• Title/Summary/Keyword: surface rheological properties

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Electrical and Rheological Properties of Colloidal of Alumina Suspensions

  • Wang, Xu-Hong;Yoshihiro Hirata
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 2000.06a
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    • pp.215-232
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    • 2000
  • The Valence(Z) of positively and negatively charged alumina particles in the dilute suspensions was analyzed with the electrical conductivity of the suspensions. The mobility of negative particles was lower than that of positive particles at a similar Z value because of the stronger effect of chemical bonding over the hydrated particle surfaces. The apparent viscosity of acidic suspensions of 1-40 vol % solid was lower than that of basic suspensions. This result was discussed based on the three important effects of the valence, concentration and nature of hydrated surface of alumina particles. The density of alumina compacts consolidated by filtration through gypsum molds became lower for the basic suspensions than for the acidic suspensions. This result was correlated to the properties of the colloidal alumina suspensions.

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MANUFACTURE AND CHARACTERISTICS OF SNACK-TYPE PRODUCTS CONTAINING MEAT AND STARCH

  • Cho, Soo-Hyun
    • Proceedings of the Korean Society for Food Science of Animal Resources Conference
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    • 1997.06a
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    • pp.19-39
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    • 1997
  • Extrusion conditions were optimized for blends of ground lamb and starch using a single-screw extruder for the purpose of producing expanded snack-type products. A central composite rotatable response surface methodology(RSM) design was used with variation in feed moisture, process temperature, and screw speed. The three variables significantly affected one or more of the measured physical properties of extrudates. The optimum conditions for minimum shear force values were 26.5% feed moisture, $148^{\circ}C$ process temperature, and 134 rpm screw speed. Lean ground beef, chicken, goat, lamb or mutton was blended with corn starch, and extruded at the optimum condition established from RSM experiments. Physical/rheological properties were generally similar, water activity was low (<0.12) and total aerobic plate counts were <10 for all products. Extrudates containing chicken had the highest ratio of polyunsaturated fatty acids to saturated fatty acids, whereas those containing beef had the highest ratio of monounsaturated fatty acids to saturated fatty acids. Sensory data indicated that texture was acceptable and flavor characteristics were not different among the products.

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Collodial Properties and Acid Consuming Capacity of Hydrous Aluminum Oxide Suspension (제산제 알루미나수화물의 콜로이드성과 제산능)

  • 이계주;이기명
    • YAKHAK HOEJI
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    • v.35 no.4
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    • pp.277-282
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    • 1991
  • Rheological, colloidal and micromeritical properties were followed to investigate aging mechanisms of hydrous aluminum oxide suspension using Zeta-meter systems, BET adsorption apparatus, Master sizer and electronmicroscope. The results indicate that hydrous aluminum oxide suspension revealed plastic flow with thixotropy. The viscosity, thixotropy and yield value were increased with increasing concentration. During aging process, the viscosity and thixotropic index were increased by an addition of glycerin, however, sorbitol stabilized aging process of the suspension being accompanied with growth of particle size and reduction in specific surface area, pore area and pore volume, and consistency. Diminution of adsorptive power of the particles was also protected by addition of sorbitol to hydrous aluminum oxide suspension. From these results, one of aging mechanism of hydrous aluminum oxide suspension assumed growth and/or crystallization of colloidal particles in aqueous suspension.

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Effect of Maleylation on Physicochemical Properties of Soybean Glycinin

  • Shin, Weon-Sun;Park, Soo-Jin;Park, Chun-Wuk;Kim, Kang-Sung
    • Macromolecular Research
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    • v.15 no.7
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    • pp.671-675
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    • 2007
  • Soybean proteins appear to harbor a great deal of potential as functional ingredients due to the fact that they are composed of highly bioavailable peptides and amino acids. To develop drink- or gel-type foods formulated with soybean protein, the physicochemical properties of intact and chemically modified soy glycinin were assessed. Maleylation to soy glycinin altered the surface charges of glycinin via the modification of lysine residues, and subsequently generated the dissociation of glycinin subunits owing to the increase in charge repulsion. This modification thus improved the solubility of glycinin, particularly under acidic pH conditions. It is worthy of note that maleylation increased the susceptibility of the basic subunits of mTGase and the formation of a substantial quantity of molecules at a low protein solution concentration. The results of dynamic rheological studies indicated that the 5% intact glycinin progressively formed the gel with mTGase treatment in a concentration-dependent manner, but maleylated-glycinin did not.

