• Title/Summary/Keyword: surface analyses

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Surface Photooxidation of Poly(butylene terephthalate) Films by UV/Ozone Irradiation (자외선/오존 조사에 의한 Poly(butylene terephthalate) 필름의 표면 광산화)

  • Joo, Jin-Woo;Jang, Jinho
    • Textile Coloration and Finishing
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    • v.28 no.2
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    • pp.63-69
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    • 2016
  • Poly(butylene terephthalate)(PBT) surface was modified by UV/ozone irradiation and the effect of UV energy on the surface properties of the irradiated PBT films were characterized by the reflectance, surface roughness, contact angles, ESCA, and ATR analyses of the film surface. The surface reflectance, at the short wavelength of visible spectrum of particularly 400nm, decreased with increasing UV energy. And the irradiation roughened the film surface uniformly in the nano scale. The maximum surface roughness increased from 110nm for the unirradiated sample to 303nm at the UV energy of $10.6J/cm^2$. The surface energy of PBT film increased from $50.5mJ/m^2$ for the unirradiated PBT to $58.8mJ/m^2$ at the irradiation of $21.2J/cm^2$. The improvement in hydrophilicity was caused by the introduction of polar groups containing oxygens such as C-O and C=O bonds resulting in higher $O_{1s}/C_{1s}$. The increased dyeability of the modified film to cationic dyes may be resulted from the photochemically introduced anionic and dipolar dyeing sites on the PBT films surfaces.

Consideration of NDVI and Surface Temperature Calculation from Satellite Imagery in Urban Areas: A Case Study for Gumi, Korea

  • Bhang, Kon Joon;Lee, Jin-Duk
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.35 no.1
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    • pp.23-30
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    • 2017
  • NDVI (Normalized Difference Vegetation Index) plays an important role in surface land cover classification and LST (Land Surface Temperature Extraction). Its characteristics do not full carry the information of the surface cover typically in urban areas even though it is widely used in analyses in urban areas as well as in vegetation. However, abnormal NDVI values are frequently found in urban areas. We, therefore, examined NDVI values on whether NDVI is appropriate for LST and whether there are considerations in NDVI analysis typically in urban areas because NDVI is strongly related to the surface emissivity calculation. For the study, we observed the influence of the surface settings (i.e., geometric shape and color) on NDVI values in urban area and transition features between three land cover types, vegetation, urban materials, and water. Interestingly, there were many abnormal NDVI values systematically derived by the surface settings and they might influence on NDVI and eventually LST. Also, there were distinguishable transitions based on the mixture of three surface materials. A transition scenario was described that there are three transition types of mixture (urban material-vegetation, urban material-water, and vegetation-water) based on the relationship of NDVI and LST even though they are widely distributed.

Electrocatalytic activity of carbon-supported near-surface alloys (NSAs) for electrode reaction of fuel cell (연료전지 전극 반응을 위한 카본 담지 표면 합금의 전기촉매 활성)

  • Park, In-Su;Sung, Yung-Eun
    • New & Renewable Energy
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    • v.2 no.4 s.8
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    • pp.64-69
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    • 2006
  • There is a worldwide interest in the development and commercialization of polymer electrolyte membrane fuel cells [PEMFCs] for vehicular and stationary applications. One of the major objectives is the reduction of loaded electrode materials, which is comprise of the Pt-based noble metals. In this paper, a novel chemical strategy is described for the preparation and characterization of carbon-supported and surface-alloys, which were prepared by using a successive reduction process. After preparing Au colloid nanoparticles, the supporting of Au colloid nanoparticles occurred spontaneously in the carbon black-dispersed aqueous solution. Then nano-scaled active materials were formed on the surface of carbon-supported Au nanoparticles. The structural and electrochemical analyses indicate that the active materials were deposited on the surface of Au nanoparticles selectively and that an alloying process occurred during the successive reducing process. The carbon-supported & surface-alloys showed the higher electrocatalytic activity than those of the particle-alloys and commercial one [Johnson-Matthey] for the reaction of methanol and formic acid oxidation. The increased electrocatalytic activity might be attributed to the effective surface structure of surface-alloys, which have a high utilization of active materials for the surface reaction of electrode.

