• 한국결정성장학회:학술대회논문집
• /
• 한국결정성장학회 2000년도 Proceedings of 2000 International Nano Crystals/Ceramics Forum and International Symposium on Intermaterials
• /
• pp.215-232
• /
• 2000

The Valence(Z) of positively and negatively charged alumina particles in the dilute suspensions was analyzed with the electrical conductivity of the suspensions. The mobility of negative particles was lower than that of positive particles at a similar Z value because of the stronger effect of chemical bonding over the hydrated particle surfaces. The apparent viscosity of acidic suspensions of 1-40 vol % solid was lower than that of basic suspensions. This result was discussed based on the three important effects of the valence, concentration and nature of hydrated surface of alumina particles. The density of alumina compacts consolidated by filtration through gypsum molds became lower for the basic suspensions than for the acidic suspensions. This result was correlated to the properties of the colloidal alumina suspensions.

• 한국축산식품학회:학술대회논문집
• /
• 한국축산식품학회 1997년도 제18차 정기총회 및 학술발표회
• /
• pp.19-39
• /
• 1997

Extrusion conditions were optimized for blends of ground lamb and starch using a single-screw extruder for the purpose of producing expanded snack-type products. A central composite rotatable response surface methodology(RSM) design was used with variation in feed moisture, process temperature, and screw speed. The three variables significantly affected one or more of the measured physical properties of extrudates. The optimum conditions for minimum shear force values were 26.5% feed moisture, $148^{\circ}C$ process temperature, and 134 rpm screw speed. Lean ground beef, chicken, goat, lamb or mutton was blended with corn starch, and extruded at the optimum condition established from RSM experiments. Physical/rheological properties were generally similar, water activity was low (<0.12) and total aerobic plate counts were <10 for all products. Extrudates containing chicken had the highest ratio of polyunsaturated fatty acids to saturated fatty acids, whereas those containing beef had the highest ratio of monounsaturated fatty acids to saturated fatty acids. Sensory data indicated that texture was acceptable and flavor characteristics were not different among the products.

• 약학회지
• /
• 제35권4호
• /
• pp.277-282
• /
• 1991

Rheological, colloidal and micromeritical properties were followed to investigate aging mechanisms of hydrous aluminum oxide suspension using Zeta-meter systems, BET adsorption apparatus, Master sizer and electronmicroscope. The results indicate that hydrous aluminum oxide suspension revealed plastic flow with thixotropy. The viscosity, thixotropy and yield value were increased with increasing concentration. During aging process, the viscosity and thixotropic index were increased by an addition of glycerin, however, sorbitol stabilized aging process of the suspension being accompanied with growth of particle size and reduction in specific surface area, pore area and pore volume, and consistency. Diminution of adsorptive power of the particles was also protected by addition of sorbitol to hydrous aluminum oxide suspension. From these results, one of aging mechanism of hydrous aluminum oxide suspension assumed growth and/or crystallization of colloidal particles in aqueous suspension.

• Macromolecular Research
• /
• 제15권7호
• /
• pp.671-675
• /
• 2007

Soybean proteins appear to harbor a great deal of potential as functional ingredients due to the fact that they are composed of highly bioavailable peptides and amino acids. To develop drink- or gel-type foods formulated with soybean protein, the physicochemical properties of intact and chemically modified soy glycinin were assessed. Maleylation to soy glycinin altered the surface charges of glycinin via the modification of lysine residues, and subsequently generated the dissociation of glycinin subunits owing to the increase in charge repulsion. This modification thus improved the solubility of glycinin, particularly under acidic pH conditions. It is worthy of note that maleylation increased the susceptibility of the basic subunits of mTGase and the formation of a substantial quantity of molecules at a low protein solution concentration. The results of dynamic rheological studies indicated that the 5% intact glycinin progressively formed the gel with mTGase treatment in a concentration-dependent manner, but maleylated-glycinin did not.

• 한국전산유체공학회:학술대회논문집
• /
• 한국전산유체공학회 2008년도 학술대회
• /
• pp.186-196
• /
• 2008

The dependence of the rheological properties of blood on shape, aggregation, and deformability of red blood cells (RBCs) has been investigated using hybrid systems by coupling fluid with solid models. We present a simple approach for simulating blood as a multi-component fluid, in which RBCs are modeled as droplets of acquired biconcave shape. We used lattice Boltzmann method (LBM) due to its excellent numerical stability as a simulation tool. The model enables us to control the droplet static shape by imposing non-isotropic surface tension force on the interface between the two components. The use of the proposed non-isotropic surface tension method is justified by the Norris hypothesis. This hypothesis states that the shape of the RBC is due to a non-uniform interfacial surface tension force acting on the RBC periphery. This force is caused by the unbalanced distribution of the lipid molecules on the surface of the RBC. We also used the same concept to investigate the dynamic shape change of the RBC while flowing through the microvasculature, and to explore the physics of the Fahraeus, and the Fahraeus-Lindqvist effects.

• 한국전산유체공학회:학술대회논문집
• /
• 한국전산유체공학회 2008년 추계학술대회논문집
• /
• pp.186-196
• /
• 2008

The dependence of the rheological properties of blood on shape, aggregation, and deformability of red blood cells (RBCs) has been investigated using hybrid systems by coupling fluid with solid models. We present a simple approach for simulating blood as a multi-component fluid, in which RBCs are modeled as droplets of acquired biconcave shape. We used lattice Boltzmann method (LBM) due to its excellent numerical stability as a simulation tool. The model enables us to control the droplet static shape by imposing non-isotropic surface tension force on the interface between the two components. The use of the proposed non-isotropic surface tension method is justified by the Norris hypothesis. This hypothesis states that the shape of the RBC is due to a non-uniform interfacial surface tension force acting on the RBC periphery. This force is caused by the unbalanced distribution of the lipid molecules on the surface of the RBC. We also used the same concept to investigate the dynamic shape change of the RBC while flowing through the microvasculature, and to explore the physics of the Fahraeus, and the Fahraeus-Lindqvist effects.

