• International Journal of Air-Conditioning and Refrigeration
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• v.13 no.4
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• pp.206-216
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• 2005

Numerical analysis has been carried out to investigate laminar convective heat transfer at zero gravity in a tube for supercritical water near the thermodynamic critical point. Fluid flow and heat transfer are strongly coupled due to large variation of thermodynamic and transport properties such as density, specific heat, viscosity, and thermal conductivity near the critical point. Heat transfer characteristics in the developing region of the tube show transition behavior between liquid-like and gas-like phases with a peak in heat transfer coefficient distribution near the pseudo critical point. The peak of the heat transfer coefficient depends on pressure and wall heat flux rather than inlet temperature and Reynolds number. Results of the modeling provide convective heat transfer characteristics including velocity vectors, temperature, and the properties as well as the heat transfer coefficient. The effect of proximity on the critical point is considered and a heat transfer correlation is suggested for the peak of Nusselt number in the tube.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.17 no.12
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• pp.1095-1105
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• 2005

Numerical analysis has been carried out to investigate transient turbulent convective heat transfer in a vertical tube for supercritical water near the thermodynamic critical point. Heat transfer and fluid flow in the tube we strongly coupled due to the large variations of thermodynamic and transport properties such as density, specific heat, and turbulent viscosity. As pressure in the tube approaches to the critical pressure, the properties variation with time becomes larger. Heat transfer coefficient rapidly decreases along the tube near the pseudocritical temperature at the tube wall for $P_R<1.2$. Stanton number variation with time is largely reduced in the region of gas-like phase in comparison with Nusselt number. Turbulent viscosity ratio close to the wall increases near the pseudocritical temperature and it gradually decreases with time.

• Journal of Life Science
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• v.18 no.2
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• pp.213-219
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• 2008

Flavonoids in pine needles are known to be effective scavengers of free radical. Especially, proanthocyanidin, a kind of flavonoids possesses cardiovascular protection and antioxidative activities. Here, we evaluated proanthocyanidin contents in total polyphenolic compounds of pine needle extracts prepared by using hot water, ethanol, hexane or sub-supercritical $CO_2$. Analyses of total polyphenolic compounds and proanthocyanidin in each extracts indicated that hot water extract contained the highest concentrations, but sub-supercritical extract contained the lowest concentrations. On the other hand, evaluation of proanthocyanidin contents in total polyphenolic compounds in each extracts showed that sub-supercritical extract possessed the highest content, but hot water extract possessed the lowest content. These results indicate that extracts containing high concentrations of both total polyphenolic compounds and proanthocyanidin could be obtained by using hot water or ethanol extractions. Furthermore, extract containing high content of proanthocyanidin out of total polyphenolic compounds could be achieved by using sub-supercritical extraction. Measurement of antioxidative activities of extracts showed that hot water extract possessed the highest activity. In this study, we prepared extracts from pine needles by four different methods and evaluated the antioxidative compounds in extracts that could be used for effective components of functional food products.

• Proceedings of the Korean Nuclear Society Conference
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• 2004.10a
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• pp.865-866
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• 2004

• Nuclear Engineering and Technology
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• v.39 no.4
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• pp.257-272
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• 2007

Supercritical water-cooled reactors (SCWRs) are recognized as a Generation IV reactor concept. The Super LWR is a pressure-vessel type thermal spectrum SCWR with downward-flow water rods and is currently under study at the University of Tokyo. This paper reviews Super LWR safety. The fundamental requirement for the Super LWR, which has a once-through coolant cycle, is the core coolant flow rate rather than the coolant inventory. Key safety characteristics of the Super LWR inhere in the design features and have been identified through a series of safety analyses. Although loss-of-flow is the most important abnormality, fuel rod heat-up is mitigated by the "heat sink" and "water source" effects of the water rods. Response of the reactor power against pressurization events is mild due to a small change in the average coolant density and flow stagnation of the once-through coolant cycle. These mild responses against transients and also reactivity feedbacks provide good inherent safety against anticipated-transient-without-scram (ATWS) events without alternative actions. Initiation of an automatic depressurization system provides effective heat removal from the fuel rods. An "in-vessel accumulator" effect of the reactor vessel top dome enhances the fuel rod cooling. This effect enlarges the safety margin for large LOCA.

