• Economic and Environmental Geology
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• v.55 no.4
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• pp.367-376
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• 2022

One of biopolymer, β-glucan (BG) chains were crosslinked by citric acid under the heating condition for the adsorption of Pb and Cu ions in the aqueous solution. The variation of functional groups on BG itself and crosslinked β-glucan (CBG) with their surface adsorption characteristics were investigated by FTIR and SEM-EDX. Adsorption kinetic results showed that adsorption of Pb and Cu onto the CBG followed the pseudo-second-order kinetic model and intra-particle diffusion model. The Langmuir adsorption model was depicted better adsorption characteristics than the Freundlich model. The adsorption capacities of Pb and Cu onto the CBG estimated by the Langmuir model were 59.70 and 23.44 mg/g, respectively. This study suggested that CBG may act as an eco-friendly adsorbent for the adsorption of Pb and Cu in the aqueous solution.

• Korean Journal of Materials Research
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• v.32 no.5
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• pp.264-269
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• 2022

Ti₃C₂T_x MXene, which is a representative of the two-dimensional MXene family, is attracting considerable attention due to its remarkable physicochemical and mechanical properties. Despite its strengths, however, it is known to be vulnerable to oxidation. Many researchers have investigated the oxidation behaviors of the material, but most researches were conducted at high temperatures above 500 ℃ in an oxidation-retarding environment. In this research, we studied changes in the structural and electrical properties of Ti₃C₂T_x MXene induced by low-temperature heat treatments in ambient conditions. It was found that a number of TiO₂ particles were formed on the MXene surface when it was mildly heated to 200 ℃. Heating the material to higher temperatures, up to 400 ℃, the phase transformation of Ti₃C₂T_x MXene to TiO₂ was accelerated, resulting in a TiO₂/Ti₃C₂T_x hybrid. Consequently, the metallic nature of pure Ti₃C₂T_x MXene was transformed to semiconductive behavior upon heat-treating at ≥ 200 ℃. The results of this research clearly demonstrate that Ti₃C₂T_x MXene may be easily oxidized even at low temperatures once it is exposed to air.

• Journal of Powder Materials
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• v.29 no.6
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• pp.477-484
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• 2022

Thermal protection systems (TPS) are a group of materials that are indispensable for protecting spacecraft from the aerodynamic heating occurring during entry into an atmosphere. Among candidate materials for TPS, ceramic insulation materials are usually considered for reusable TPS. In this study, ceramic insulation materials, such as alumina enhanced thermal barrier (AETB), are fabricated via typical ceramic processing from ceramic fiber and additives. Mixtures of silica and alumina fibers are used as raw materials, with the addition of B4C to bind fibers together. Reaction-cured glass is also added on top of AETB to induce water-proof functionality or high emissivity. Some issues, such as the elimination of clumps in the AETB, and processing difficulties in the production of reusable surface insulation are reported as well.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.3C
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• pp.219-228
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• 2006

In this study, a series of fire tests was carried out to evaluate fire-induced damage to structural members in tunnels. From the tests, the loss amount of concrete materials under the RWS scenario was slightly bigger than under the RABT fire scenario. Especially under the RWS fire scenario where the maximum temperature is over $1,200^{\circ}C$, the loss of concrete materials was mainly induced by melting. Generally, the loss of materials in reinforced concrete was slightly smaller than that in unreinforced concrete. Depending upon an applied fire scenario, fire-induced damage to shotcrete was quite different. From the realtime investigation of a specimen surface by a digital camcorder, it was proved that the material loss under the RABT fire scenario was mainly induced by spalling. However, it was also revealed that although fire-induced damage in the initial heating stage under the RWS was so close to that under the RABT, the material loss under the RWS at the later stage after 50 minutes elapsed since fire initiation was induced not by spalling but by melting.

• Journal of the Korean Society for Heat Treatment
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• v.37 no.1
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• pp.16-22
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• 2024

The conventional degreasing process involves removing oil and contaminants at temperatures above 80℃, resulting in excessive energy consumption, increased process costs, and environmental issues. In this study, we aimed to find the optimal degreasing conditions for the pre-treatment process of electro-galvanizing cold-rolled steel sheets, conducted efficiently at room temperature without the need for a separate heating device. To achieve this, we developed a room temperature degreasing solution and a brush-type degreasing tool, aiming to reduce energy consumption and normalize the decrease in degreasing efficiency caused by temperature reduction. Alkaline degreasing solution were prepared using KOH, SiO₂, NaOH, Na₂CO₃, and Sodium Lauryl Sulfate, with KOH and NaOH as the main components. To enhance the degreasing performance at room temperature, we manufactured additives including sodium oleate, sodium stearate, sodium palmitate, sodium lauryl sulfate, ammonium lauryl sulfate, silicone emulsion, and EDTA-Na. Room temperature additives were added to the alkaline degreasing solution in quantities ranging from 0.1 to 20 wt.%, and the uniformity of degreasing and the adhesion of the galvanized layer were evaluated through Dyne Test, T-bending Test, OM, SEM, and EDS analyses. The results indicated that the optimal degreasing solution composition consisted of NaOH (30 g/L), Na₂CO₃ (30 g/L), SLS (6 g/L), and room temperature additives (≤1 wt%).

