• Title/Summary/Keyword: supersaturation

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On the Contrast of Aerosol Size Distribution and Cloud Condensation Nuclei Concentrations between the East and the West of the Korean Peninsula (대관령과 영종도에서 측정한 에어러솔 크기분포 및 CCN 수농도에 관한 연구)

  • Kim, Jong Hwan;Park, Min-Su;Shim, Sungbo;Yum, Seong Soo
    • Atmosphere
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    • v.22 no.1
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    • pp.87-96
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    • 2012
  • Aerosol number concentration ($N_{CN}$), size distribution and cloud condensation nuclei (CCN) concentration ($N_{CCN}$) were measured during 16-21 August 2008 at Daegwallyeong (DG) located in the eastern rural region of the Korean Peninsula. In the very next week (22-29 August 2008) the same aerosol properties were measured at Yeongjong Island (YJ) in the Yellow Sea. $N_{CN}$ for all 3 size cuts (above 3, 6 and 10 nm) was significantly higher at DG than YJ, but $N_{CCN}$ was significantly lower at the former and resulted in the $N_{CCN}/N_{CN}$ ratio more than twice higher at YJ ($0.94{\pm}0.09$ vs. $0.35{\pm}0.15$ at 0.53% supersaturation). The geometric mean diameter at DG, $53{\pm}15nm$, was much smaller than that at YJ, $91{\pm}6nm$, due to the particle formation events that were likely to have occurred continuously at DG. For given mean diameter, aerosols were more likely to act as CCN at YG compared to those at DG.

The Study on the Gallbladder Empting in Patients with Gallstones (담석증 환자의 담낭수축능에 관한 연구)

  • Yoon, Han-Sik
    • Journal of radiological science and technology
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    • v.21 no.2
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    • pp.31-35
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    • 1998
  • Gallstone diseases appear frequently in surgical patients. One of the etiolic factors in the formation of cholesterol gallstones is the supersaturation of bile with cholesterol. The bile stasis in the gallbladder may also play a role in the formation of cholesterol gallstones by supplying the proper condition to nucleation of cholesterol crystal. Author evaluated gallbladder empting in response to fat meal by ultrasonography in 12 patients with gallstones and normal control group of 12 healthy subjects. Of the 12 patients with gallstones, six had radiolucent stones and the rest of them had radioopaque stones. Additionally, author evaluated gallbladder contraction in both cholesterol gallstones and pigment gallstones. The gallbladder was significantly contracted in control group by the fat meal but not by water. The contraction of gallbladder by fat meal with gallstone patients was significantly decreased compared with those in control group. The time of maximum contraction was 30 minutes in patients with gallstones. At 30 minutes, the gallbladder contraction was more significantly decreased in patients with radiolucent stones than in those with radioopaque stones. In conclusion, the more significant decrease of gallbladder contraction in patients with radiolucent stones may be interpretated as the possible factor of pathologenesis for the formation of the cholesterol stone.

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Growth of Nano- and Microstructured Indium Nitride Crystals by the Reaction of Indium Oxide with Ammonia

  • Jung, Woo-Sik;Ra, Choon-Sup;Min, Bong-Ki
    • Bulletin of the Korean Chemical Society
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    • v.26 no.9
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    • pp.1354-1358
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    • 2005
  • Nano- and microstructured indium nitride crystals were synthesized by the reaction of indium oxide ($In_2O_3$) powder and its pellet with ammonia in the temperature range 580-700 ${^{\circ}C}$. The degree of nitridation of $In_2O_3$ to InN was very sensitive to the nitridation temperature. The formation of zero- to three-dimensional structured InN crystals demonstrated that $In_2O_3$ is nitridated to InN via two dominant parallel routes (solid ($In_2O_3$)-to-solid (InN) and gas ($In_2O$)-to-solid (InN)). The growth of InN crystals with such various morphologies was explained by the vapor-solid (VS) mechanism where the degree of supersaturation of In vapor determines the growth morphology and the vapor was mainly by the reaction of $In_2O$ with ammonia and partially by sublimation of solid InN. The pellet method was proven to be useful to obtain homogeneous InN nanowires.

