• Title/Summary/Keyword: surface topology

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Preparation and Properties of Bio-inspired Waterborne Polyurethanes Containing Different Amount of Paraffin Wax

  • Kim, Hye-Lin;Kim, Ae-Li;Lee, Young-Hee;Kim, Sung Yeol;Park, Cha-Cheol;Rahman, Mohammad Mizanur;Kim, Han-Do
    • Textile Coloration and Finishing
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    • v.30 no.1
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    • pp.9-19
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    • 2018
  • To prepare bio-inspired antifouling coating materials having similar structure with lotus, self-crosslinkable waterborne polyurethanes emulsions containing paraffin wax (CWPU/P0, 0.25, 0.5, 1.0, 1.5, 2.0, the number indicated the wt% of wax) were prepared by an emulsifier-free/solvent free prepolymer mixing process. The as-polymerized CWPU/P emulsions containing 0 - 1.00wt% of paraffin wax were found to be stable after 4 months, however, CWPU/P emulsions containing 1.50 and 2.00wt% of paraffin wax were unstable within 1 month storage. Considering the stability of emulsions, the optimum paraffin wax content was found to be about 1wt% to obtain stable antifouling coating emulsion material. The surface topology of CWPU/P film samples was characterized by atomic force microscopy (AFM). This study examined the effect of paraffin wax content on the surface roughness, water contact angle/surface energy, water swelling, light transmittance and tensile properties of CWPU/P film samples.

The Effect of Lattice Topology on Benzyl Alcohol Adsorption on Kaolinite Surfaces: Quantum Chemical Calculations of Mulliken Charges and Magnetic Shielding Tensor (캐올리나이트 규산염 층과 벤질알코올의 반응에 대한 양자화학계산에서 결정학적 위상이 멀리켄 전하와 자기 차폐 텐서에 미치는 영향)

  • Lee, Bum-Han;Lee, Sung-Keun
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.4
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    • pp.313-325
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    • 2007
  • In order to have better insights into adsorption of organic molecules on kaolinite surfaces, we performed quantum chemical calculations of interaction between three different model clusters of kaolinite siloxane surfaces and benzyl alcohol, with emphasis on the effect of size and lattice topology of the cluster on the variation of electron density and magnetic shielding tensor. Model cluster 1 is an ideal silicate tetrahedral surface that consists of 7 hexagonal rings, and model cluster 2 is composed of 7 ditrigonal siloxane rings with crystallographically distinct basal oxygen atoms in the cluster, and finally model cluster 3 has both tetrahedral and octahedral layers. The Mulliken charge analysis shows that siloxane surface of model cluster 3 undergoes the largest electron density transfer after the benzyl alcohol adsorption and that of model cluster 1 is apparently larger than that of model cluster 2. The difference of Mulliken charges of basal oxygen atoms before and after the adsorption is positively correlated with hydrogen bond strength. NMR chemical shielding tensor calculation of clusters without benryl alcohol shows that three different basal oxygen atoms (O3, O4, and O5) in model cluster 2 have the isotropic magnetic shielding tensor as $228.2{\pm}3.9,\;228.9{\pm}3.4,\;and\;222.3{\pm}3.0ppm$, respectively. After the adsorption, the difference of isotropic chemical shift varies from 1 to 5.5 ppm fer model cluster 1 and 2 while model cluster 2 apparently shows larger changes in isotropic chemical shift. The chemical shift of oxygen atoms is also positively correlated with electron density transfer. The current results show that the adsorption of benzyl alcohol on the kaolinite siloxane surfaces can largely be dominated by a weak hydrogen bonding and electrostatic force (charge-charge interaction) and demonstrate the importance of the cluster site and the lattice topology of surfaces on the adsorption behavior of the organic molecules on clay surfaces.

Structural Analysis of Exosomes Using Different Types of Electron Microscopy

  • Choi, Hyosun;Mun, Ji Young
    • Applied Microscopy
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    • v.47 no.3
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    • pp.171-175
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    • 2017
  • Negative staining has been traditionally used for exosome imaging; however, the technique is limited to surface topology only and can cause staining artifacts. Therefore, to analyze the internal structure of exosomes, we employed a method of block preparation, thin sectioning, and electron tomography. In addition, an automatic serial sectioning technique with 15-nm thickness through focused ion beam was employed to observe the three-dimensional structure of exosomes of various sizes. Cryo-transmission electron microscopy revealed the near-to-native structure of exosomes.

Robust Hierarchical Data Fusion Scheme for Large-Scale Sensor Network

  • Song, Il Young
    • Journal of Sensor Science and Technology
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    • v.26 no.1
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    • pp.1-6
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    • 2017
  • The advanced driver assistant system (ADAS) requires the collection of a large amount of information including road conditions, environment, vehicle status, condition of the driver, and other useful data. In this regard, large-scale sensor networks can be an appropriate solution since they have been designed for this purpose. Recent advances in sensor network technology have enabled the management and monitoring of large-scale tasks such as the monitoring of road surface temperature on a highway. In this paper, we consider the estimation and fusion problems of the large-scale sensor networks used in the ADAS. Hierarchical fusion architecture is proposed for an arbitrary topology of the large-scale sensor network. A robust cluster estimator is proposed to achieve robustness of the network against outliers or failure of sensors. Lastly, a robust hierarchical data fusion scheme is proposed for the communication channel between the clusters and fusion center, considering the non-Gaussian channel noise, which is typical in communication systems.