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Axial frequency analysis of axially functionally graded Love-Bishop nanorods using surface elasticity theory

  • Nazemnezhad, Reza;Shokrollahi, Hassan
    • Steel and Composite Structures
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    • v.42 no.5
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    • pp.699-710
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    • 2022
  • This work presents a comprehensive study on the surface energy effect on the axial frequency analyses of AFGM nanorods in cylindrical coordinates. The AFGM nanorods are considered to be thin, relatively thick, and thick. In thin nanorods, effects of the inertia of lateral motions and the shear stiffness are ignored; in relatively thick nanorods, only the first one is considered; and in thick nanorods, both of them are considered in the kinetic energy and the strain energy of the nanorod, respectively. The surface elasticity theory which includes three surface parameters called surface density, surface stress, and surface Lame constants, is implemented to consider the size effect. The power-law form is considered for variation of the material properties through the axial direction. Hamilton's principle is used to derive the governing equations and boundary conditions. Due to considering the surface stress, the governing equation and boundary condition become inhomogeneous. After homogenization of them using an appropriate change of variable, axial natural frequencies are calculated implementing harmonic differential quadrature (HDQ) method. Comprehensive results including effects of geometric parameters and various material properties are presented for a wide range of boundary condition types. It is believed that this study is a comprehensive one that can help posterities for design and manufacturing of nano-electro-mechanical systems.

Fluid-structure interaction analysis of deformation of sail of 30-foot yacht

  • Bak, Sera;Yoo, Jaehoon;Song, Chang Yong
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.5 no.2
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    • pp.263-276
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    • 2013
  • Most yacht sails are made of thin fabric, and they have a cambered shape to generate lift force; however, their shape can be easily deformed by wind pressure. Deformation of the sail shape changes the flow characteristics over the sail, which in turn further deforms the sail shape. Therefore, fluid-structure interaction (FSI) analysis is applied for the precise evaluation or optimization of the sail design. In this study, fluid flow analyses are performed for the main sail of a 30-foot yacht, and the results are applied to loading conditions for structural analyses. By applying the supporting forces from the rig, such as the mast and boom-end outhaul, as boundary conditions for structural analysis, the deformed sail shape is identified. Both the flow analyses and the structural analyses are iteratively carried out for the deformed sail shape. A comparison of the flow characteristics and surface pressures over the deformed sail shape with those over the initial shape shows that a considerable difference exists between the two and that FSI analysis is suitable for application to sail design.

A POSTEROANTERIOR ROENTGENOCEPHALOMETRIC STUDY OF SKELETAL CRANIOFACIAL ASYMMETRIC PATIENTS (골격형 안면 비대칭 부정교합자에 대한 정모두부방사선 계측학적 연구)

  • Cheon, Ok-Jin;Suhr, Cheong-Hoon
    • The korean journal of orthodontics
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    • v.20 no.3 s.32
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    • pp.565-581
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    • 1990
  • This study was undertaken to investigate the degree of asymmetry in each part of the head in skeletal craniofacial asymmetric patients, and secondarily to determine the nature of difference existed between asymmetric patients and normal persons. The subjects consisted of 49 asymmetric adult patients and 52 normal adults, and the average ages were 21 years 5 months and 23 years 5 months, respectively. The computerized analyses of 33 linear measurements, 12 angular measurements, and 8 surface areas from posteroanterior cephalometric radiograph were carried out. The conclusions were as follows; 1. Asymmetry was a common finding in both normal and asymmetric group. 2. When the analyses were undertaken after the head was divided into 3 parts anteroposteriorly and superoinferiorly in the asymmetric patients, there were significant asymmetries in all parts excepts in the cranial base region. 3. When the analyses were undertaken after the head was divided into respective 3 parts anteroposteriorly in the asymmetric patients, the more posterior part showed relative stability than the more anterior part. 4. When the analyses were undertaken after the head was divided into 3 parts superoinferiorly in the asymmetric patients, the more superior part showed relative stability than the more inferior part. 5. Twelve variables indicating asymmetry were selected and the highest ranked variable was Me-Mid-sagittal reference line.

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Dynamic interaction effects of buried structures on seismic response of surface structures

  • Sisman, Rafet;Ayvaz, Yusuf
    • Earthquakes and Structures
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    • v.19 no.1
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    • pp.1-16
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    • 2020
  • This study presents an investigation of the dynamic interactions between a surface structure lying on two different soil deposits and a square-shaped buried structure embedded in the soil. To this end, a large number of numerical models are generated by using a well-known Finite Element Method software, i.e., OpenSEES. The interaction phenomenon is assumed to be affected by six different parameters. In the parametric study, these parameters are assumed to have various values in accordance with the engineering practices. A total of 1620 possible combinations of the parameter values are addressed in this study. 30 different numerical models are also generated as the 'free-field cases' to set a reference. The surface structure drift and acceleration amplifications are used as a measure to evaluate the dynamic interactions. The response (i.e., drifts and accelerations) amplifications are calculated as the ratio of the maximum surface structure response in any 'case' to the maximum surface structure response in corresponding free-field case. Variation of the response amplifications with any of the investigated parameters is addressed in this paper. The results obtained from the numerical analyses clearly reveal that the presence of a buried structure in the vicinity of a surface structure can cause both amplification and de-amplification of the surface structure responses, depending on the case parameters.

