• Title/Summary/Keyword: surface aging

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Preparation and Interface Properties of Colloidal Silica (콜로이드 실리카의 제조 및 계면특성)

  • Lee, Han Chul;Kim, Jong Hyub;Chang, Yoon Ho
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.386-390
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    • 2006
  • Colloidal silica which has high surface area and excellent surface properties are chemically stable inorganic materials and used for various applications in industry. Silica sol was prepared from sodium silicate solution by acid neutralization method and ion exchange treatment to remove sodium ions. Through the experimental analysis for controlling factors of particle growth rate, such as temperature, pH, and aging time, the uniform size distribution of silica sol could be obtained. The size distribution and shape of silica sol was measured by TEM and dynamic light scattering method. Zeta potential change and gelling phenomena of silica sol and its rheological properties also investigated.

A Study on the Classification of Type for the Village Community Center (마을회관 유형 분류에 관한 연구)

  • Shin, Young-Sun;Kang, Young-Eun;Oh, Dong-Yop;Jee, Dal-Nim;Im, Seung-Bin
    • Journal of Korean Society of Rural Planning
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    • v.14 no.3
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    • pp.75-87
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    • 2008
  • Changes in society organization of rural villages in our country are caused by aging society and lessening of economic activity population aggravates the economy of rural villages. With this, it joins in with the aging of village community center, the representative center space of the rural village and therefore, it is a point of view where the change is necessary in the size and the side of function. The research which it sees is made on-the-spot inspection and literature investigation compensate in behalf of 25 administrative village community centers led in the object by grasping present status and drew up the layout sketches and plane surface degrees of the village community centers. By referring to the photographs and the topographical maps taken in the spot, it was able to divide the village community centers into side of arrangement, side of plane surface and side of form and managed to seize the characters, problems and improvable directions of each of them. The research result could be used as a guidable provision and be applied in the fundamental research in developing model of village community centers during space planning in the future.

A Study on the Evaluation of Mterial Degradaion for 2.25Cr-1Mo Steel using Ultrasonic Attenuation Characterization

  • Kim, Chung-Soek;Park, Ik-Keun;Park, Un-Su;Kim, Hyun-Mook;Kwun, Sook-In;Byeon, Jai-Won
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2001.10a
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    • pp.319-323
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    • 2001
  • In significant number of energy-related facilities for like thermal power plant or petro-chemical industry, CrMo steels are widely used energy conversion industries. However, these materials undergo precipitation of carbides or intermetallic compounds into grain boundary and change of internal microstructure such as coarsening of precipitation, decrease of solute elements and impurity segregation under more severe service conditions, which results in deterioration of inherent superior material characteristics. In this study, it was verified experimentally the feasibility of the aging degradation evaluation for degraded 2.25Cr-lMo steel specimens prepared by isothermal aging heat treatment at 63$0^{\circ}C$ by high frequency longitudinal ultrasonic and surface SH wave investigating the change of attenuation coefficient analyzed by spectral analysis. Attenuation coefficient had a tendency to increase as degradation proceeded.

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The UV Images and Aging Judgement with Behaviors Caused by Surface Contamination on 22.9[kV] Class Insulators (22.9[kV]급 애자의 표면오염에 의한 자외선 영상과 열화판정)

  • Shong, Kil-Mok;Kim, Young-Seok
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.1
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    • pp.167-174
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    • 2010
  • In this paper, the ultraviolet rays images and aging judgement caused by surface contamination on 22.9[kV] class insulators was defined. UV images represented by the corona discharge are divided 3 types such as sunflower, jellyfish, amoeba and in detail, there are classified the progress mechanism of eight. In the field which is installed the power facilities, immediately, this judgement method can be found out the deteriorated parts of the power facilities. These steps are possible to judge the deterioration of power facilities through reliable data. Hereafter, this study as the diagnostic technology suitable for the sites is used.

Mechanical Properties and Smoothness of Semiconductive Materials(Shield) in Power Cable (전력케이블내 반도전 재료(층)의 기계적 특성 및 평활도에 관한 연구)

  • Yang Jong-Seok;Lee Yong-Sung;Park Dae-Hee;Lee Kyoung-Yong
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.54 no.4
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    • pp.154-160
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    • 2005
  • We have investigated thermal properties showed by changing the content of carbon black which is the component parts of semiconductive shield in underground power transmission cable. Specimens were made of sheet with the nine of those for measurement. Density of specimens was measured by density meter, and then stress-strain of specimens was measured by TENSOMETER 2000. A speed of measurement was 200[mm/min], ranges of stress and strain were 400(Kgf/$cm^2$) and 600[$\%$]. In addition, tests of stress-strain were progressed by aging specimens at air oven. Finally surface profile was shown in order to looking for protrusion of specimens by using smoothness tester. Density was highly measured according to increasing the content of carbon black from this experimental result, and stress was decreased, while strain was increased according to increasing the content of carbon black. And stress-strain were decreased some after aging because of oxidation reaction of chemical defect. Lastly surface of specimens smoothed generally.

