• Title/Summary/Keyword: surface active agent

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Using response surface methodology and Box-Behnken design in the study of affecting factors on the dairy wastewater treatment by MEUF

  • Khosroyar, Susan;Arastehnodeh, Ali
    • Membrane and Water Treatment
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    • v.9 no.5
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    • pp.335-342
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    • 2018
  • Micelle-Enhanced Ultrafiltration (MEUF) is a membrane separation processes that improving ultrafiltration process with the formation of micelles of the surface active agents. Surface active agents are widely used to improve membrane processes due to the ability to trap organic compounds and metals in the treatment of industrial waste water. In this study, surface active agents are used to improve micelle-enhanced ultrafiltration (MEUF) to reduce chemical oxygen demand (COD), total dissolved solid (TDS), turbidity and clogging the membrane in dairy wastewater treatment. Three important operational factors (anionic surface active agent concentration, pressure and pH) and these interactions were investigated by using response surface methodology (RSM) and Box-Behnken design. Results show that due to the concentration polarization layer and increase the number of Micelles; the anionic surface active agent concentration has a negative effect on the flux and has a positive effect on the elimination of contamination indices. pH, and the pressure have the greatest effect on flux. On the other hand, it could be stated that these percentages of separation are in the percentages range of Nano-filtration (NF). While MEUF process has higher flux than NF process. The results have been achieved at lower pressure while NF process needs high pressure, thus making MEUF is the replacement for the NF process.

Tracking Performance Test of Polymer Insulator with Salt Solution which is added Surface Active Agent (계면활성제가 첨가된 염수용액에 따른 폴리머 애자의 트래킹 성능 평가)

  • Cho, Han-Goo;Han, Dong-Hee;Lee, Un-Yong;Lim, Kee-Joe;Choi, In-Hyuk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1121-1124
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    • 2004
  • Aging test to estimate life property of polymer insulator is executed through several international standard such as IEC 61109 and CEA tracking wheel test, but is not getting clear conclusion yet. There are two methods in the diagnosis method of polymer insulator such as off-line and on-line. The diagnosis methods in off-line are external condition analysis by the eye, contaminant analysis on surface, surface analysis, pollution withstand voltage test, power frequency flashover voltage test, lightning impulse flashover test, tensile fracture load test and flexural load test. The diagnosis methods in off-line most are the method for virgin and last aged sample. However, the diagnosis method in on-line is method that can be evaluate sample state as progressing continuously aging test in beginning, The diagnosis method in on-line is arranged as following: leakage current measurement, electric field, surface state investigation, thermal image, emitting light measurement and then so. In this paper, the tracking performance of polymer insulator with salt solution which is added surface active agent. The diagnosis of insulator sample has been analyzed by leakage current and visual examination.

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Kinetics of In-situ Degradation of Nerve Agent Simulants and Sarin on Carbon with and without Impregnants

  • Saxena, Amit;Sharma, Abha;Singh, Beer;Suryanarayana, Malladi Venkata Satya;Mahato, Timir Haran;Sharma, Mamta;Semwal, Rajendra Prasad;Gupta, Arvind Kumar;Sekhar, Krishnamurthy
    • Carbon letters
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    • v.6 no.3
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    • pp.158-165
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    • 2005
  • Room temperature kinetics of degradation of nerve agent simulants and sarin, an actual nerve agent at the surface of different carbon based adsorbent materials such as active carbon grade 80 CTC, modified whetlerite containing 2.0 and 4.0 % NaOH, active carbon with 4.0 % NaOH, active carbon with 10.0 % Cu (II) ethylenediamine and active carbon with 10.0 % Cu (II) 1,1,1,5,5,5-hexafluoroacetylacetonate were studied. The used adsorbent materials were characterized for surface area and micropore volume by $N_2$ BET. For degradation studies solution of simulants of nerve agent such as dimethyl methylphosphonate (DMMP), diethyl chlorophosphate (DEClP), diethyl cyanophosphate (DECnP) and nerve agent, i.e., sarin in chloroform were prepared and used for the uniform adsorption on the adsorbent systems using their incipient volume at room temperature. Degradation kinetics was monitored by GC/FID and was found to be following pseudo first order reaction. Kinetics parameters such as rate constant and half life were calculated. Half life of degradation with modified whetlerite (MWh/NaOH) system having 4.0 % NaOH was found to be 1.5, 7.9, 1206 and 20 minutes for DECnP, DEClP, DMMP and sarin respectively. MWh/NaOH system showed maximum degradation of simulants of nerve agents and sarin to their hydrolysis products. The reaction products were characterized using NMR technique. MWh/NaOH adsorbent was also found to be active against sulphur mustard.

