• 제목/요약/키워드: surface changes

검색결과 5,018건 처리시간 0.035초

LPG 폭발사고 예방을 위한 Maghemite의 영향 (Effects of the Maghemite for Explosive accident Prevention to Liquefied Petroleum Gas)

  • 박영구
    • 한국안전학회지
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    • 제11권2호
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    • pp.67-78
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    • 1996
  • Gas sensing element, $\gamma-Fe_2O_3$was synthesized by dehydration, reduction, and oxidation of $$${\gamma}$-FeOOH, which was synthesized with $FeSO_4\;{\cdot}\;7H_2O$ and NaOH. They were produced as a bulk-type, a thick film-type. Then, their responses and mechanisms of response to the gas of liquefied-petroleum were studied. The qualities of gas sensing elements are decided by the structure and the relative surface area. In the process of $\alpha-FeOOH $synthesis, the effects of reaction conditions as the equivalent ratio, on the structure and the relative surface area of gas sensing element were observed. The changes of the structure were measured with XRD, SEM, TG-DTA and BET. The resistance changes of the synthesized gas sensor in the air were measured. The response ratio were also measured for the changes of working temperature and gas concentration. As a result of analysis with XRD, it was confirmed that the the best conditions for the synthesis of $\alpha -FeOOH$ were equivalent ratio 0.65. The thick film-type element of $\gamma-Fe_2O_3$responded more quickly than the bulk-type did. The structure and the relative surface area of the $\alpha-FeOOH $were confirmed as the important factors deciding gas response charcteristics.

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기후변화 대응 건축물 기화냉각시스템 적용에 따른 외부 열환경 변화 연구 (Changes in the External Heat Environment of Building Evaporative Cooling Systems in Response to Climate Change)

  • 윤용한;권기욱
    • 한국환경과학회지
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    • 제27권12호
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    • pp.1261-1269
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    • 2018
  • The purpose of this study was to investigate changes in the external thermal environment, following the application of evaporative cooling systems in buildings, in response to climate change. In order to verify changes in the external thermal environment, a T-test was performed on the microclimate, Thermal Comfort Index (TCI), and building surface temperature. Differences in microclimate, following the application of the evaporative cooling system in the building, were significant in terms of temperature and relative humidity. In particular, temperature decreased by more than 7% when the evaporative cooling system was applied. According to the results of the Thermal Comfort Index analysis, the Wet-Bulb Globe Temperature (WBGT) was below the limit of outdoor activities, indicating that outdoor activities were possible. The Universal Thermal Climate Index (UTCI) values were within the very strong heat stress range when the evaporative cooling system was not applied, When the system was applied, the UTCI values were within the strong heat stress range, indicating that they were lowered by one level. The building surface temperature decreased by ~10% or more when the evaporative cooling system was applied, compared to when it was not applied. Finally, the outside surface temperature of the building decreased by ~12% or more when the system was applied, compared to when it was not applied. We conclude that the energy saving effect of the building was significant.

Glazing 횟수가 전장지르코니아에 미치는 굴곡강도와 표면 미세구조의 변화 (A study of the changes in the strength and microstructure of the zirconia crown surface by the glazing number)

  • 오선미
    • 대한치과기공학회지
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    • 제43권2호
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    • pp.35-41
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    • 2021
  • Purpose: This study aimed to investigate the flexural strength and surface microstructure of the zirconia crown according to the number of glazing zirconia prostheses. Methods: The specimens were made as follows. A specimen without glazing: 1ea, first glazed specimens (group B): 10ea, second glazed specimens (group C): 10ea, third glazed specimens (group D): 10ea. Three-point measuring strength equipment and electron microscopes were used for strength measurement and microstructure observation. As for statistical analysis, one-way ANOVA and t-test (level of significance level=5%) were used to determine the difference in the change in flexural strength according to the number of glazing zirconia prostheses. Results: ANOVA analysis of groups B (1st glazing), C (2nd glazing), and D (3rd glazing) revealed that the change in strength between the groups is statistically significant (p=0.023). The Mann-Whitney test for each group revealed that the difference in flexural strength between groups B and C was not statistically significant (z=-0.302, p=0.762) while that between groups C and D was statistically significant (z=-0.257, p=0.01). Microstructure observation revealed 3 changes in the microstructure of the surface of the glaze powder were observed. Conclusion: According to the number of glazing zirconia prostheses, it was found that the difference in strength between groups was statistically significant, and changes in the microstructure were observed.