Development of Al plasma assisted chemical vapor deposition using DMEAA (DMEAA를 이용한 알루미늄 PACVD법의 개발)

  • 김동찬;김병윤;이병일;김동환;주승기
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.33A no.10
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    • pp.98-106
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    • 1996
  • A thin film of aluminum for ultra large scale integrated circuits metalization has been deposited on TiN and SiO$_{2}$ substrates by plasma assisted chemical vapor deposition using DMEAA (dimenthylethylamine alane) as a precursor. The effects of plasma on surface topology and growth characteristics were investigated. Thermal CVD Al could not be got continuous films on insulating subsrate such as SiO$_{2}$. However, it was found that Al films could be deposited on SiO$_{2}$ substate without any pretreatments by the hydrogen plasma for pyrolysis of DMEAA. Compared to the thermal CVD, PACVD films showed much better reflectance and resistance on TiN and SiO$_{2}$ substrate. We obtained mirror-like PACVD Al film of 90% reflectance and resistance on TiN and SiO$_{2}$ substrates. We obtained mirror-like PACVD Al film of 90% reflectance on TiN substrate. Excellent conformal step coverage was obtained on submicron contact holes ;by the PACVD blanket deposition.

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DIGITAL COVERING THEORY AND ITS APPLICATIONS

  • Kim, In-Soo;Han, Sang-Eon
    • Honam Mathematical Journal
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    • v.30 no.4
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    • pp.589-602
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    • 2008
  • As a survey-type article, the paper reviews various digital topological utilities from digital covering theory. Digital covering theory has strongly contributed to the calculation of the digital k-fundamental group of both a digital space(a set with k-adjacency or digital k-graph) and a digital product. Furthermore, it has been used in classifying digital spaces, establishing almost Van Kampen theory which is the digital version of van Kampen theorem in algebrate topology, developing the generalized universal covering property, and so forth. Finally, we remark on the digital k-surface structure of a Cartesian product of two simple closed $k_i$-curves in ${\mathbf{Z}}^n$, $i{\in}{1,2}$.

A THREE-DIMENSIONAL UNSTRUCTURED FINITE VOLUME METHOD FOR ANALYSIS OF DROPLET IMPINGEMENT IN ICING (비정렬 격자 기반의 결빙 액적 해석을 위한 유한체적 기법)

  • Jung, K.Y.;Jung, S.K.;Myong, R.S.
    • Journal of computational fluids engineering
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    • v.18 no.2
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    • pp.41-48
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    • 2013
  • Ice accretion on the solid surface is an importance factor in assessing the performance of aircraft and wind turbine blade. Changes in the external shape due to ice accretion can greatly deteriorate the aerodynamic performance. In this study, a three-dimensional upwind-type second-order positivity-preserving finite volume CFD scheme based on the unstructured mesh topology is developed to simulate two-phase flow in atmospheric icing condition. The code is then validated by comparing with NASA IRT experimental data on the sphere. The present results of the collection efficiency are found to be in close agreement with experimental data and show improvement near the stagnation region.

Triangle Based Geometric modeling for rapid Prototyping CAM system (고속시작 시스템을 위한 삼각형 기반 형상모델링)

  • 채희창
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1996.04a
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    • pp.587-591
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    • 1996
  • Usually triangular patches are used to transfer geometric shape in Rpaid Prototyping CAM system. STL, a list of triangles, is de facto in RP industry. Because STL has no topology data, it can cause errornous results. So, STL should be verified before using. After adding support structures to anchor the part to the platform and to prevent sagging or distortion, slicing and layer by layer manufacturing process are done. But triangular patch is surface model and cannot provide dufficient information on geometry in the above processes. So, geometric modeling is necessary in verifying STL, adding support structures, and slicing. It is natural that triangle based modeling is the best when traingular patches are used as input. Considering support structures, solid and faces coexist in RP process. Therefore non-manifold modeler is required. In this study, triangle based non-manifold geometric modeling is proposed for RP system consitent with STL input.

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Automatic Generation of 3-D Finite Element Meshes: Part(II) -Mesh Generation from Tetrahedron-based Octree- (삼차원 유한요소의 자동생성 (2) -사면체 옥트리로부터의 유한요소 생성-)

  • 정융호;이건우
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.3
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    • pp.647-660
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    • 1995
  • Given the tetrahedron-based octree approximation of a solid as described in part(I) of this thesis, in this part(II) a systematic procedure of 'boundary moving' is developed for the fully automatic generation of 3D finite element meshes. The algorithm moves some vertices of the octants near the boundary onto the exact surface of a solid without transforming the topology of octree leaf elements. As a result, the inner octree leaf elements can be used as exact tetrahedral finite element meshes. In addition, as a quality measure of a tetrahedral element, 'shape value' is propopsed and used for the generation of better finite elements during the boundary moving process.

Passage Feature Recognition Algorithm for Automatic Parting Surface Generation in Plastic Injection Mold (플라스틱 사출 금형의 분할면 자동 생성을 위한 관통 특징 형상 추출 알고리즘의 개발)

  • 정강훈;이건우
    • Korean Journal of Computational Design and Engineering
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    • v.5 no.2
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    • pp.196-205
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    • 2000
  • This paper proposes a topology-based algorithm for recognizing the passage features using a concept of multi-face hole loop. The Multi-face hole loop is a concetpual hole loop that is formed over several connected faces. A passage feature is recognized in the proposed approach by two multi-face hole loops that constitute its enterance and exit. The algorithm proposed in this paper checks the connectivity of the two multi-face hole loops to recognize passage features. The total number of passage features in a part is calculated from Euler equation and is compared with the number of found passage features to decide when to terminate. To find all multi-face hole loops in a part, this paper proposes an algorithm for finding all combinations of connected faces. The edge convexity is used to judge the validity of multi-face hole loops. By using the algorithm proposed in this paper, the passage features could be recognized effectively. The approach proposed in this paper is illustrated with several example parts.

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