• Title/Summary/Keyword: surface reactivity

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Characteristics of Gold and Silver Based Bi- and Tri-metallic SPR Chip in the Intensity Measurement Mode (반사광 측정 모드에서 금과 은을 사용한 이층 금속 칩과 삼층 금속 칩의 특성 연구)

  • Kim, Hyungjin;Kim, Chang-duk;Sohn, Young-Soo
    • Journal of Sensor Science and Technology
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    • v.25 no.2
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    • pp.143-147
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    • 2016
  • Characteristics of the conventional gold (Au) surface plasmon resonance (SPR) chip, bi-metallic(Au/silver (Ag)) SPR chip, and tri-metallic(Au/Ag/Au) SPR chip were investigated and compared in the intensity measurement mode for the enhancement of SPR image sensor reactivity. Reflectance curves of the Au, bi- and tri-metallic SPR chips were acquired in phosphate-buffered saline (PBS) solution and were compared. The line width of the reflectance curve of the bi-metallic chip was the narrowest among the three different types of the chips. Also, the tangential slope of the bi-metallic chip was steeper than those of the other chips. Various concentrations of bovine serum albumin (BSA) were utilized in the SPR experiment. As a result, among the above three chips reflectance variation value of the bi-metallic chip was the largest.

Investigation of Oxygen Incorporation in AlGaN/GaN Heterostructures

  • Jang, Ho-Won;Baik, Jeong-Min;Lee, Jong-Lam;Shin, Hyun-Joon;Lee, Jung-Hee
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.3 no.2
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    • pp.96-101
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    • 2003
  • Direct evidence on the incorporation of high concentration of oxygen into undoped AlGaN layers for the AlGaN/GaN heterostuctures is provided by scanning photoemission microscopy using synchrotron radiation. In-situ annealing at $1000^{\circ}C$ resulted in a significant increase in the oxygen concentration at the AlGaN surface due to the predominant formation of Al-O bonds. The oxygen incorporation into the AlGaN layers resulting from the high reactivity of Al to oxygen can enhance the tunneling-assisted transport of electrons at the metal/AlGaN interface, leading to the reduction of the Schottky barrier height and the increase of the sheet carrier concentration near the AlGaN/GaN interface.

Improvement of $CO_2$Decomposition by Impregnating Noble Metals to Nano-size (Ni, Zn)-ferrites (귀금속 첨가에 의한 나노 (Ni, Zn)-페라이트의 $CO_2$분해 향상)

  • Kim, Jeong-Sik;An, Jeong-Ryul;Gang, Gye-Myeong
    • Korean Journal of Materials Research
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    • v.11 no.10
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    • pp.846-850
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    • 2001
  • In the present study, nano-size powders of ternary ferrites, $Ni_{0.5}Zn_{0.5}Fe_2O_4$, as the potential catalysts of $CO_2$decomposition, were prepared by the wet processing of hydrothermal synthesis and coprecipitation method, and the catalyzing effects of impregnation of the noble metals, Pt and Pd, onto $Ni_{0.5}Zn_{0.5}Fe_2O_4$for the $CO_2$decomposition were investigated. XRD results of the synthesized ferrites showed a typical spinel structure of ferrite and the particle size was very small as about 6~10 nm. BET surface area of the ternary ferrites was not affected by the impregnation of Pt and Pd. The reactivity of the $CO_2$decomposition to carbon was improved by the impregnation of the noble metals of Pd and Pt. The effect of Pd-impregnation on the $CO_2$decomposition rate was higher than Pt-impregnation.