• Journal of the Microelectronics and Packaging Society
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• v.23 no.2
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• pp.97-104
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• 2016

In the preparation of Ag-coated Cu flakes using L-ascorbic acid as a reductant for the electroless Ag plating, the effects of pretreatment methods and the reductant concentration on the uniformity of Ag coating layer and the anti-oxidation property of Ag-coated Cu flakes during the heating in air were evaluated. It was found that the removal degree of surface oxide layer during the pretreatment has great influence on the uniformity of Ag coating layer and the formation degree of hole defects in the flakes has slight effect on the anti-oxidation property of Ag-coated Cu flakes. It was also verified that the reductant concentration has great influence on the coverage uniformity and thickness of Ag coating, thus it was could be considered a main process parameter. When the reductant concentration was 0.04 M, high-quality Ag-coated Cu flakes was obtained. When the concentration increased to 0.06 M, however, the anti-oxidation property of Ag-coated Cu flakes became remarkably worse owing to remnant of Cu surface non-coated with Ag by the formation of pure Ag fine particles.

• Fire Science and Engineering
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• v.33 no.6
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• pp.126-131
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• 2019

Real-scale fire tests were performed on animal-origin foods using a gas stove with no overheating prevention device. When the animal-origin foods were ignited, a large quantity of white smoke and steam was generated from them; however, when they became dry and began to carbonize, a dark smoke was generated. Even after the gas stove was overheated for more than 5400 s, mackerel, pollack, chicken, etc., did not ignite. However, pork, beef, and tuna caught fire after 2643 s, 2819 s, and 6492 s of heating, respectively. The flame patterns of animal-origin foods were in the forms of a mixed laminar flow and a turbulent flow, and a halo pattern was produced. A sand glass form of the flame pattern was generated when a kitchen hood was operated, but a triangular flame pattern was produced when the kitchen hood was not operated. When the tuna in the pot was overheated, it spontaneously ignited after 6492 s, with the surface temperature of the kitchen hood rapidly rising to 464.5 ℃. Moreover, the temperature at the back of the pot, which was 6 cm away from the outer surface of the upper part of the pot, was 869 ℃ after 6660 s because of the radiant heat. The flame formed a sand glass pattern on the kitchen wall. When the kitchen hood was not operated, or when the flame grew lower than the height of the ceiling, a triangular pattern was formed.

• Journal of Bio-Environment Control
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• v.22 no.1
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• pp.35-41
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• 2013

This study was conducted to provide data necessary for reducing the condensation on greenhouse covering in winter season. The variation of VPD (Vapor Pressure Deficit) and condensation flux was analyzed in experimental tomato greenhouse. VPD values in experimental plastic greenhouse were greater than 0.2 kPa of disease prevention threshold, and lower than 0.5 kPa of threshold for dehumidification. The surface temperature of inside covering was slightly higher than the average temperature of outside and above curtain, and changed according to outside temperature. The humidity above curtain was nearly 100% and good condition for condensation. The humidity below curtain was 75~90% and comparatively stable condition for growing. The condensation flux value in experimental greenhouse corresponded with result of Seginer and Kantz (1986).

• Journal of Soil and Groundwater Environment
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• v.17 no.2
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• pp.54-61
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• 2012

In this study, the adsorption of $Cu^{2+}$ from aqueous solution by the biochar derived from woody biomass at different pyrolysis temperatures has been investigated. The woody biomass wastes used in this study were branch of willow ($Salix$ $koreensis$ $Andersson$) and bark of chestnut ($Castanea$ $crenata$ $var.$ $dulcis$). Three biochar samples prepared by heating each biomass at temperature of $300^{\circ}C$, $500^{\circ}C$, and $700^{\circ}C$were tested for the adsorption capacity of Cu. Also the physicochemical properties of the developed biochars were studied using different characterization techniques such as FT-IR, SEM, BET surface area, and cation exchange capacity (CEC). The adsorption of Cu could be well described by Langmuir model for both willow and chestnut biochars with $R^2{\geq}0.98$. The maximum adsorption capacities of the biochar produced at $700^{\circ}C$ from the Langmuir equation were found to be 12.5 mg $g^{-1}$ and 16.9 mg $g^{-1}$ for willow and chestnut, respectively. Chestnut biochar was found to interact more effectively with the active sites available for Cu, resulting higher removal of Cu(II) than wiloow biochar. Ion exchange and surface complexation found to be the main mechanisms involved in the adsorption process. This study demonstrated the feasibility of the biochars derived from woody biomass to be as a low-cost potential adsorbent for heavy metals as Cu(II) removal in aquatic system.

• Journal of Bio-Environment Control
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• v.22 no.3
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• pp.270-278
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• 2013

The objective of the present study is to provide data needed to decide covering method to be able to increase the thermal insulation and light transmittance efficiency of commercial greenhouse. The thermal insulation effect, PPF transmittance and quantity of condensation water were estimated in experimental tomato greenhouses covered with three types of coverings of single layer, air inflated and conventional double layers covering. The overall heat flow of air inflated double layers greenhouse was similar to that of conventional double layers greenhouse, but the temperature between covering material and thermal screen in air inflated double layers greenhouse was lower than that in conventional double layers greenhouse at the same outside temperature condition due to air leakage through the gap of roof vent. The overall heat transfer coefficients acquired by experiment that was performed in single layer and conventional double layers greenhouses were close to those obtained from model experiment. Even though the PPF transmittance of air inflated double layers greenhouse was lower than that of single layer greenhouse, which was greater than that of conventional double layers greenhouse. The quantity of condensation water on covering surface of single layer greenhouse was greater than that of air inflated double layers greenhouse due to lower covering surface temperature.