• Macromolecular Research
• /
• v.12 no.1
• /
• pp.134-140
• /
• 2004

Semi-crystalline poly(ethylene terephthalate) (PET) film surfaces were modified with argon and oxygen plasmas by radio-frequency (RF) glow discharge at 240 mTorr/40 W; the changes in topography and surface structure were investigated by atomic force microscopy (AFM) in conjunction with specular reflectance of infrared microspectroscopy (IMS). Under our operating conditions, analysis of the AFM images revealed that longer plasma treatment results in significant ablation on the film surface with increasing roughness, regardless of the kind of plasma used. The basic topographies, however, were different depending upon the kind of gas used. The specular reflectance analysis showed that the ablative mechanisms of the argon and oxygen plasma treatments are entirely different with one another. For the Ar-plasma-treated PET surface, no observable difference in the chemical structure was observed before and after plasma treatment. On the other hand, the oxygen-plasma-treated PET surface displays a significant decrease in the number of aliphatic C-H groups. We conclude that a constant removal of material from the PET surface occurs when using the Ar-plasma, whereas preferential etching of aliphatic C-H groups, with respect to, e.g. , carbonyl and ether groups, occurs upon oxygen plasma.

• Korean Journal of Chemical Engineering
• /
• v.35 no.12
• /
• pp.2365-2378
• /
• 2018

We investigated the correlation between vanadium surface density and VOx structure species in the selective catalytic reduction of NOx by $NH_3$. The properties of the $VOx/TiO_2$ catalysts were investigated using physicochemical measurements, including BET, XRD, Raman spectroscopy, FE-TEM, UV-visible DRS, $NH_3-TPD$, $H_2-TPR$, $O_2-On/Off$. Catalysts were prepared using the wet impregnation method by supporting 1.0-3.0 wt% vanadium on $TiO_2$ thermally treated at various calcination temperatures. Through the above analysis, we found that VOx surface density was $3.4VOx/nm^2$, and the optimal V loading amounts were 2.0-2.5 wt% and the specific surface area was $65-80m^2/g$. In addition, it was confirmed that the optimal VOx surface density and formation of vanadium structure species correlated with the reaction activity depending on the V loading amounts and the specific surface area size.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.8
• /
• pp.2247-2254
• /
• 2010

The surface structures of copper phthalocyanine (CuPc) thin films deposited on sulphur-passivated and plane perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA)-covered InAs(100) surfaces have been studied by low energy electron diffraction (LEED) and van der Waals (vdW) intermolecular interaction energy calculations. The annealing to $300^{\circ}C$ and $450^{\circ}C$ of $(NH_4)_2S_x$-treated InAs(100) substrates produces a ($1{\times}1$) and ($2{\times}1$) S-passivated surface respectively. The CuPc deposition onto the PTCDA-covered InAs(100) surface leads to a ring-like diffraction pattern, indicating that the 2D ordered overlayer exists and the structure is dominantly determined by the intermolecular interactions rather than substrate-molecule interactions. However, no ordered LEED patterns were observed for the CuPc on S-passivated InAs(100) surface. The intermolecular interaction energy calculations have been carried out to rationalise this structural difference. In the case of CuPc unit cells on PTCDA layer, the planar layered CuPc structure is more stable than the $\alpha$-herringbone structure, consistent with the experimental LEED results. For CuPc unit cells on a S-($1{\times}1$) layer, however, the $\alpha$-herringbone structure is more stable than the planar layered structure, consistent with the absence of diffraction pattern. The results show that the lattice structure during the initial stages of thin film growth is influenced strongly by the intermolecular interactions at the interface.

• Design & Manufacturing
• /
• v.2 no.1
• /
• pp.15-19
• /
• 2008

While recent industrial structure is various, it is small quantity batch production structure, and products requiring of various functions are increasing. In order to improve the quality of the sheared surface in cutting of inner structure bonded sheet metal the cut-off operation is mainly investigated, which is the typical shearing process in sheet metal forming technology. The sandwich sheet metals considered have inner structure which is constructed in the form of crimped expanded metal and woven metal. The inner structure is bonded between solid sheet by resistance welding or adhesive bonding. The shearing process is visualized by the computer vision system installed in front of the cut-off die and the sheared surface is measured and quantitatively compared with the help of the optical microscope after cut-off operation. From test results we found that the influence of sheared position can be observed and explained clearly and this result can be utilized to get the better sheared surface.