SINGLE-PHASE MULTI-COMPONENT SIMULATION OF STATIC SHAPE AND DYNAMIC DEFORMATION OF RED BLOOD CELLS USING LATTICE BOLTZMANN METHOD (Lattice Boltzmann Method을 이용한 적혈구의 정적인 모양과 동적변형에 대한 연구)

  • Farhat, Hassan;Kim, Y.H.;Lee, J.S.
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03a
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    • pp.186-196
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    • 2008
  • The dependence of the rheological properties of blood on shape, aggregation, and deformability of red blood cells (RBCs) has been investigated using hybrid systems by coupling fluid with solid models. We present a simple approach for simulating blood as a multi-component fluid, in which RBCs are modeled as droplets of acquired biconcave shape. We used lattice Boltzmann method (LBM) due to its excellent numerical stability as a simulation tool. The model enables us to control the droplet static shape by imposing non-isotropic surface tension force on the interface between the two components. The use of the proposed non-isotropic surface tension method is justified by the Norris hypothesis. This hypothesis states that the shape of the RBC is due to a non-uniform interfacial surface tension force acting on the RBC periphery. This force is caused by the unbalanced distribution of the lipid molecules on the surface of the RBC. We also used the same concept to investigate the dynamic shape change of the RBC while flowing through the microvasculature, and to explore the physics of the Fahraeus, and the Fahraeus-Lindqvist effects.

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SINGLE-PHASE MULTI-COMPONENT SIMULATION OF STATIC SHAPE AND DYNAMIC DEFORMATION OF RED BLOOD CELLS USING LATTICE BOLTZMANN METHOD (Lattice Boltzmann Method을 이용한 적혈구의 정적인 모양과 동적변형에 대한 연구)

  • Farhat, Hassan;Kim, Y.H.;Lee, J.S.
    • 한국전산유체공학회:학술대회논문집
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    • 2008.10a
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    • pp.186-196
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    • 2008
  • The dependence of the rheological properties of blood on shape, aggregation, and deformability of red blood cells (RBCs) has been investigated using hybrid systems by coupling fluid with solid models. We present a simple approach for simulating blood as a multi-component fluid, in which RBCs are modeled as droplets of acquired biconcave shape. We used lattice Boltzmann method (LBM) due to its excellent numerical stability as a simulation tool. The model enables us to control the droplet static shape by imposing non-isotropic surface tension force on the interface between the two components. The use of the proposed non-isotropic surface tension method is justified by the Norris hypothesis. This hypothesis states that the shape of the RBC is due to a non-uniform interfacial surface tension force acting on the RBC periphery. This force is caused by the unbalanced distribution of the lipid molecules on the surface of the RBC. We also used the same concept to investigate the dynamic shape change of the RBC while flowing through the microvasculature, and to explore the physics of the Fahraeus, and the Fahraeus-Lindqvist effects.

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Studies on the Thermal and Rheological Properties of Polypropylene/Starch-MB Blends (폴리프로필렌/옥수수전분 블렌드의 열적 유변학적특성 연구)

  • Kim, Youn Cheol;Lee, Chang-Young
    • Applied Chemistry for Engineering
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    • v.18 no.6
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    • pp.557-561
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    • 2007
  • Polypropylene (PP)/corn starch master batch (starch-MB) blends with different PP compositions of 40, 50, 60, and 80 wt% were prepared by melt compounding at $200^{\circ}C$, using lab scale Brabender mixer. The chemical structures and thermal properties of the PP/starch-MB blends were investigated by FT-IR, differential scanning calorimetry (DSC), and thermogravimetric analyzer (TGA). The chemical structure was confirmed by the existence of hydroxy group. There was no district change in melting temperature and melting enthalpy, and TGA curve indicated a decrease in degradation temperature with starch-MB content. The porosity change of blend was measured by scanning electron microscope (SEM), the degree of porosity on the blend surface increased with the starch-MB content. The rheological properties indicated an increase in complex viscosity, shear thinning tendency and elasticity with the starch-MB concentration. These effects were confirmed by an oscillatory viscometer at $200^{\circ}C$. From these results, it is found that 40 wt% is the optimum starch-MB concentration. The fiber was fabricated from PP60/MB40 with 40 wt% starch-MB and the porosity and tensile properties were investigated.