Study on the Retarding Mechanism and Strength Loss of Gypsum from Hydrolyzed Wheat Protein Retarder

  • Ding, Yi;Fang, Youchun;Fang, Hui;Zhang, Qicai;Zhang, Fengjun;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.52 no.1
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    • pp.28-32
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    • 2015
  • In this article, the influence of a hydrolyzed wheat protein retarder on the hydration process, ion concentration in liquid phase, degree of supersaturation, and crystal morphology of plaster was investigated. Furthermore, the retarding mechanism and the strength loss of gypsum were also studied by scanning electron microscopy (SEM). The results indicate that the use of the hydrolyzed wheat protein retarder for plaster achieved a better retarding effect and lower strength loss. The combination of gypsum plaster with the retarder not only decreased the plaster's early hydration rate and prolonged its setting time efficiently, but also militated against the crystal morphology of dihydrate gypsum. For example, the crystal dimensions changed little, but the proportion of needle-shaped crystals decreased. Combination with calcium ions on the surface of dihydrate gypsum crystal nuclei may form a chemisorbed layer, reduce the surface energy of the crystal nuclei, and inhibit the growth of the crystal nuclei of dihydrate gypsum. Consequently, the hydration process of building gypsum becomes greatly extended and is slowed down significantly.

The study on the synthesise of Ga$_2$O$_3$ nanomaterials (Ga$_2$O$_3$ 나노물질 합성에 관한 연구)

  • 이종수;박광수;노태용;성만영;김상식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.13-17
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    • 2002
  • Ga$_2$O$_3$ nanomaterials were synthesized from mechanically ground GaN powders with thermal annealing Ga$_2$O$_3$ nanobelts were farmed in a nitrogen atmosphere, while Ga$_2$O$_3$ nanoparticles were formed inan oxygen atmosphere. The structural properties of the Ga$_2$O$_3$ nanomaterials were investigated by X-ray diffractometer (XRD) and high-resolution transmission eleotron microscope (HRTEM). The study of field emission scanning electron microscopy (FESEM) on the microstructures of nanomaterials revealed that the nanobelts are with the range of about 10∼200nm width and 10∼50nm thickness, and that nanoparticles are with the range of about 20∼50nm radius. On the basis of XRD and HRTEM data, we determined that the nanobelts grow toward a direction perpendicular to the (010) lattice plane and that they are enclosed by facets of the (10T) and (101) lattice planes. The formation of the nanobelts may be described by the vapor-solid(VS) mechanism, and the supersaturation device of gaseous phase may play an important role in the formation of Ga$_2$O$_3$ nanomaterials.

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Phase Stability Studies of Unirradiated Al-U-10wt.%Mo Fuel at Elevated Temperature

  • Kim, Ki-Hwan;Jang, Se-Jung;Hyun suk Ahn;Park, Jong-Man;Kim, Chang-Kyu;Sohn, Dong-Seong
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.273-278
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    • 1998
  • The phase stability of atomized U-10wt. %Mo powder and the thermal compatibility of dispersed fuel meats at 40$0^{\circ}C$ and 50$0^{\circ}C$ have been characterized. Atomized U-10Mo powder has a good \ulcorner-U phase stability, and excellent thermal compatibility with aluminum matrix in a dispersion fuel. It is thought that the good phase stability is related to th large supersaturation of Mo atoms in the atomized particles. The reasons for the excellent thermal compatibility have been considered to be as follows. Before thermal decomposition of ${\gamma}$-U in particle, supersaturated Mo atoms at ${\gamma}$-U grain boundaries inhibit the diffusion of Al atoms. After thermal decomposition of ${\gamma}$-U into ${\gamma}$-U and U$_2$Mo, the intermetallic compound of U$_2$Mo seems to retard the penetration of Al atoms. The penetration mechanisms of aluminum atoms in the atomized particles are assumed be classified as (a) diffusion through the reacted layer between fuel particles and Al matrix leaving a kernel-like unreacted island and (b) diffusion along grain boundaries showing several unreacted islands and more reacted regions.