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Development of New Fiber Reinforced Campsite Materials by Reactive Plasma Surface Treatmnt - (I) Improving the Wettability on the Glass Plate by Plasma Surface Treatment - (반응성 플라즈마 표면처리 기법을 도입한 새로운 유리섬유강화 복합재료의 개발 및 물성연구 - (I) Plasma처리에 의한 평판유리표면의 젖음성 개선에 관한 연구 -)

  • Song, I Y.;Byun, S.M.;Kim, S.T.;Cho, J.S.;Kim, G.S.;Park, C.H.
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.581-583
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    • 1993
  • One of the principal problems encountered in the use of fiber reinforced composites is to establish an active fiber surface to achieve maximum adhesion between resin and fiber surface. In order to improve the interface bonding, the surface of glass fiber should be treated with silane coupling agent in ordinary composite manufacturing processes. However, the price of the coupling agent is very high and in the treating process voids are formed, which decreasees electrical and mechanical strength. We want to develope new process that will overcome the disadvantage of the coupling agent and achieve maximum adhesion at the interface between resin and fiber by active plasma treatment on the glass fiber surface. In this study, we investigate the improvement of contact angle on the glass plate surface as the first step in developing new GFRP.

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Tracking Performance Test of Polymer Insulator with Salt Solution which is added Surface Active Agent (계면활성제가 첨가된 염수용액에 따른 폴리머 애자의 트래킹 성능 평가)

  • Cho, Han-Goo;Lee, Un-Yong;Han, Dong-Hee;Kang, Sung-Hwa;Choi, In-Hyuk;Lim, Kee-Joe
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.1
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    • pp.62-67
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    • 2005
  • Recently, polymer insulators that are used for high voltage applications have some advantages such as light weight, small size, vandalism resistance, hydrophobicity and easy making process. During outdoor service of polymer insulators, the surface of the insulating material is frequently subjected to moisture and contamination that lead to dry band arcing. Their tracking resistance, erosion resistance, end sealing and shed design are very important because dry band arcing causes degradation of polymer surface. Aging test to estimate life property of polymer insulator is executed through several international standard such as IEC 61109 and CEA tracking wheel test, but is not getting clear conclusion yet. There are two methods in the diagnosis method of polymer insulator such as off-line and on-line. The diagnosis methods in off-line are external condition analysis by the eye, contaminant analysis on surface, surface analysis, pollution withstand voltage test, power frequency flashover voltage test, lightning impulse flashover test, tensile fracture load test and flexural load test. Polymer material is also investigated it's tracking resistance by adding surface active agent in IEC 587. In this paper, the tracking performance of polymer insulator with salt solution which is added surface active agent. The diagnosis of insulator sample has been analyzed by leakage current and visual examination, STRI guide and thermal image camera.

