• 제목/요약/키워드: surface black layer

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Fabrication of surface-enhanced Raman scattering substrate using black silicon layer manufactured through reactive ion etching (RIE 공정으로 제조된 블랙 실리콘(Black Silicon) 층을 사용한 표면 증강 라만 산란 기판 제작)

  • Kim, Hyeong Ju;Kim, Bonghwan;Lee, Dongin;Lee, Bong-Hee;Cho, Chanseob
    • Journal of Sensor Science and Technology
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    • v.30 no.4
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    • pp.267-272
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    • 2021
  • In this study, Ag was deposited to investigate its applicability as a surface-enhanced Raman scattering substrate after forming a grass-type black silicon structure through maskless reactive ion etching. Grass-structured black silicon with heights of 2 - 7 ㎛ was formed at radio-frequency (RF) power of 150 - 170 W. The process pressure was 250 mTorr, the O2/SF6 gas ratio was 15/37.5, and the processing time was 10 - 20 min. When the processing time was increased by more than 20 min, the self-masking of SixOyFz did not occur, and the black silicon structure was therefore not formed. Raman response characteristics were measured based on the Ag thickness deposited on a black silicon substrate. As the Ag thickness increased, the characteristic peak intensity increased. When the Ag thickness deposited on the black silicon substrate increased from 40 to 80 nm, the Raman response intensity at a Raman wavelength of 1507 / cm increased from 8.2 × 103 to 25 × 103 cps. When the Ag thickness was 150 nm, the increase declined to 30 × 103 cps and showed a saturation tendency. When the RF power increased from 150 to 170 W, the response intensity at a 1507/cm Raman wavelength slightly increased from 30 × 103 to 33 × 103 cps. However, when the RF power was 200 W, the Raman response intensity decreased significantly to 6.2 × 103 cps.

Development of High Functional Black Resin Coated Electrogalvanized Steel Sheet for Digital TV Panel

  • Jo, Du-Hwan;Kwon, Moonjae;Lee, Jae-Hwa;Kang, Hee-Seung;Jung, Yong-Gyun;Song, Yon-Kyun;Jung, Min-Hwan;Cho, Soo-Hyoun;Cho, Yeong-Bong;Cho, Myoung-Rae;Cho, Byoung-Chon;Lim, Kwangsoo;Seon, Pan-Woo;Han, Hyeon-Soop;Jeong, Hwon-Woo;Lee, Jae-Ryung;Kim, Jong-Sang
    • Corrosion Science and Technology
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    • v.12 no.1
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    • pp.1-6
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    • 2013
  • Recently Digital TV industry has drastically been moving the illuminating system, which causes an obvious product change from PDP and LCD to LED model to provide high-definition image. Due to strong competition in the digital industry, TV manufacturers make a great efforts to reduce production cost by using low-priced materials such as steels instead of aluminum and plastic etc. In this paper we have developed a new low-priced electrogalvanized steel sheet, which has a black resin composite layer, to substitute conventional high-priced PCM steel and plastic mold for rear cover panel in the digital TV. The black resin composite was prepared by mechanical dispersion of the mixture solution that consists of high solid polyester resin, melamine hardener, black pigment, micronized silica paste, polyacrylate texturing particle and miscellaneous additives. The composite solution was coated on the steel sheet using roll coater followed by induction furnace curing and cooling. Although the coated layer has a half thickness compared to the conventional PCM steels having $23{\mu}m$ thickness, it exhibits excellent quality for the usage of rear cover panel. The new steel sheet was applied to test products to get quality certification from worldwide electronic appliance customers. Detailed discussion provides in this paper including preparation of composite solution, roll coating technology, induction curing technology and quality evaluation from customers.