Electrocatalytic activity of Carbon-supported near-surface alloys (NSAs) for Electode reaction of Fuel cell (연료전지 전극 반응을 위한 카본 담지 표면 합금의 전기촉매 활성)

  • Park, In-Su;Lee, Kug-Seung;Choi, Baeck-Beom;Sung, Yung-Eun
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.316-319
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    • 2006
  • There is a worldwide interest in the development and commercialization of Polymer Electrolyte Membrane Fuel Cells (PEMFCs) for vehicular and stationary applications. One of the major objectives is the reduction of loaded electrode materials, which is comprise of the Pt-based noble metals. In this paper, a novel chemical strategy is described for the preparation and characterization of carbon-supported and surface-alloys, which were prepared by using a successive reduction process. After preparing Au colloid nanoparticles, the deposition of Au colloid nanoparticles occurred spontaneously in the carbon black-dispersed aqueous solution. Then nano-scaled active materials were formed on the surface of carbon-supported Au nanoparticles. The structural and electrochemical analyses indicate that the active materials were deposited on the surface of Au nanoparticles selectively and that an at toying process occurred during the successive reducing process The carbon-supported & surface-alloys showed the higher electrocatalytic activity than those of the particle-alloys and commercial one (Johnson-Matthey) for the reaction of methanol and formic acid oxidation. The increased electrocatalytic activity might be attributed to the effective surface structure of surface-alloys, which have a high utilization of active materials for the surface reaction of electrode.

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Quantitative Analysis of Roughness of Powder Surface Using Three-Dimensional Laser Profiler and its Effect on Green Strength of Powder Compacts (분말 표면 조도의 3차원 레이저 분석기를 이용한 정량화와 압분성형체 강도에 미치는 영향 분석)

  • Lee, Dong-Jun;Yoon, Eun-Yoo;Kim, Ha-Neul;Kang, Hee-Soo;Lee, Eon-Sik;Kim, Hyoung-Seop
    • Journal of Powder Materials
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    • v.18 no.5
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    • pp.406-410
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    • 2011
  • Green strength is an important property of powders since high green strength guarantees easy and safe handling before sintering. The green strength of a powder compact is related to mainly mechanical and surface characters, governed by interlocking of the particles. In this study, the effect of powder surface roughness on the green strength of iron powders was investigated using a transverse rupture test. Three-dimensional laser profiler was employed for quantitative analyses of the surface roughness. Two different surface conditions, i.e. surface roughness, of powders were compared. The powders having rough surfaces show higher green strength than the round surface powders since higher roughness leads increasing interlocked area between the contacting powders.

Effects of Surface Pretreatment on Deposition and Adhesion of Electrophoretic Paint on AZ31 Mg Alloy

  • Nguyen, Van Phuonga;Moon, Sungmo
    • Journal of Surface Science and Engineering
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    • v.50 no.2
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    • pp.72-84
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    • 2017
  • In this work, electrophoretic paint (E-paint) was deposited on AZ31 Mg alloy after four different surface pretreatments: knife abrading, SiC paper abrading, deionized (DI) water immersion and NaOH immersion. The deposition process of E-paint was studied by analyses of voltage-time and current-time curves, amount of deposited paint, current efficiency and surface oxide film resistance and the adhesion of E-paint was examined by tape test before and after immersion in DI water for 500 h at $40$^{\circ}C$. It was found that the induction time for the deposition, the amount of deposited paint and the current efficiency are inversely proportional to the resistances of surface films prepared by different surface pretreatment methods. The electrophoretic painting showed longer inductance time, larger amount of deposited paint and higher current efficiency on the highly conducting surfaces, such as knife-abraded and SiC-abraded surfaces than on the less conducting surfaces, such as DI water-immersed and NaOH-immersed samples. Excellent adhesion was observed on the E-paintings deposited onto knife-abraded and SiC-abraded AZ31 Mg alloy samplesSiC-abraded AZ31 Mg alloy samples.