park, Sang-Won
    • Journal of Environmental Science International
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    • v.21 no.7
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    • pp.787-795
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    • 2012
  • The purpose of this study is to synthesize transition metal doped mesoporous silica catalyst and to characterize its surface in an attempt to decomposition of $N_2O$. Transition metal used to surface modification were Ru, Pd, Cu and Fe concentration was adjusted to 0.05 M. The prepared mesoporous silica catalysts were characterized by X-ray diffraction, BET surface area, BJH pore size, Scanning Electron Microscopy and X-ray fluorescence. The results of XRD for mesoporous silica catalysts showed typical the hexagonal pore system. BET results showed the mesoporous silica catalysts to have a surface area of 537~973 $m^2/g$ and pore size of 2~4 nm. The well-dispersed particle of mesoporous silica catalysts were observed by SEM, the presence and quantity of transition metal loading to mesoporous surface were detected by XRF. The $N_2O$ decomposition efficiency on mesoporous silica catalysts were as follow: Ru>Pd>Cu>Fe. The results suggest that transition metal doped mesoporous silica is effective catalyst for decomposition of $N_2O$.

Surface Wetting Effect on Spread-Splash Transition Criterion (표면 젖음성이 스프레드-스플래시 영역 간 천이 조건에 미치는 효과)

  • Ryu, S.U.;Lee, S.Y.
    • Journal of ILASS-Korea
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    • v.12 no.4
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    • pp.198-203
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    • 2007
  • In the present work, surface wetting effect on spread-splash regime and transition criterion of the water and ethanol droplets impacting an unheated dry wall has been experimentally investigated. The droplet was directed on a polished STS plate and a glass slide, and the impinging behavior was visualized and recorded using a CCD camera. Droplet diameter and velocity approaching the wall were measured as well. The critical Sommerfeld number representing the spread-splash boundary for the ethanol droplet impinging on the substrates turned out to be smaller compared to that for the water droplet impinging on the substrates with the surface roughness condition remained unchanged. The shift of the transition boundary is considered to be due to the effect of the surface wettability represented by static contact angle and surface tension of droplet.

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On the strong attractive force dependence of the surface phase transition : Qualitative consideration from the occupation statistics (표면상변이의 강인력 의존성 : 점유통계를 이용한 정성적 고찰)

  • 김철호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.4
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    • pp.573-577
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    • 1997
  • Surface phase transition is known to be observed at the system that there exists a strong attractive potential between particles adsorbed. This study presents a dependence of the surface phase transition on strong attractive force using a simple occupation statistical method. It was found that the system exhibits a phase transition from the vacuum phase into the population phase and the critical pressure also increases with the temperature. This fact indicates that these results explain well qualitatively the surface phase transition.

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A Study on the Behavior of Liquid Free Surface in a Shaking Vessel (진동교반조에서의 액자유표면의 거동에 관한 연구)

  • Lee, Young-Sei;Kim, Moon-Gab
    • Journal of the Korean Society of Industry Convergence
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    • v.3 no.3
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    • pp.209-217
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    • 2000
  • An attempt has been made to examine the highest liquid surface by means of measuring the movement of liquid free surface wave in the agitated vessel wall. Also, Relationship has been investigated between transition frequency, $N_z$ for behavior of liquid free surface and transition frequency for behavior of mass transfer coefficient in the agitated vessel wall. A surface wave is occured within agitated vessel, the highest height of wetted vessel wall, $h_w$ is coincided with the highest liquid surface, h. However the lowest height of wetted vessel, $h^*{_w}$ is not descended to lowest liquid free surface, $h^*$. The proposed model has been tested sucessfully for the behavior of liquid free surface.