북극진동과 한반도 지표기온 관계의 장기변동성 (Decadal Changes in the Relationship between Arctic Oscillation and Surface Air Temperature over Korea)

  • 전예준;송강현;손석우
    • 대기
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    • 제31권1호
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    • pp.61-71
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    • 2021
  • The relationship between the Arctic Oscillation (AO) and surface air temperature (SAT) over Korea is re-examined using the long-term observation and reanalysis datasets for the period of December 1958 to February 2020. Over the entire period, Korean SAT is positively correlated with the AO index with a statistically significant correlation coefficient, greater than 0.4, only in the boreal winter. It is found that this correlation is not static but changes on the decadal time scale. While the 15-year moving correlations are as high as 0.6 in 1980s and 1990s, they are smaller than 0.3 in the other decades. It is revealed that this decadal variation is partly due to the AO structure change over the North Pacific. In the period of 1980s-1990s, the AO-related sea level pressure fluctuation is strong and well defined over the western North Pacific and the related temperature advection effectively changes the winter SAT over Korea. In the other periods, the AO-related circulation anomaly is either weak or mostly confined within the central North Pacific. This result suggests that Korean SAT-AO index relationship, which becomes insignificant in recent decades is highly dependent on mean flow change in the North Pacific.

Investigation on nanoadhesive bonding of plasma modified titanium for aerospace application

  • Ahmed, Sabbir;Chakrabarty, Debabrata;Mukherjee, Subroto;Joseph, Alphonsa;Jhala, Ghanshyam;Bhowmik, Shantanu
    • Advances in aircraft and spacecraft science
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    • 제1권1호
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    • pp.1-14
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    • 2014
  • Physico-chemical changes of the plasma modified titanium alloy [Ti-6Al-4V] surface were studied with respect to their crystallographic changes by X-Ray Diffraction (XRD) and Scanning Electron Microscope (SEM).The plasma-treatment of surface was carried out to enhance adhesion of high performance nano reinforced epoxy adhesive, a phenomenon that was manifested in subsequent experimental results. The enhancement of adhesion as a consequence of improved spreading and wetting on metal surface was studied by contact angle (sessile drop method) and surface energy determination, which shows a distinct increase in polar component of surface energy. The synergism in bond strength was established by analyzing the lap-shear strength of titanium laminate. The extent of enhancement in thermal stability of the dispersed nanosilica particles reinforced epoxy adhesive was studied by Thermo Gravimetric Analysis (TGA), which shows an increase in onset of degradation and high amount of residuals at the high temperature range under study. The fractured surfaces of the joint were examined by Scanning electron microscope (SEM).

치수강의 가령적 변화에 의한 연령추정 - 면적시수에 의하여 - (An Estimation of Age Bases on the Changes in the Human Dental Cavity Caused by Increase in Age (By Surface Index of Pulp Cavity))

  • 정의태;김종열
    • Journal of Oral Medicine and Pain
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    • 제6권1호
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    • pp.101-110
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    • 1981
  • For the purpose of an estimation of age based on the changes in the human dental cavity caused by increase in age, 1,208 extracted teeth in the parts from central incisors and lateral incisors and lateral incisors to second premolars of upper and lower, right and left side were evaluated and analized all of surface index of pulp cavity. The results are as follows : 1. The surface index of pulp caxities of upper and lower, central and lateral incisors, and tend to decrease regularly as the age increase. So above teeth are more applicable to age estimation than canine and premolars. 2 For the purpose of age estimation by surface index of pulp cavity of central and lateral incisor, linear equations are as follows. Upper central incisor: X=(16.301-Y)/0.12 Upper lateral incisor: X=(16.620-Y)/0.11 Lower central incisor: X=(20.963-Y)/0.16 X=Age Y=Surface index of pulp cavity Correlation coefficient between chronologic age and estimated age is 0.699 3.The least error(3.3 yrs of age)reveals in 41-45 age group, which shows the highest possibility of estimation of age. The highest error(4.1 yrs of age)reveals in 61-65 age group and 56-60 age group.

