• Bulletin of the Korean Chemical Society
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• v.28 no.4
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• pp.635-646
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• 2007

The reaction of gas-phase hydrogen atoms H with H atoms chemisorbed on a graphite surface has been studied by the classical dynamics. The graphite surface is composed of the surface and 10 inner layers at various gas and surface temperatures (Tg, Ts). Three chains in the surface layer and 13 chains through the inner layers are considered to surround the adatom site. Four reaction pathways are found: H2 formation, H-H exchange, H desorption, and H adsorption. At (1500 K, 300 K), the probabilities of H2 formation and H desorption are 0.28 and 0.24, respectively, whereas those of the other two pathways are in the order of 10-2. Half the reaction energy deposits in the vibrational motion of H2, thus leading to a highly excited state. The majority of the H2 formation results from the chemisorption-type H(g)-surface interaction. Vibrational excitation is found to be strong for H2 formed on a cold surface (~10 K), exhibiting a pronounced vibrational population inversion. Over the temperature range (10-100 K, 10 K), the probabilities of H2 formation and H-H exchange vary from 0 to ~0.1, but the other two probabilities are in the order of 10-3.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.15 no.3
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• pp.124-127
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• 2005

It is demonstrated that the annealing process for Ti in-diffusion to z-cut $LiNbO_3$ at temperature lower than the curie temperature in a platinum (Pt) box can cause a ferroelectric micro-domain inversion at the +z surface and Li out-diffusion, therefore which should be avoided or suppressed for waveguide type periodically poled lithium niobate (PPLN) devices. The depth of the inversion layer depends on the Ti-diffusion conditions such as temperature, atmosphere, the sealing method of $LiNbO_3$ in the Pt box and crystal orientation is experimentally examined. The result shows that the polarization-inverted domain boundary appears at the only +z surface and its thickness is about $1.6{\mu}m$. Also, for the etched $LiNbO_3$, surface the domain shape was observed by the optical microscope and atomic force microscopy (AEM), and distribution of the cation concentrations in the $LiNbO_3$ crystal by the secondary ion mass spectrometry (SIMS).

• Proceedings of the Korean Geotechical Society Conference
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• 2005.03a
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• pp.384-391
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• 2005

Three dimensional finite difference elastic wave model was developed to estimate the feasibility of surface wave applications in geotechnical problems. The wave motions calculated by the developed program in this study shows good agreement with well known analytic solutions. The surface wave motions calculated from layered dam type structure can be interpreted as a infinite layer structure using dispersion curve but it is need a special source of which high energy in frequency band lower than 10 Hz to get information of physical properties in few tens meter deep. The source which has high energy in the low frequency band, however, can give defect on dam and this will make some limitation in real field applications. The dispersion curves calculated from the surface wave motion of homogeneous and center core type dam models will give rise to fatal errors if the conventional infinite layer structure used in their interpretation because the surrounding materials and boundaries of dam make some distortion in dispersion curve of surface wave. So it is strongly recommended to use three dimensional inversion model for correct interpretation and estimation of physical properties of dam materials.

• Journal of Environmental Science International
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• v.12 no.12
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• pp.1245-1254
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• 2003

A numerical simulation for 11 February 1996 has been done to grasp main mechanisms of the occurrence of strong downslope winds near Gangnung area. The simulation performed by using ARPS (Advanced Regional Prediction System) showed that enhanced surface winds were not related with a reflection of vertically propagating gravity waves. Froude numbers were about 1.0, 0.4 and 0.6 for the atmosphere above Daekwanryoung and above a place located 220km upstream, and above another place located 230km downstream from the Taebak mountains, respectively. This suggested that as a subcritical flow ascended the upslope side of the Taebak mountains, Froude numbers would tend to increase according to the increase in wind speed, and near the crest the flow would become supercritical and continue to accelerate as it went down the downslope side until it was adapted back to the ambient subcritical conditions in a turbulent hydraulic jump. Simulated Froude numbers corroborated the hydraulic jump nature of the strong downslope wind. In addition, the inversion was found near the mountain top height upstream of the mountains, and it was favorable for the occurrence of strong downslope winds.

• Applied Chemistry for Engineering
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• v.19 no.2
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• pp.185-190
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• 2008

In order to increase the surface area of electrodes for electrosorption, porous carbon electrodes were fabricated by a wet phase inversion method. A carbon slurry consisting of a mixture of activated carbon powder (ACP), polyvinylidene fluoride (PVdF), and N-methyl-2-pyrrolidone (NMP) as a solvent was cast directly on a graphite sheet. The cast film was then immersed in pure water for phase inversion. The physical and electrochemical properties of the electrodes were investigated using scanning electron microscopy (SEM), porosimetry, and cyclic voltammetry. The SEM images verified that the pores of various sizes were formed uniformly on the electrode surface. The average pore sizes determined for the electrodes fabricated with various NMP contents ranged from 64.2 to 82.4 nm and the size increased as the NMP content increased. All of the voltammograms showed a typical behavior of charging and discharging characteristic at the electric double layer. The electrical capacitance ranged from 3.88 to $5.87F/cm^2$ depending on the NMP contents, and the electrical capacitance increased as the solvent content decreased. The experimental results showed that the solvent content is an important variable controlling pore size and ultimately the capacitance of the electrode.