Study on the new development of combined electrochemical processes using pulse current (마이크로 펄스 전해 복합가공에 관한 연구)

  • 박정우;이은상;문영훈
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.05a
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    • pp.918-921
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    • 2002
  • Some investigators who have tried to achieve the highly smooth surface finish using electrochemical processes have reported that high current density produced lustrous surfaces while the opposite conditions produced a passive layer and had a tendency to produce a black surface. However, processing at a low current density may produce a non-lustrous surface but the improvement of dimensional accuracy of the surface is significant. The surface with pulse process was a bit more lustrous than with continuous current but the black passive layer still could be found at grooved surface. There are two ways to achieve highly smooth surface finish. One is brushing it with a brush the other is electrochemical machining (ECM) with high current. The former method is the most common polishing practice, but not only may the surface obtained differ from operator to operator, but precision smooth surface on micro grooves are difficult to obtain. The latter one recently has been used to produce a highly smooth surface after EDM process. However, the material removal rate in ECM with high current is relatively high. Hence the original shape of the micro grooves, which was formed by electrochemical micro-machining (EMM) process, may be destroyed. In this study, an electrochemical polishing process using pulse current is adopted as a possible alternative process when micro grooves formed by EMM process should be polished. Mirror-like micro grooves with lustrous and smooth surface can be produced electrochemically with pulse current because the voltage and current used can be lower than the case of continuous current. This study will discuss the accurate control of physical and electrical conditions so as to achieve mirror-like micro grooves with lustrous and smooth surface without destroying the original shape of micro grooves.

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MULTISENSOR SATELLITE MONITORING OF OIL POLLUTION IN NORTHEASTERN COASTAL ZONE OF THE BLACK SEA

  • Shcherbak, Svetlana;Lavrova, Olga;Mytyagina, Marina;Bocharova, Tatiana;Krovotyntsev, Vladimir;Ostrovskiy, Alexander
    • Proceedings of the KSRS Conference
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    • v.2
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    • pp.989-992
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    • 2006
  • The new approach to the problem of oil spill detection consisting in combined use of all available quasiconcurrent satellite information (AVHRR NOAA, TOPEX/Poseidon, Jason-1, MODIS Terra/Aqua, QuikSCAT) is suggested. We present the results of the application of the proposed approach to the operational monitoring of seawater condition and pollution in the coastal zone of northeastern Black Sea conducted in 2006. This monitoring is based on daily receiving, processing and analysis of data different in nature (microwave radar images, optical and infrared data), resolution and surface coverage. These data allow us to retrieve information on seawater pollution, sea surface and air-sea boundary layer conditions, seawater temperature and suspended matter distributions, chlorophyll a concentration, mesoscale water dynamics, near-surface wind and surface wave fields. The focus is on coastal seawater circulation mechanisms and their impact on the evolution of pollutants.

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Machining of Micro Grooves using Hybrid Electrochemical Processes with Voltage Pulses (펄스 전기화학 복합가공기술을 적용한 미세 그루브 가공)

  • 이은상;박정우;문영훈
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.9
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    • pp.32-39
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    • 2003
  • Pulse electrochemical machining process with high or low current density may produce a non-lustrous surface on workpiece surface. The usual polishing process to remove a black layer from the surface has been hand polish the part. But the milli-to-micro meter scale structure formed by the electrochemical machining process may be destroyed while polishing process. The application of ultra short voltage pulses based on the analysis of electrical double layer charging process allows high resolution electrochemical machining and polishing. This technique was based on the specific polarization resistance from the comparison of ideal and experimental potential variation during short voltage pulses.

Heat generation characteristics of the heating mortar according to repeated electricity supply (반복전기공급에 따른 발열모르타르의 발열 특성)

  • Kim, Young-Min;Lim, Chang-Min;Gwon, Hyeon-U;Lee, Gun-cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.170-171
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    • 2022
  • In recent years, due to the occurrence of traffic accidents caused by black ice in winter, the number of personal injuries is increasing rapidly. Black ice is a phenomenon that occurs like a thin layer of ice on the road surface. Accordingly, many developments of heat-generating concrete are being developed to remove ice by increasing the temperature by supplying constant electricity to places where black ice is likely to occur. These heating elements are being developed by mixing a conductive material represented by carbon nanotubes with concrete. However, research up to now has been focused on efficient temperature rise and derivation of the optimum mixing ratio, and the evaluation of maintaining heat generation performance during continuous repetition is insufficient. Therefore, in this study, a heating test specimen was manufactured and 50V power was repeatedly supplied to evaluate the heating characteristics.