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Interaction Between Surface Plasmon Resonance and Inter-band Transition in Gold Thin Film (금 박막에서 표면 플라즈몬 공명과 국소적 밴드 간 천이의 상호작용)

  • Kang, Daekyung;Kumar, Marredi Bharath;Adeshina, Mohammad Awwal;Choi, Bongjun;Park, Jonghoo
    • Journal of Sensor Science and Technology
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    • v.28 no.4
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    • pp.262-265
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    • 2019
  • The effect of inter-band transition on surface plasmon resonance in gold thin film was investigated. We induced localized inter-band transition in the film by using incident light on its surface from a green laser (532 nm) source, and the surface plasmon resonance for inter-band transition was investigated at different wavelengths. It was determined that the reflectivity of blue light (450 nm) was significantly reduced in the region where the green laser was incident. We demonstrated that this decrease is mainly due to the coupling between the blue light and the surface plasmon resonance of excited electrons in higher energy states, based on experimental results for the incident and polarization angle-dependent reflectivity of the blue light.

Consideration of NDVI and Surface Temperature Calculation from Satellite Imagery in Urban Areas: A Case Study for Gumi, Korea

  • Bhang, Kon Joon;Lee, Jin-Duk
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.35 no.1
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    • pp.23-30
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    • 2017
  • NDVI (Normalized Difference Vegetation Index) plays an important role in surface land cover classification and LST (Land Surface Temperature Extraction). Its characteristics do not full carry the information of the surface cover typically in urban areas even though it is widely used in analyses in urban areas as well as in vegetation. However, abnormal NDVI values are frequently found in urban areas. We, therefore, examined NDVI values on whether NDVI is appropriate for LST and whether there are considerations in NDVI analysis typically in urban areas because NDVI is strongly related to the surface emissivity calculation. For the study, we observed the influence of the surface settings (i.e., geometric shape and color) on NDVI values in urban area and transition features between three land cover types, vegetation, urban materials, and water. Interestingly, there were many abnormal NDVI values systematically derived by the surface settings and they might influence on NDVI and eventually LST. Also, there were distinguishable transitions based on the mixture of three surface materials. A transition scenario was described that there are three transition types of mixture (urban material-vegetation, urban material-water, and vegetation-water) based on the relationship of NDVI and LST even though they are widely distributed.

The Rheological Behaviors of Solid-Liquid Transfer Emulsion (고상-액상 전이형 에멀젼의 레올로지 거동)

  • Park, Byeong-Gyun;Han, Jong-Sub;Lee, Sang-Min;Lee, Cheon-Koo;Yoon, Moung-Seok
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.31 no.2 s.51
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    • pp.135-140
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    • 2005
  • A solid state emulsion haying high velocity gradient shows two important transition ranges in the plot of storage modulus(G') as a function of shear strain, when the state is changed from solid to liquid. However, a solid state emulsion having low velocity gradient shows only one apparent transition range when the change from solid to liquid state takes place. The result implies the importance of the surface properties in the solid state emulsion. The addition of water phase in the solid state emulsion reduces the modulus in the modulus in the surface transition range by increasing interfacial friction and weakening the matrix. The addition of pigments increases the modulus in the modulus in the surface transition range by reinforcing the matrix, when there is no wafer phase in the solid state emulsion. When the solid state emulsion has water phase, however, the addition of pigments decreases the modulus in the modulus in the surface transition range.

Nanoscopic Understanding of Phase Transition of Epitaxial VO2 Thin Films (에피택셜 VO2 박막의 상전이에 대한 미시적 이해)

  • Kim, Dong-Wook;Sohn, Ahrum
    • Journal of the Korean institute of surface engineering
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    • v.50 no.3
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    • pp.141-146
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    • 2017
  • We investigated configuration of metallic and insulating domains in $VO_2$ thin films, while spanning metal-insulator phase transition. Kelvin probe force microscopy, of which spatial resolution is less than 100 nm, enables us to measure local work function (WF) at the sample surface. The WF of $VO_2$ thin films decreased (increased) as increasing (decreasing) the sample temperature, during the phase transition. The higher and lower WF regions corresponded to the insulating and metallic domains, respectively. The metallic fraction, estimated from the WF maps, well explained the temperature-dependent resistivity based on the percolation model. The WF mapping also showed us how the structural defects affected the phase transition behaviors.