An Experimental Study on the Rheological Properties of the Combined Self-Compacting Concrete by Quality Variations (품질변동에 따른 병용계 자기충전 콘크리트의 유동특성에 관한 실험적 연구)

  • Kwon, Yeong-Ho
    • Journal of the Korea Concrete Institute
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    • v.26 no.3
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    • pp.277-285
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    • 2014
  • The purpose of this study is to investigate experimentally the variation factors range having influence on the rheological properties of the combined self-compacting concrete according to materials quality, weighting error and site conditions. Two types cement (blast-furnace slag cement and belite cement), lime stone powder as binder and the optimum mix proportions in the preceded study are selected for this study. Also, variations for sensitivity test are as followings; (1) Concrete temperature 3 cases (2) Surface moisture of sand 5cases (3) Fineness modulus of sand 5cases (4) Specific surface of lime stone powder 3cases (5) Dosage of chemical admixture 5cases. Slump flow ($650{\pm}50mm$), 500 mm reaching time (($7{\pm}3sec$), V-type flowing time ($15{\pm}5sec$) and U-box height (min. 300 mm) are tested for sensitivity. As test results, the variations range for quality control are as followings. (1) Concrete temperature; $10{\sim}20^{\circ}C$(below $30^{\circ}C$) (2) Surface moisture of sand; $base{\pm}0.6%$ (3) Fineness modulus of sand; $2.6{\pm}0.2$ (4) Dosage of chemical admixture; $base{\pm}0.2%$ (5) Specific surface of lime stone powder $6000cm^2/g$. Compared with two types cement including based belite cement (binary type) and based slag cement (ternary type), the combined self-compacting concrete used belite cement type is most stable in the quality control because of high contents for lime stone powder and $C_2S$. It is to propose a control scheme of the combined self-compacting concrete in the actual construction work.

Studies on Rheological Properties of High Solid Coating Colors(Part 2) - Effect of Rheology Modifiers on High-Shear Viscosity and Dynamic Penetration Behavior - (고농도 도공액의 유동특성에 관한 연구(제2보) - 유동성 조절제가 고전단 점도 및 동적 침투특성에 미치는 영향 -)

  • Yoo, Sung-Jong;Cho, Byoung-Uk;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.3
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    • pp.121-127
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    • 2011
  • This study used two types of rheology modifiers including an alkali-swellable emulsion (ASE) and an surface-adhesion emulsion (SAE) to elucidate their effects on high shear viscosity and dynamic penetration behavior among the flow properties of high solids coating. Since rheology under high shear and dynamic penetration behavior significantly affect the quality of coated paper in case of high solids coating, it is very important to examine the variations in rheology of high solids coating color by rheology modifier. It was found that the high solids coating color prepared with the SAE type showed superior dynamic penetration behavior and high shear viscosity than that with the ASE type rheology modifier.

A Study on Rheological Properties for Preparing Flow Mark Free PP Compounds (흐름자국이 없는 PP 복합소재 제조를 위한 유변학적 특성 연구)

  • Lee, Yong-Hee;Nam, Byeong-Uk;Lim, Jae-Gon;Choi, Chi-Hoon
    • Elastomers and Composites
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    • v.44 no.2
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    • pp.156-163
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    • 2009
  • Our objective is to increase the flowability of Polypropylene(PP) compounds and achieve flow mark free surface in injection molded specimen. We have investigated flowabilities of PP compounds which were composed of PP, rubber, talc, and trace amount of additives. Flowability measurement was performed with four types PPs of which molecular weight distributions(MWD) and melt indexes(MI) were different. Rheological properties of the PP compounding materials, such as spiral flow(SF) length, MI, and shear viscosity, were evaluated. When PP with the broad MWD was used, there were remarkable cases where the spiral flow length of low MI PP compound was longer than that of higher MI PP compound. The PP compound having low MI but broad MWD PP has more flowability than the compound with only high MI.