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"Histologic Examination of Histoacryl When Used in a Subcutaneous Sites.";An Experimental Study (조직접착제인 Histoacryl을 피하조직에 적용하였을 때의 조직학적 소견에 대한 연구)

  • Shin, Dong-Moung;Kim, Jong-Yoo;Lim, Sung-Bin;Chung, Chin-Hyung
    • Journal of Periodontal and Implant Science
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    • v.29 no.4
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    • pp.913-928
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    • 1999
  • Since their discovery in 1949, cyanoacrylates interest many people as possibly being the ideal "Tissue glue". Several different forms of these compounds have been developed in attempt to reduce or eliminate tissue toxicity. Butyl-2-cyanoacrylate(Histoacryl) appears to be the most ideal material as it induces low tissue reactivity & toxicity. In this study, the histotoxic response of histoacryl, when used in a subcutaneous site was compared to a controls which was conventionally sutured. This response was greater than the control that showed no inflammation. However, these findings may not corre-late in actual clinical settings, because most patients tolerate mild degrees of infla-mmation well. Majority of the studies evaluating the histotoxicity of histoacryl have been per-formed when applied superficially & not below the skin surface. This is why further studies are required to evaluate the his-totoxicity of histoacryl when used in a sub-cutaneous site or mucosa.

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Combustion Characteristics of Minco Sub-bituminous Coal at Oxy-Fuel Conditions (민코 아역청탄의 순산소 연소특성)

  • Kim, Jae-Kwan;Lee, Hyun-Dong;Jang, Seok-Won;Kim, Sung-Chul
    • Journal of the Korean Society of Combustion
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    • v.14 no.2
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    • pp.1-9
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    • 2009
  • New way to effectively capture $CO_2$ in coal fired power plant is the combustion of coal using oxy-fuel technology. Combustion characteristics of Minco sub-bituminous coal at oxy-fuel conditions using TGA and drop tube furnace (DTF) were included activation energy about the char burnout, volatile yield and combustion efficiency of raw coal, the porosity of pyrolyzed char and fusion temperature of by-product ash. TGA result shows that the effect of $CO_2$ on combustion kinetics reduces activation energy by approximately 7 kJ/mol at air oxygen level(21% $O_2$) and decreases the burning time by approximately 16%. The results from DTF indicated similar combustion efficiency under $O_2/CO_2$ and $O_2/N_2$ atmospheres for equivalent $O_2$ concentration whereas high combustion efficiency under $O_2/N_2$ than $O_2/CO_2$ was obtained for high temperature of more than $1,100^{\circ}C$. Overall coal burning rate under $O_2/CO_2$ is decreased due to the lower rate of oxygen diffusion into coal surface through the $CO_2$ rich boundary layer. By-product ash produced under $O_2/CO_2$ and $O_2/N_2$ was similar IDT in irrelevant to $O_2$ concentration and atmospheres gas during the coal combustion.

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Improvement of the Quality of Cryogenic Machining by Stabilization of Liquid Nitrogen Jet Pressure (액체질소 분사 안정화를 통한 극저온가공 품질 향상)

  • Gang, Myeong Gu;Min, Byung-Kwon;Kim, Tae-Gon;Lee, Seok-Woo
    • Journal of the Korean Society for Precision Engineering
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    • v.34 no.4
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    • pp.247-251
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    • 2017
  • Titanium alloy has been widely used in the aerospace industry because of its high strength and good corrosion resistance. During cutting, the low thermal conductivity and high chemical reactivity of titanium generate a high cutting temperature and accelerates tool wear. To improve cutting tool life, cryogenic machining by using a liquid nitrogen (LN2) jet is suggested. In cryogenic jet cooling, evaporation of LN2 in the tank and transfer tube could cause pressure fluctuation and change the cooling rate. In this work, cooling uniformity is investigated in terms of liquid nitrogen jet pressure in cryogenic jet cooling during titanium alloy turning. Fluctuation of jet spraying pressure causes tool temperature to fluctuate. It is possible to suppress the fluctuation of the jet pressure and improve cooling by using a phase separator. Measuring tool temperature shows that consistent LN2 jet pressure improves cryogenic cooling uniformity.