• Applied Microscopy
• /
• v.48 no.1
• /
• pp.27-32
• /
• 2018

Barium titanate ($BaTiO_3$) nanoparticle is one of the most promising materials for future multi-layer ceramic capacitor and ferroelectric random access memory. It is well known that electrical property of nanoparticles depends on the atomistic structure. Although surface may possibly have an impact on the atomistic structure, reconstructed structure at the surface has not been widely investigated. In the present study, Ba-ion position near surface in a $BaTiO_3$ nanoparticle has been quantitatively characterized by scanning transmission electron microscopy. It was found that some Ba ions at the surface were greatly displaced in non-uniform directions.

• 제어로봇시스템학회:학술대회논문집
• /
• 1996.10b
• /
• pp.253-256
• /
• 1996

In this paper, A new time-varying sliding surface design using eigenvalue locus is proposed to achieve fast and robust in a class of high-order uncertain dynamic system. A moving sliding surface(MSS) was proposed earlier for the second-order variable structure control systems(VSCS). This methodology led to fast and robust control responses of the second-order VSCS. However, the moving algorithm of the MSS was too complicated to be employed the high-order VSCS. To resolve this problem, we propose a new moving algorithm that switching surface moves such that the eigenvalues of equivalent system in the sliding mode have a predetermined locus. Using the proposed surface fast and robust behaviors are accomplished. The problem of chattering can be eliminated by using a boundary layer of switching surface. The efficiency of proposed algorithm is illustrated by an application to four-order workbench.

• The KIPS Transactions:PartB
• /
• v.8B no.5
• /
• pp.573-578
• /
• 2001

This research proposes a generalized local feature structure named "LSG(Local Surface Group) for model-based 3D object recognition". An LSG consists of a surface and its immediately adjacent surface that are simultaneously visible for a given viewpoint. That is, LSG is not a simple feature but a viewpoint-dependent feature structure that contains several attributes such as surface type. color, area, radius, and simultaneously adjacent surface. In addition, we have developed a new method based on Bayesian theory that computes a measure of how distinct an LSG is compared to other LSGs for the purpose of object recognition. We have experimented the proposed methods on an object databaed composed of twenty 3d object. The experimental results show that LSG and the Bayesian computing method can be successfully employed to achieve rapid 3D object recognition.

• Journal of Sensor Science and Technology
• /
• v.25 no.3
• /
• pp.213-217
• /
• 2016

The superhydrophobic and superoleophobic meshes surfaces have been used in various applications such as self-cleaning, anti-icing, gas exchange, oil-water separation, sound-wave penetrable anti-wetting structures, etc. In particular, there are many studies for oil-water separation with environmental issues. Because of high pressure and dynamic environment, oil-water separation filters must have stable surface properties as super-hydrophobicity and superoleophobicity. The oleophobicity of surface depends on the surface chemistry and roughness of the surface. The roughness of oleophobic surface enhances its static contact angle and stability. The multi-scale hierarchical structure provides a stable superhydrophobic state by maintaining a Cassie state. In this research, we fabricated a superoleophobic mesh with a multi-scale hierarchical structure to increase the pressure resistance and adjusted a size of the mesh hole.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 2014.10a
• /
• pp.236-239
• /
• 2014

Most naval underwater weapon system can be simplified to a circular cylindrical structure which has vibrating machineries inside. In order to predict efficiently the total acoustic radiation power of cylindrical structure, surface velocity is measured and radiation efficiency of surface element is calculated. Then, they are substituted to the surface pressure in the simplified Helmholtz integral equation which assumes acoustic far-field and plane-wave approximation at the surface. Surface velocity and total acoustic radiation power for a submerged cylinder are measured in water-tank. In this example, it is found that total acoustic power output obtained from the prediction is in good agreement with that of measurement in mid-high frequency range.

• Journal of Magnetics
• /
• v.18 no.4
• /
• pp.375-379
• /
• 2013

The electronic and the magnetic properties of (001) surface of $KCaN_2$ half-metallic compound with full-Heusler structure are studied with the use of a full-potential linearized augmented plane wave method. Two possible terminations of the surface are considered and only the one with N atoms in the topmost layer is found to retain the half-metallic properties of the bulk. The magnetic properties of N-terminated surface are enhanced compared with the properties of the bulk. The calculated magnetic moments on the N atoms in the $KCaN_2$ are 1.26 ${\mu}_B$ in the bulk and 1.90 ${\mu}_B$ at the surface. The subsurface metal atoms are also slightly polarized. In the surface terminated with metal atoms, not only the half-metallicity is destroyed, but also the magnetic properties of the system are weakened.