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Characteristics and Origin of Salts in the Black Surface Layer of Stone Monuments (석조기념물 흑색표면층에 있는 염의 특성과 기원)

  • Do, Jinyoung
    • Journal of Conservation Science
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    • v.12 no.1 s.15
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    • pp.15-25
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    • 2003
  • It is well known that the salt in stoneworks impact on damage of stone by various methods. Various kind of salt is detected in high content in the black surface layer of stone monuments and it is required about origin and roles of salts on blackening to considerate. In this study have been investigated the characteristics of salt in the black crust of sandstone and limestone which used in historical monuments in Berlin, Germany. Salt was analyzed for cation by Atomic Absorption and Atomic Emission Spectroscopy and for anion by ion Chromatograph. The representative ions are $Ca^{2+}\;and\;SO_4^{-2}$ in all samples and the most obvious combinations was proved in calcium sulfate by statistical methods. Because gypsum was detected by X-ray diffraction analyses in the black crusts, this calcium sulfate was confirmed by 2 hydrate type. The probable origin of Ca is air particle in atmosphere around sandstone and calcite in mother rock in limestone, and that of S is polluted air and mortar which used as conservation works.

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New Ramp-reset Waveform for Fast Addressing in AC-PDPs

  • Kim, Oe-Dong;Ahn, Byoung-Nam;Choi, Kwang-Yeol;Yoo, Eun-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.643-646
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    • 2005
  • We present new ramp-reset waveforms that realize fast addressing in AC-PDPs. These waveforms distort the distribution of wall charges on the surface of a phosphor layer: hence, the enhanced electric field helps to ignite a cell faster. They also reduce the black luminance: the divide of erasing ramp down discharges into two parts, i.e. a surface discharge and a vertical discharge, makes lower luminance.

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Effect of crystallinity on the electrochemical properties of carbon black electrodes

  • Yoo, Hye-Min;Heo, Gun-Young;Park, Soo-Jin
    • Carbon letters
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    • v.12 no.4
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    • pp.252-255
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    • 2011
  • Carbon-based electric double-layer capacitors are being evaluated as potential energy-storage devices in an expanding number of applications. In this study, samples of carbon black (CB) treated at different temperatures ranging from $650^{\circ}C$ to $1100^{\circ}C$ were used as electrodes to improve the efficiency of a capacitor. The surface properties of the heat-treated CB samples were characterized by X-ray photoelectron spectroscopy and X-ray diffraction. The effect of the heat-treatment temperature on the electrochemical behaviors was investigated by cyclic voltammetry and in galvanostatic charge-discharge experiments. The experimental results showed that the crystallinity of the CBs increased as the heat-treatment temperature increased. In addition, the specific capacitance of the CBs was found to increase with the increase in the heat-treatment temperature. The maximum specific capacitance was 165 $F{\cdot}g-1$ for the CB sample treated at $1000^{\circ}C$.

Properties of Dye Sensitized Solar Cells with Adding Nano Carbon Black into Blocking Layer

  • Kim, Kwangbae;Noh, Yunyoung;Song, Ohsung
    • Journal of the Korean Ceramic Society
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    • v.52 no.4
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    • pp.294-298
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    • 2015
  • Blocking layers with nano carbon blacks (NCBs) were prepared by adding 0.0 ~ 0.5 wt% NCBs to the $TiO_2$ blocking layer. Then, dye sensitized solar cells (DSSCs) were fabricated with a $0.45cm^2$ active area. TEM and micro-Raman spectroscopy were used to characterize the microstructure and phases of the NCBs, respectively. Optical microscopy and AFM were used to analyze the microstructure of the $TiO_2$ blocking layer with NCBs. UV-VIS-NIS spectroscopy was used to determine the band gap of the $TiO_2$ blocking layer with NCBs. A solar simulator and potentiostat were used to determine the photovoltaic properties and impedance of DSSCs with NCBs. The energy conversion efficiency (ECE) increased from 3.53 to 6.20 % when the NCB content increased from 0.0 to 0.3 wt%. This indicates that the effective surface area and electron mobility increased in the $TiO_2$ blocking layer with NCBs. However, the ECE decreased when the NCB content was increased to over 0.4 wt%. This change occurred because the effective electron transport area decreased with the addition of excessive NCBs to the $TiO_2$ blocking layer. The results of this study suggest that the ECE of DSSCs can be enhanced by adding the appropriate amount of NCBs to the $TiO_2$ blocking layer.