The Development of Water-Soluble Black Coloring Agent and Its Application (수용성 흑색 착색제의 개발과 이의 응용)

  • Kim, M.G.;Jung, B.H.;Moon, M.J.;Kim, S.S.
    • Journal of the Korean Society for Heat Treatment
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    • v.15 no.5
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    • pp.213-218
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    • 2002
  • In order to develop the economic and environmental water-soluble black coloring agent, some adequate chemical mixtures were mixed and this solution was applied to coat quenched and tempered 51B20 steel bolt. Some basic properties of the solution and characteristics of the coated film in addition to the corrosion resistance were investigated. The developed 100 kg of water-soluble black coloring agent solution was a chemical mixture consisted of 10 kg of aqueous coloring agent, 40 kg of surface active agent, 0.3 kg of anti-foam agent and $50{\ell}$ of water. The coated film of the bolt was composed of hard layer of about $2{\mu}m$ and the disbondable soft layer of about $4{\mu}m$ above the hard layer. Many surface active agents peaks and a few hydrophilic peaks were observed in the coated film. Surface roughness value of the coated bolt was lower than that of the non-coated bolt. Corrosion resistance of the coated bolt considerably improved and also relatively showed a good polarization resistance at test condition of $40^{\circ}C$ colorizing temperature and 5% the solution concentration in 3% NaCl anodic polarization test. Initial appearance time of the surface rust was greatly retarded owing to the coated film in salt spray test.

Synthesis and Properties of Polyurethane-Acrylate Top-Coating Agent

  • Son, Young-Joon;Lee, Dong Jin;Bae, Jong Woo;Lee, Jung Hee
    • Elastomers and Composites
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    • v.50 no.2
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    • pp.98-102
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    • 2015
  • A series of polyurethane-acrylate hybrids were synthesized by 2-step emulsion polymerization of a variety of acrylate monomers such as 2-hydroxy ethyl methacrylate (HEMA), methyl methacrylate (MMA). Experiment was performed to improve stability and emulsibility of surface treatment agent, and it was found that the polyurethane-acrylate hybrids having an optimum composition (MMA : 20%, LA(EO)3-S : 3% and TDA-7 : 5%) was shown to be quite surface active in the solid contents. These results suggests that the optimal polyurethane-acrylate hybrids in this study have high potential as top coating agent, which may have high gloss and excellent properties.

Preparation and Characterization of Microcapsule for non-aqueous dyeing (비수계 염색용 마이크로캡슐의 제조 및 성질)

  • 최창남;박원규;변수진;이기영
    • Textile Coloration and Finishing
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    • v.15 no.5
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    • pp.327-332
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    • 2003
  • In this study, the polyurethane microcapsules for non-aqueous dyeing containing iron oxide and disperse dyes were prepared by in-situ polymerization method using hexamethylene diisocyanate(HDI) with ethylene glycol(EG). And the size, shape, and particle size distribution of microcapsules prepared were investigated. The size and shape of microcapsule were observed by optical microscope and scanning elecron microscope. The particle size distribution was analyzed by particle size analyzer. The microcapsule size and its distribution were largely effected by the existance of surface active agent in the system. When a surfactant did not exist in the system, the size distribution of microcapsules prepared was much uneven. By adding a surfactant, this phenomenon was disappeared. And the size of microcapsule was also effeced by the hydrophobicity of core material(disperse dye). It was considered due to the difference of dispersity of core materials. And the size of microcapsule prepared was inversely proportional to the stirring speed.

A case study of methanol explosion by metal hydroperoxid (유기 과산화물에 의한 메탄올 폭발 사례 연구)

  • Won You-Jon;Kang Kyong-Sik
    • Journal of the Korea Safety Management & Science
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    • v.7 no.5
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    • pp.119-133
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    • 2005
  • In the June, 1991, there was the explosion in which methanol rectified column as a part of the new surface active agent's manufacturing processes. The type of explosion was estimated as the 'detonation'. The methanol rectified column was ruined, and broken pieces of the column were scattered within 900m. Also, there were victims such as the two deads and thirteen wounded persons. The cause of the explosion was heat explosion by being concentrated locally from 0.1% to several tens% of supply fluid at Metal Hydroperoxide, which was produced by methanol and hydrogen peroxide used as the bleach of surface active agent, during the operation stoppage process of methanol rectified column.