• 한국지구물리탐사학회:학술대회논문집
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• 2006.06a
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• pp.125-130
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• 2006

Both surface seismic and far-offset VSP data were recorded alongtwo mutually perpendicular profiles in the Pungam basin. The first-arrival times were simultaneously inverted using the tomography method. For the surface data, seismic energy was generated by a 5-kg sledgehammer at 48 stations and detected by 21 surface geophones at 3 m intervals and one 3-component geophone in test borehole for the purpose of static corrections. For the VSP data, seismic waves generated by the sledgehammer on the ground were detected by a 3-component borehole geophone in a depth range of $9{\sim}99\;m$. Delay times of the hammer data were corrected using the seisgun data before the inversion to yield velocity tomograms. The tomograms indicates that the soil layer with velocities less than 750 m/s averages 1.8 m thick. The velocity varies from 5353 m/s at the depth range of $31{\sim}40\;m$ to 4262 m/s at the depth range of $65{\sim}73\;m$. Compared with core samples, the relatively large variation in velocity may due to lithology changes and fracture effects with depth.

• Proceedings of the Korean Geotechical Society Conference
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• 2000.11a
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• pp.577-584
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• 2000

Seismic refraction survey was peformed for 10 lines along NE-SW and NW-SE directions above Nampoong gallery at Makyo-ri, Dogye, Samcheok, Kangwon-do. 48 geophones were laid in line with the interval of 1m, and a 5Kg hammer was used as a source at 5 points for each line. Data processing was done using reciprocal time method, GRM, and traveltime tomography which utilizes wavefront expansion method for forward process and SIRT for inversion. The result shows that the first layer has its lower boundary between 3.49m and 8.88m. The P-wave velocity of the first and the second layer were estimated as 270 360m/s and 1550 1940m/s respectively. When the boundary of the first and second layer is smooth enough and the velocity difference is large enough, GRM has little advantage over reciprocal time method. The result of reciprocal method and traveltime tomography shows consistency. The northeast part of the boundary has syncline structure, which is similar to the topography above. This implies that the collapse of the cavities of Nampoong gallery result in the subsidence of the ground surface. The subsidence is in progress across the Youngdong railroad, therefore a proper reinforcement work is required.

• 한국지구물리탐사학회:학술대회논문집
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• 2005.05a
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• pp.287-291
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• 2005

Two-dimensional velocity tomograms of P- and S-waves were obtained by inverting traveltimes of first arrivals. The two sections of shear-wave velocity show similar features as a whole, with smaller values on the section from surface wave dispersions. Difficulties in picking SH-wave phases due to noise and later arrivals than P waves and PS converted waves are experienced. In addition, a flat layer model based on the surface wave inversion prohibits applications of the method where sgear wave velocities vary strongly in the lateral direction.

• Geophysics and Geophysical Exploration
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• v.12 no.1
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• pp.85-98
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• 2009

The tau-p inversion algorithm is widely employed to generate starting models with most computer programs, which implement refraction tomography. This algorithm emphasises the vertical resolution of many layers, and as a result, it frequently fails to detect even large lateral variations in seismic velocities, such as the decreases which are indicative of shear zones. This study demonstrates the failure of the tau-p inversion algorithm to detect or define a major shear zone which is 50m or 10 stations wide. Furthermore, the majority of refraction tomography programs parameterise the seismic velocities within each layer with vertical velocity gradients. By contrast, the Generalized Reciprocal Method (GRM) inversion algorithms emphasise the lateral resolution of individual layers. This study demonstrates the successful detection and definition of the 50m wide shear zone with the GRM inversion algorithms. The existence of the shear zone is confirmed by a 2D analysis of the head wave amplitudes and by numerous closely spaced orthogonal seismic profiles carried out as part of a later 3D refraction investigation. Furthermore, an analysis of the shot record amplitudes indicates that a reversal in the seismic velocities, rather than vertical velocity gradients, occurs in the weathered layers. The major conclusion reached in this study is that while all seismic refraction operations should aim to provide as accurate depth estimates as is practical, those which emphasise the lateral resolution of individual layers generate more useful results for geotechnical and environmental applications. The advantages of the improved lateral resolution are obtained with 2D traverses in which the structural features can be recognised from the magnitudes of the variations in the seismic velocities. Furthermore, the spatial patterns obtained with 3D investigations facilitate the recognition of structural features such as faults which do not display any intrinsic variation or 'signature' in seismic velocities.

• Applied Chemistry for Engineering
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• v.10 no.4
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• pp.515-522
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• 1999

Asymmetric polyetherimide membrane were prepared by phase inversion method, and the effects of NaOH concentration and reaction time on the morphology change of the polyetherimide membranes were studied. The morphology of skin layers varied from dense structure to sphere structure with increasing concentration of modification solution. The thickness of dense layer increased with increasing reaction time. However, when either the concentration of modifying solution was very high or the reaction time was very long, the dense layers of the asymmetric membrane were disappeared. From these results, it was found that the surface morphology of the asymmetric polyetherimide membranes depended strongly on the modification conditions such as concentration of modification solution and reaction time. These results might be explained by the hydrolysis reaction of polyetherimide into polyamic acid by the NaOH solution.