Current Research Trends in Water Treatment Membranes Based on Nano Materials and Nano Technologies (나노 기술을 이용한 수처리 분리막 소재의 최근 연구동향)

  • Lee, Hee Dae;Cho, Young Hoon;Park, Ho Bum
    • Membrane Journal
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    • v.23 no.2
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    • pp.101-111
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    • 2013
  • Nano materials having large surface area, uniform dimensions or pores can be utilized in various membrane applications. Recently, many studies have been focused on the application of nano materials and nano technologies in membrane applications by the help of the discovery and development of nano technologies. in terms of mass transport channels or functional modification. However, there have been several technological limitations for commercialization. Nano materials and nano technologies can improve 1) permeability, selectivity, 2) mechanical, chemical, thermal stability or fouling tolerance of conventional membranes and even 3) introduce new functionalities such as specific affinity and reactivity.

Evaluation on Removal of Organics and Nutrients from Reverse Osmosis Concentrate using Activated Carbon (활성탄을 이용한 역삼투 농축수의 유기물 및 영양염류 제거 평가)

  • Joo, Sung Hee;Park, Jong Min;Lee, Yang Woo
    • Journal of Korean Society on Water Environment
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    • v.28 no.3
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    • pp.479-482
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    • 2012
  • Membrane process has been one of the widely applied wastewater treatment options, especially in field. However, one of the tricky issues in the process is to treat concentrates generated from reverse osmosis (RO) system in a manner of saving cost with maximum efficiency for treating a wide range of contaminants. Stimulated with the challenging issues, we have conducted a series of experimental studies in the evaluation for removing organics and nutrients using activated carbon. Results indicated that while powdered activated carbon (PAC) efficiently removed organics and the extent of removal was proportional to the PAC dosage, little removal of nitrogen and phosphorus was observed despite increasing the PAC dose. Interestingly, applying PAC was superior in removing organics than using granular activated carbon (GAC). These results suggest smaller particle size with higher surface area could provide greater chemical reactivity in removing organics.

[ ${\beta}-cyclodextrin$ ] inclusion properties with guest molecules using hetero-bi-functional reactive dye

  • Kim, Byung-Soon;Kim, Young-Sung;Son, Young-A
    • Textile Coloration and Finishing
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    • v.19 no.2
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    • pp.32-35
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    • 2007
  • Cyclodextrin is a cyclic oligosaccharid material which shows an ability to incorporate organic guest molecules inside their cavity area. Thus, this ${\beta}-cyclodextrin$ treatment on fiber substrates may provide the changed surface characteristics of the substrates such as solubility, chemical reactivity and spectral property. In this context, the aim of this present work is to make a bridge connection using hetero-bi-functional reactive dye between fiber substrates and ${\beta}-cyclodextrin$. In addition, the corresponding Berberine inclusion behaviors into the inner cavity of ${\beta}-cyclodextrin$ was examined. The %exhaustion of Berberine inclusion as a guest molecule within the ${\beta}-cyclodextrin$ was measured using UV-Vis spectrophotometer. The findings showed that the %exhaustion of Berberine inclusion increased with increasing the prepared dye bridge compound and ${\beta}-cyclodextrin$ host material.

A Study on Structure and Reactivity of Pt-Rh Bimetallic Catalysts (Pt-Rh 이원금속 촉매의 구조와 반응성에 관한 연구)

  • Kim, Young-Kil;Shin, Ki-Whan;Yie, Jae-Eui
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.661-669
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    • 1996
  • Pt-Rh/NaY catalysts with various Pt/Rh ratios were prepared by an ion-exchange method and their characteristics were investigated by $^{129}Xe$-NMR and EXAFS. Both the $^{129}Xe$-NMR and EXAFS data indicate that the surface of PtRh bimetallic clusters was enriched with Rh atoms. The catalytic activities of these catalysts for conversion of CO, HC and $NO_x$ were measured by using simulated automobile engine exhausts under lean, rich and stoichiometric conditions. The Pt-Rh/NaY(Pt/Rh=1) catalyst exhibited the greatest reactive activity among the catalysts used in this study.

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