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Passive control of condensation shock wave in supersonic nozzles (초음속 노즐에서 발생하는 응축충격파의 피동제어)

  • Kim, Hui-Dong;Gwon, Sun-Beom;Setoguchi, Toshiaki
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.12
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    • pp.3980-3990
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    • 1996
  • When a moist air is rapidly expanded in a supersonic nozzle, nonequilibrium condensation occurs at a supersaturation state. Condensation shock wave appears in the nozzle flow if the releasing latent heat due to condensation goes beyond a critical value. It has been known that self-excited oscillations of the condensation shock wave generate in an air or a steam nozzle flow with a large humidity. In the present study, the passive control technique using porous wall with a cavity underneath was applied to the condensation shock wave. The effects of the passive control on the steady and self-excited condensation shock waves were experimentally investigated by Schlieren visualization and static pressure measurements. The result shows that the present passive control is a useful technique to suppress the self-excited oscillations of condensation shock wave.

Surface Microtopography of Pyrophyllite Crystals from Gussi Deposit, Korea (전남 구시광산에서 산출하는 엽납석 결정의 표면 미세형태)

  • Mayumi Jige;Ryuji Kitagawa;Hwang, Jin-Yeon
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.2
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    • pp.115-121
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    • 2004
  • The surface microtopography of pyrophyllite collected from the Gussi deposit, Korea was observed by mean of transmission electron microscopy (TEM) with the gold decoration technique. As results, closed step patterns with malformed circular islands were characteristically observed on the (001) surface of pyrophyllite, contrasting with spiral step patterns common in illite and kaolinite. Gussi pyrophyllite was likely crystallized from hydrothermal solution of higher temperature and/or higher supersaturation than those of other clay minerals. Comparing with micro-topographies of pyrophyllite from the Shokozan and the Uku deposits, southwest Japan, growth mechanism of Gussi pyrophyllite is almost equivalent to those from the Shokozan and the Uku deposits.

A Study on the Mechanical Properties of Spray-cast Al 6061 Alloy with Variation of Mg/Si Content (분사주조한 Al 6061 합금의 Mg/Si 첨가량의 변화에 따른 기계적 특성 고찰)

  • Lee, Jae-Sung;Kim, Myung-Ho
    • Journal of Korea Foundry Society
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    • v.28 no.4
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    • pp.179-183
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    • 2008
  • Mechanical properties of the spray-cast Al 6061 alloy with variation of Mg/Si addition were investigated. After spray-cast, hot extrusion was performed at $460^{\circ}C$ then followed ageing treatment to the T6 condition. SEM, EDX, and XRD were used to characterize a ${\beta}(Mg_{2}Si)$ precipitate. The amount of ${\beta}$ precipitate was calculated from the XRD measurements. Hardness, ultimate tensile strength and elongation were tested then compared with those of the Al 6061 alloys made by ingot metallurgy (I/M) and powder metallurgy (P/M). The ultimate tensile strength and elongation of the spray-cast Al 6061 alloy were 318MPa and 16.5%, respectively. These properties were improved in the 2.2 wt%Mg and 1.3wt%Si addition up to 349MPa of UTS and 12.5% of elongation, mainly due to increased amount of a fine supersaturated ${\beta}(Mg_{2}Si)$ precipitate.

Studies on Dissolution Rate of Drugs (XV) Dissolution Characteristics of Ibuprofen Dispersed in Sodium Deoxycholate (의약품의 용출에 관한 연구(제15보) 데옥시콜린산나트륨에 분산된 이부프로펜의 용출 특성)

  • Park, Tea-Am;Seo, Seong-Hoon;Kim, Soo-Uck
    • Journal of Pharmaceutical Investigation
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    • v.19 no.1
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    • pp.1-7
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    • 1989
  • Coprecipitates of ibuprofen (IPF)-sodium deoxycholate (DC-Na) were prepared at various mixing ratios of IPF to DC-Na. X-ray diffraction measurments indicated that IPF in 1:3 and 1:5 IPF-DC-Na coprecipitate did not exist in the crystal form, however in the 1:8 coprecipitate, IPF remained its crystalline form. The dissolution rate was tested in pH 7.4 phosphate buffer by the paddle method of dissolution test of KP V. The dissolution rates of IPF from 1:1, 1:3, 1:5, 1:8 and 1:10(w/w) IPF-DC-Na coprecipitates and physical mixtures were compared with that of IPF alone. It was found that the dissolution rate of 1:5(w/w) coprecipitate was greater than that of pure IPF, coprecipitate and physical mixture at any other ratios of the two components. The concentration of IPF released from the IPF-DC-Na coprecipitates reached a plateau within 10 min, and thereafter gradually decreased indicating that IPF released from the coprecipitate was recrystallized due to the transient supersaturation.

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