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The Electrochemical Characteristics of Surface-modified Carbonaceous Materials by tin Oxides and Copper for Lithium Secondary Batteries

  • Lee, Joong-Kee;Ryu, D.H.;Shul, Y.G.;Cho, B.W.;Park, D.
    • Carbon letters
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    • 제1권3_4호
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    • pp.170-177
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    • 2001
  • Lithium intercalated carbon (LIC) are basically employed as an anode for currently commercialized lithium secondary batteries. However, there are still strong interests in modifying carbon surface of active materials of the anode because the amount of irreversible capacity, charge-discharge capacity and high rate capability are largely determined by the surface conditions of the carbon. In this study, the carbonaceous materials were coated with tin oxide and copper by fluidized-bed chemical vapor deposition (CVD) method and their coating effects on electrochemical characteristics were investigated. The electrode which coated with tin oxides gave the higher capacity than that of raw material. Their capacity decreased with the progress of cycling possibly due to severe volume changes. However, the cyclability was improved by coating with copper on the surface of the tin oxides coated carbonaceous materials, which plays an important role as an inactive matrix buffering volume changes. An impedance on passivation film was decreased as tin oxides contents and it resulted in the higher capacity.

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한중간 해상에서 육상으로 화물운송전환수요의 추정 : 동북 3성 지역을 중심으로 (Estimations of modal shift from maritime and air transport to surface transport between China and South Korea : focusing on China's three northeast provinces.)

  • 홍성욱;이순철
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2005년도 춘계학술대회 논문집
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    • pp.1125-1131
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    • 2005
  • This study is based on the assumption of surface transport linkages between Korea and China. Active economic cooperation between South Korea and North Korea are expected within the near future and Russia and China have interested in the land transport linkages in Korean peninsula. How much freight demands between the two countries that has been mainly dependent on air and sea transportation so far may convert the transport mode to surface transportation are estimated. Particularly, freight demands between South Korea and China's three northeast provinces are focused. The sensitivity analysis depends on transport time and transport cost changes is included. The modal shifts is estimated to be more sensitive to the changes in transport costs than those in transport time, suggesting the importance of transport costs of rail and road. Despite the dearth of data on the surface transport operation in North Korea, the attempts made in this study to estimate the demand conversion are hope to provide reference points for potential effects of the rail and road transport connections between China and the Korea peninsula before our discussions expand to the establishment of freight transport network of the northest Asia and, moreover, the Eurasian continent.

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레이저 쇼크 피닝에 의한 2205 듀플렉스 스테인리스강의 표면 경도 향상과 표면 변화 관찰 (Improvement of Surface Hardness of 2205 Duplex Stainless Steel by Laser Shock Peening and Observations of Surface Changes)

  • 임현태;정회민;김필규;정성호
    • 한국레이저가공학회지
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    • 제14권1호
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    • pp.19-24
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    • 2011
  • This work reports the results for laser shock peening of duplex stainless steel (22% Chromium - 5% Nickel) using a pulsed Nd:YAG laser (wavelength = 532nm, pulse width = 8ns). for the application to high-capacity pumps for seawater desalination plants. By properly selecting the process parameters such as laser intensity of 10GW/$cm^2$, laser pulse density of 75pulse/$mm^2$, and $100{\mu}m$ thick aluminum foil as an absorbent coating layer, the surface hardness of duplex stainless steel could be enhanced by 26%, from 256HV to 323HV with little changes in surface morphology and roughness. The depth of laser shock peened layer was measured to be around 2mm. The large enhancement of surface hardness is considered to have high practical importance in minimizing abrasive and corrosive deterioration of pump parts.

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황색종 잎담배의 엽면지질 성분 조성 및 건조중 변화 (Composition of Leaf Surface Lipid in Flue-cured Tobacco and Their Changes during Flue-curing)

  • 지상운;김도연;이문용;김영희;신승구
    • 한국연초학회지
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    • 제19권1호
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    • pp.57-63
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    • 1997
  • The composition of leaf surface lipid in Flue-cured tobacco and their changes during curing was investigated. The flue-cured variety, Nicotiana tabacum cv. NC 82 was cultivated at Eumsung experiment station in 1996. The samples of riced leaves with different stalk Position(Lugs, Cutter, Leaf and Tips) and different curing stage at half yellowing(24hr), yellowing(48 hr) , color axing(72 hr), midrib drying(96 hr) and cured(120 hr) were collected for analysis of leaf surface lipid. $\alpha$ - and $\beta$ - 4, 8, 13-Duvatriene-1, 3-diol($\alpha$, $\beta$-DVT) were major components in leaf surface lipid extracted with methylene chloride and sugar ester was detected slightly DVT content was increased with ascending stalk position, but increasing trend of total hydrocarbon was not observed. While DVT was decreased throughout curing of tobacco leaves, hydrocarbon content did not show significant change during curing process. Twenty-two duvane compounds were detected by capillary GC in duvane fraction isolated from leaf surface lipid and of which 11 compounds were identified by GC-MS. These compounds were decreased with curing in all stalk position.

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