• Title/Summary/Keyword: surface state

Search Result 3,696, Processing Time 0.035 seconds

Nitrogen adsorption on the stepped planes of tungsten: II. W(210) and W(310) plane (계단형 텅스텐 결정면의 질소 흡착에 관한 연구: II. W(210) 및 W(310)면)

  • 최대선;한종훈;백선목;박노길;김용욱;황정남
    • Journal of the Korean Vacuum Society
    • /
    • v.5 no.4
    • /
    • pp.301-308
    • /
    • 1996
  • The heat of desorption and the work function change induced by nitrogen adsorption on the slepped tungstein surface plants, W(210) and W(310), are measured using the Field Electron Emission Microscope(FEM). The adsoption sites are predicted from the Thermal Desortion Spectra(TDS). The wirk function change of both W(210) and W(310) planes increase as increasing the nitrogen dose and saturates at the nitrogen dose about 5 Langmuir to 0.29 eV and 0.20 eV respectively. We find three adsorption site on each plane for the low dose range. The TDS result shows that the intensity of $\alpha_1$ state on W(310) is much stronger than that of $\alpha_1$ state on W(210), and the direction of nitrogen dipole moment adsorbed on the sites correspond to $\alpha_1$ and $\beta_2$ state on W(210) and W(310) planes are in the opposite direction to that of the equivalent states on W(100) plane. From this observation we can predict the relative atomic position in the z-direction (perpendicular direction to the surface) of nitrogen molecules/atoms adsorbed on these sites.

  • PDF

Water film covering characteristic on horizontal fuel rod under impinging cooling condition

  • Penghui Zhang;Bowei Wang;Ronghua Chen;G.H. Su;Wenxi Tian;Suizheng Qiu
    • Nuclear Engineering and Technology
    • /
    • v.54 no.11
    • /
    • pp.4329-4337
    • /
    • 2022
  • Jet impinging device is designed for decay heat removal on horizontal fuel rods in a low temperature heating reactor. An experimental system with a fuel rod simulator is established and experiments are performed to evaluate water film covering capacity, within 0.0287-0.0444 kg/ms mass flow rate, 0-164.1 kW/m2 heating flux and 13.8-91.4℃ feeding water temperature. An effective method to obtain the film coverage rate by infrared equipment is proposed. Water film flowing patterns are recoded and the film coverage rates at different circumference angles are measured. It is found the film coverage rate decreases with heating flux during single-phase convection, while increases after onset of nucleate boiling. Besides, film coverage rate is found affected by Marangoni effect and film accelerating effect, and surface wetting is significantly facilitated by bubble behavior. Based on the observed phenomenon and physical mechanism, dry-out depth and initial dry-out rate are proposed to evaluate film covering potential on a heating surface. A model to predict film coverage rate is proposed based on the data. The findings would have reliable guide and important implications for further evaluation and design of decay heat removal system of new reactors, and could be helpful for passive containment cooling research.

Force-induced Unbinding Dynamics in a Multidimensional Free Energy Landscape

  • Hyeona, Chang-Bong
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.3
    • /
    • pp.897-900
    • /
    • 2012
  • We examined theory for force-induced unbinding on a two-dimensional free energy surface where the internal dynamics of biomolecules is coupled with the rupture process under constant tension f. We show that only if the transition state ensemble is narrow and activation barrier is high, the f-dependent rupture rate in the 2D potential surface can faithfully be described using an effective 1D energy profile.

Design of auto-depth control system for submerged body (수증운동체 자동심도제어 시스템 설계연구)

  • 이동익;윤형식;최중락;양승윤
    • 제어로봇시스템학회:학술대회논문집
    • /
    • 1990.10a
    • /
    • pp.481-484
    • /
    • 1990
  • Normal operation when deeply submerged is a relatively easy task, and human operator control can often provide adequate performance. Near surface depthkeeping, on the other hand, is difficult to both man and machine. Because of the inherent limitation of the human operator, manual control may prove inadequate for near surface depthkeeping in some sea state. This paper describe the control algorithm of an automatic depth control system for submerged body that can be used for both near surface and deeply submerged depthkeeping operations. The computer simulations demonstrate the excellent depthkeeping performance of the controller under seaway effects.

  • PDF

The Salt Accumulation Model on the Soil Surface by Evaporation, Transpiration and Rainfall

  • Chang, Nam-Kee;Kim, Ju-Hoon
    • The Korean Journal of Ecology
    • /
    • v.2 no.1
    • /
    • pp.31-37
    • /
    • 1978
  • The salt accumulation on the soil surface can be mathematically described. Although the movement of salts in soil solution is expressed in terms of mathematical model, which has certain limitations in practical application, except the exchangeable and absorbable state salts in soil solution. This model is illustrated by analyticl experiments in which evaporation from the bare soils, transpiration of plants and rainfall are required. Agreement between the model and the measured data was satisfactory, which validating the salt accumulation theory on the soil surface.

  • PDF

Surface pH Of The Northeastern Pacific Ocean

  • Park, Kilho
    • 한국해양학회지
    • /
    • v.1 no.1_2
    • /
    • pp.1-6
    • /
    • 1966
  • A latitudinal, differential pH distribution is observed in the Northeastern Pacific Ocean with a pH range of 8.15 at high latitude (42 N) to 8.29 at low latitude (23 N). These pH values are generally greater than the calculated equilibrium pH with respect to atmospheric carbon dioxide. If we assume that the calculated equilibrium pH values ae valid, then the surface waters are undersaturated with respect to the atmospheric carbon dioxide during April to June 1966. A high surface pH value of about 8.26 was observed immediately south of the SubarcticBoundary zone near 170 W. This value differs from the equilibration pH by as much as 0.1 unit.