• 공업화학
• /
• 제18권6호
• /
• pp.557-561
• /
• 2007

폴리프로필렌(polypropylene, PP)/옥수수전분(corn starch) 마스터뱃취(MB) 블렌드를 PP 함량을 40, 50, 60, 80 wt%로 변화시키며 실험실 규모의 Brabender mixer를 이용하여 $200^{\circ}C$에서 제조하였다. PP/전분MB 블렌드의 화학구조와 열적특성을 적외선분광기(FT-IR), 시차주사열용량분석기(DSC) 그리고 열중량분석기(TGA)를 이용하여 관찰하였다. PP/전분MB 블렌드의 화학구조는 수산기의 존재여부를 통해 확인하였다. 또한 용융온도 및 엔탈피에는 큰 변화가 나타나지 않음을 알 수 있었고, 블렌드의 분해온도는 전분MB 함량에 따라 감소하고 있음을 보여주었다. 블렌드의 다공성 변화는 주사전자현미경(SEM)을 이용하여 측정하였고, 전분MB의 함량이 증가함에 따라 표면에 다공성의 증가를 보여주었다. PP/전분MB 블렌드의 유변학적 특성은 $200^{\circ}C$에서 동적유변학측정기를 이용하여 측정하였다. 전분MB의 함량이 증가할수록 용융점도와 shear thinning이 증가하였고, 탄성특성이 증가함을 보여주었다. 열적특성, 다공성 형성여부와 유변학적특성을 비교 평가하여, 전분MB의 함량을 40 wt%로 선정하였다. PP60/전분MB40 블렌드를 이용하여 섬유를 제조하였고, 다공성과 인장특성을 평가하였다.

• 콘크리트학회논문집
• /
• 제26권3호
• /
• pp.277-285
• /
• 2014

이 연구는 현장에서 사용하는 재료의 품질 및 계량오차, 현장조건 등에 따라 병용계 자기충전 콘크리트의 유동특성에 영향을 미치는 변동요인의 범위를 실험적으로 규명하기 위한 것이다. 병용계 자기충전 콘크리트의 재료는 벨라이트 시멘트와 석회석 미분말을 사용한 벨라이트계 및 슬래그 시멘트와 석회석 미분말을 사용한 슬래그계가 선정되었으며, 선행연구에서 제시된 최적배합 조건을 대상으로 하였다. 변동요인으로 (1) 콘크리트의 온도 3종류, (2) 잔골재의 표면수율 5종류, (3) 잔골재의 조립률 5종류, (4) 고성능AE감수제의 사용량 5종류, (5) 석회석 미분말의 분말도 3종류 등을 대상으로 민감도 시험을 실시하였다. 민감도 시험의 항목은 슬럼프 플로우, 500 mm 플로우 도달시간, V-깔대기 유하시간, U-box 충전성 높이를 대상으로 하였다. 실험 결과, (1) 콘크리트 온도는 $10{\sim}20^{\circ}C$ 범위, (2) 잔골재의 표면수율은 ${\pm}0.6%$ 범위, (3) 잔골재의 조립률 $2.6{\pm}0.2$ 범위, (4) 고성능AE감수제의 사용량은 ${\pm}0.2%$ 범위, (5) 석회석 미분말의 분말도는 $6000cm^2/g$ 범위에서 현장품질을 관리해야 한다. 벨라이트계 및 슬래그계에 따른 차이는 크지 않았지만, 석회석 미분말 및 $C_2S$ 함량이 높은 벨라이트계가 안정적인 경향을 나타내었다. 따라서 이러한 결과를 현장 시공현장에서 병용계 자기충전 콘크리트의 관리방안으로 제안하고자 한다.

• 펄프종이기술
• /
• 제43권3호
• /
• pp.121-127
• /
• 2011

This study used two types of rheology modifiers including an alkali-swellable emulsion (ASE) and an surface-adhesion emulsion (SAE) to elucidate their effects on high shear viscosity and dynamic penetration behavior among the flow properties of high solids coating. Since rheology under high shear and dynamic penetration behavior significantly affect the quality of coated paper in case of high solids coating, it is very important to examine the variations in rheology of high solids coating color by rheology modifier. It was found that the high solids coating color prepared with the SAE type showed superior dynamic penetration behavior and high shear viscosity than that with the ASE type rheology modifier.

• Elastomers and Composites
• /
• 제44권2호
• /
• pp.156-163
• /
• 2009

사출성형 시 흐름자국이 생기지 않는 흐름성이 향상된 PP(Polypropylene) 복합재료를 제조하기 위한 연구를 진행하였다. PP는 분자량 분포와 용융지수(MI)가 다른 4종류의 PP를 사용하였으며, PP, 탈크, 고무와 약간의 첨가제로 구성된 PP컴파운드의 유변학적 특성은 Spiral Flow(SF), MI, 전단점도를 측정함으로써 평가하였다. 분자량 분포가 넓은 PP를 사용한 경우 MI가 상대적으로 낮다 하더라도 SF는 MI가 높은 PP보다 높게 관찰되는 경우도 있었다. 사출성형시 표면에 흐름자국이 발생하지 않도록 하기 위해서는 분자량 분포가 넓은 PP를 사용하는 것이 바람직 함을 확인하였다.