A Study on the Breakdown Mechanism of Rotating Machine Insulation

  • Kim, Hee-Gon;Kim, Hee-Soo;Park, Yong-Kwan
    • Journal of Electrical Engineering and information Science
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    • v.2 no.3
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    • pp.71-76
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    • 1997
  • A lot of experiments and analyses have been done to determine the aging mechanism of mica-epoxy composite material used for large generator stator windings in order to estimate remaining life of the generator for last decades. After degrading artificially the mica-epoxy composite material, the surface analysis is performed to analyze breakdown mechanism of insulation in air and hydrogen atmosphere; i) In the case of air atmosphere, it is observed that an aging propagation from conductor to core by partial discharge effect and the formation of cracks between layers is widely carbonized surface. ii) In case of hydrogen atmosphere, the partial discharge effect is reduced by the hydrogen pressure (4kg/$\textrm{cm}^2$). Potassium ions forming a sheet of mica is replaced by hydrogen ions, which can lead to microcracks. It is confirmed that the sizes of crack by SEM analysis are 10∼20[$\mu\textrm{m}$] in length under air, and 1∼5[$\mu\textrm{m}$] in diameter, 10∼50[$\mu\textrm{m}$] in length under hydrogen atmosphere respectively. The breakdown mechanism of sttor winding insulation materials which are composed of mica-epoxy is analyzed by the component of materials with EDS, SEM techniques. We concluded that the postassium ions of mica components are replaced by H\ulcorner, H$_3$O\ulcorner at boundary area of mica-epoxy and/or mica-mica. It is proposed that through these phenomena, the conductive layers of potassium enable creation of voids and cracks due to thermal, mechanical, electrical and environmental stresses.

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The Influence of Weathering Conditions on the Outer Membrane of Biogas with Plasticized PVC : A Study using Non-destructive Tests

  • Kim, Changhwan;Ki, Wootae;Kim, SangMyung;Shin, Jinyong
    • Journal of Surface Science and Engineering
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    • v.47 no.2
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    • pp.57-62
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    • 2014
  • The biogas holder is composed of an outer membrane and an inner membrane which are subject to outdoor exposure and gas exposure respectively. The influence of weathering conditions on the photo-degradation of a biogas holder was investigated. Tests were performed under three different methods - outdoor exposure tests (Seosan, Arizona), accelerated tests (Xenon-are lamp) with the outer-membrane of biogas. Moreover, the changes in the aging process were monitored using color difference, gloss, the contact angle and an optical microscope. Changes in physical properties, such as decrease reduction in gloss, decrease in the contact angle, increase in color difference were observed in the aging process. The comparison between membrane 3B, 4B and membrane 5B under xenon-arc were discussed. Membrane 5B was very sensitive to ultraviolet (UV) ray. There were many difficulties in the outdoor exposure test due to acid rain, dust, and stain resistance.

Metallurgical Reaction Properties between In-15Pb-5Ag Solder and Zu-Ni Surface Finish (In-l5Pb-5Ag 솔더와 Au/Ni 층과의 반응 특성)

  • 이종현;엄용성;최광성;최병석;윤호경;박흥우;문종태
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2002.05a
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    • pp.183-188
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    • 2002
  • With the contact pad consisted of $0.5{\mu}{\textrm}{m}$ $Au/5{\mu}{\textrm}{m}$ Ni/Cu layers on a conventional ball grid array(BGA) substrate, metallurgical reaction properties between the pad and In-15(wt.%)Pb-5Ag solder alloy were studied after reflow and solid aging. In as-reflow condition, thin AuIn$_2$or Ni$_{28}$In$_{72}$ intermetallic layer was formed at the solder/pad interface according to reflow time. Dissolution of the Au layer into the molten solder was remarkably limited in comparison with eutectic Sn-37Pb alloy. After solid aging of 300 hrs, thickness of In-Ni layer increased to about $2{\mu}{\textrm}{m}$ in the both as-reflow case. It was observed that In atoms diffuse through the AuIn$_2$phase to react with underlaying Ni layer. The metallurgical reaction properties between In-l5Pb-7Ag alloy and Au/Ni surface finish were analysed to result in suppression of Au-embrittlement in the solder joints.

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The Cathodoluminance Properties of $Y_2SiO_5$:Ce Blue Phosphor with Surface Coatings ($Y_2SiO_5$:Ce 청색 형광체의 표면 코팅에 따른 음극선 발광특성)

  • 음현중;김성우;이임렬
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.590-593
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    • 1999
  • $Y_2SiO_5$:Ce was considered as blue phosphor for field emission display because it had an excellent resistance against brightness saturation. But unfortunately It hadn't a sufficient brightness to be applied to FED. In this experiment It-$In_2O_3$, MgO and $SiO_2$ were coated onto $Y_2SiO_5$:Ce phosphor in order to improve the cathodoluminance(CL properties. The coating structures were identified to be the crystalline phases of $In_2O_3$ and MgO respectively. They had fine particle-like shape and were distributed on the surface of $Y_2SiO_5$:Ce phosphor. It was found that the CL efficiency of $Y_2SiO_5$:Ce phosphors were decreased after coatings with In20:j and MgO in voltage range from 500 V to 5 kV. But the brightness of $Y_2SiO_5$:Ce phosphor was increased after coating of 5 0 2 . And also the aging test showed that $In_2O_3$ coating improved the life time of $Y_2SiO_5$:Ce phosphor.

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Performance of Polymer Suspension Insulator with Shed Profile (갓 형상에 따른 폴리머 현수애자의 열화특성)

  • Cho, H.G.;Lee, U.Y.;Kang, S.H.;Lim, K.J.;Yeo, H.G.;Ji, W.Y.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.539-542
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    • 2003
  • Recently, the polymer insulators which are being used for high voltage applications have some advantages such as light weight, small size, vandalism resistance, hydrophobicity and easy making process. During outdoor service of polymer insulators, the surface of the insulating material is frequently subjected to moisture and contamination which lead to the well known phenomenon of dry band arcing. Their tracking resistance, erosion resistance, end sealing and shed design are very important because dry band arcing causes degradation of polymer surface. The shape design of porcelain insulator is formalized but design standard for polymer insulator is no standardized up to now, much research is necessary in real condition. In this paper, the aging property of polymer insulator with shed shape(regular, alternative type) is analyzed through numerical analysis, CEA(canadian electricity association) tracking wheel test and IEC 61109 Annex C.

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