  • PDF

A Study on the Novel Sliding Mode Observer (새로운 슬라이딩 모드를 이용한 상태 관측기의 설계에 관한 연구)

  • Park, Seung-Kyu;An, Ho-Kyun;Lee, Jae-Dong
    • Proceedings of the KIEE Conference
    • /
    • 1998.07b
    • /
    • pp.744-746
    • /
    • 1998
  • In this paper, a new sliding mode observer is proposed by introducing a new sliding surface. The new sliding surface is defined based on the augmented error system with virtual error state. The new sliding mode observer have more degree of freedom than the existing VSS observer. It can have dynamics on the sliding surface.

  • PDF

Leather's Environment-friendly Adhesion Surface Treatment of shoe's material by Plasma (플라즈마를 이용한 신발소재의 환경 친화적인 접착 표면 처리(I))

  • Ha, Soon-Hee;Jang, U-Jin;Seul, Soo-Duk
    • Journal of Adhesion and Interface
    • /
    • v.6 no.2
    • /
    • pp.6-12
    • /
    • 2005
  • The plasma generally, ionized gas state, is the 4th material state composed the universe. Generating the plasma artificially has been studied by spending energy and it has a lot of applications in human's life. There are several merits to modify the surface of polymer using plasma. Above all, plasma maintains the property of polymer because of it changes the property of surface only. Also, it doesn't use a organic solvent and it is the environment friendship because of there are no waste under processing. Furthemore, in case of high-pressure plasma, it is possible that automated-processing continuously. In this study, we tried the reforming of surface to rise the adhesive strength between the material of polymer, experimented the rising of adhesive strength through a experiment of peel strength by virtue of processing time and using gas, confirmed the change of polymer's surface through measuring the surface contact angle analyzer and scanning electron microscopy (SEM).

  • PDF

Proposed Guidelines for Selection of Methods for Erosion-corrosion testing in Flowing Liquids

  • Matsumura, Masanobu
    • Corrosion Science and Technology
    • /
    • v.6 no.6
    • /
    • pp.291-296
    • /
    • 2007
  • The corrosion of metals and alloys in flowing liquids can be classified into uniform corrosion and localized corrosion which may be categorized as follows. (1) Localized corrosion of the erosion-corrosion type: the protective oxide layer is assumed to be removed from the metal surface by shear stress or turbulence of the fluid flow. A macro-cell may be defined as a situation in which the bare surface is the macro-anode and the other surface covered with the oxide layer is the macro-cathode. (2) Localized corrosion of the differential flow-velocity corrosion type: at a location of lower fluid velocity, a thin and coarse oxide layer with poor protective qualities may be produced because of an insufficient supply of oxygen. A macro-cell may be defined as a situation in which this surface is the macro-anode and the other surface covered with a dense and stable oxide layer is the macro-cathode. (3) Localized corrosion of the active/passive-cell type: on a metal surface a macro-cell may be defined as a situation in which a part of it is in a passivation state and another in an active dissolution state. This situation may arise from differences in temperature as well as in the supply of the dissolved oxygen. Compared to uniform corrosion, localized corrosion tends to involve a higher wall thinning rate (corrosion rate) due to the macro-cell current as well as to the ratio of the surface area of the macro-anode to that of the macro-cathode, which may be rationalized using potential vs. current density diagrams. The three types of localized corrosion described above can be reproduced in a Jet-in-slit test by changing the flow direction of the test liquid and arranging environmental conditions in an appropriate manner.

Aerosol Deposition and Behavior on Leaves in Cool-temperate Deciduous Forests. Part 1: A Preliminary Study of the Effect of Fog Deposition on Behavior of Particles Deposited on the Leaf Surfaces by Microscopic Observation and Leaf-washing Technique

  • Watanabe, Yoko;Yamaguchi, Takashi;Katata, Genki;Noguchi, Izumi
    • Asian Journal of Atmospheric Environment
    • /
    • v.7 no.1
    • /
    • pp.1-7
    • /
    • 2013
  • To establish the method for investigating the behavior of aerosol particles deposited on the leaf surface against fog water under natural conditions, scanning electron microscopy with energy-dispersive X-ray (SEM-EDX) analysis and wash water analysis by ion chromatography after the washing treatment were performed using leaves of white birch collected from low part of the tree crown and the top of the tree in Sapporo City, Hokkaido, northern Japan. Each of collected leaves was divided into two parts according to the treatment performed: leaf surface (adaxial side) was 1) untreated, and 2) washed with deionized water with a pipette. In untreated samples, many particles of various shapes, including soil particles and organic debris, were deposited on the surface. Particles containing S were found on the surface of samples collected from only low part of the tree crown. After the washing treatment, SEM-EDX analysis revealed that soil particles and particles containing S had been washed off with water, although some particles such as soil particles and organic debris still remained on the leaf surface. The major anion such as $SO{_4}^{2-}$ was detected in wash water of all samples, although the peak of S in X-ray spectra was not detected from samples collected at top of the tree. The combination of SEM-EDX analysis with wash water analysis indicated that $SO{_4}^{2-}$ was deposited on the leaf surface in dissolved state and/or in state of submicron particles. These results suggested that fog water could remove soil particles and particles containing S and $SO{_4}^{2-}$ from the leaf surfaces, but not all particles. There was no difference in sampling position in the tree crown. Our study suggested that combination with SEM-EDX analysis and wash water analysis would be effective for investigation of the behavior of particles on the leaf surface against fog water.