• The Journal of the Convergence on Culture Technology
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• v.8 no.6
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• pp.615-624
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• 2022

In this study, we assessed anti-oxidant activity, anti-microbial, inhibition of biofilm formation and inflammatory factors(nitric oxide, interleukin-6, interleukin-8) inhibitory effect of Perillae semen hydrothermal extract(PSW) and three kinds of Perillae semen supercritical fluid extract(PSSs) extracted by controlling temperature with no variation of pressure. Compared with PSW, PSSs had significantly lower minimal inhibitory concentrations(MICs) against Staphylococcus aureus(S. aureus) and the ability of PSSs to inhibit formation of biofilm was also superior. PSSs reduce the production of inflammatory mediator and inflammatory cytokines significantly compared to PSW. We suggest, therefore, Perillae semen supercritical fluid 45℃ extract which showed the best anti-microbial, inhibition of biofilm formation, and inhibition of inflammatory factors production among the supercritical fluid extracts could be used for protecting patients with atopic dermatitis from pruritus and transepidermal water loss as a functional ingredient from nature.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.4
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• pp.340-346
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• 2013

Study on clean and efficient utilization technology for low rank coal with high moisture content is actively ongoing due to limited reserves of petroleum and of high grade coal and serious climate change caused by fossil fuel usage. In the present study, supercritical water gasification of low rank coal was performed. With increasing reaction temperature, content of combustible gases such as $H_2$ and $CH_4$ in the syngas increased while the $CO_2$ content decreased. As the reaction pressure increased from 210 to 300 bar, the $CO_2$ content in the syngas increased while the hydrocarbon gas content decreased. The $H_2$ and $CH_4$ content in the syngas increased slightly with pressure. With the addition of Pd, Pt, and Ru catalysts, it was possible to improve the production of $H_2$. Moreover, the increase of active metal content in the catalyst increased the $H_2$ productivity. The Ru catalyst shows the best performance for increasing the $H_2$ content in the syngas, while decreasing the $CO_2$ content.

• Clean Technology
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• v.14 no.4
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• pp.248-255
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• 2008

The volume expansion of three ionic liquids (ILs) in the presence of supercritical carbon dioxide has been measured at pressures up to 32 MPa and at temperatures from 313.15 to 333.15 K in a high-pressure view cell. The imidazolium-derivative ionic liquids 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][$PF_6$]), 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][$BF_4$]), and 1-octyl-3-methylimidazolium tetrafluoroborate ([omim][$BF_4$]) were employed in this research. The effects of pressure, temperature, nature of anion and cation as well as the water content on the volume expansion of ILs by absorbing $CO_2$ were investigated experimentally. The volume expansion was higher for the ILs with longer cationic alkyl group and for the ILs with lower anion polarity. The lower the water content, the lower the temperature, or the higher the pressure, the higher was the expansion of IL phase.

• Korean Chemical Engineering Research
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• v.46 no.4
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• pp.747-751
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• 2008

The effect of additives in the synthesis of biodiesel fuel using supercritical methanol was studied in order to examine the possibility of application of spent vegetable oil as a raw material, which has high contents of water or free fatty acid. The experiments were performed by varying the contents of water, free fatty acid or antioxidants respectively in a batch reactor. The contents of fatty acid methyl ester was analyzed by a gas chromatography. As the water contents increased, the contents of fatty acid methyl ester decreased, however, the decrease was very little compared with the alkaline and acid catalyst. The effect of the contents of free fatty acid, vitamin E, and ${\beta}$-carotene was negligible.

• Korean Chemical Engineering Research
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• v.44 no.6
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• pp.636-643
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• 2006

Supercritical water oxidation of DMMP using continuous flow reactor was studied at temperature ranging from 440 to $540^{\circ}C$ and a fixed pressure of 242 bar. The range of residence times in the reactor was from 10 to 26 s, and oxygen excess value varied from -40 to 200%. Destruction efficiencies (DE) of DMMP were greater than 99.7% at $540^{\circ}C$, and increased as the DMMP concentrations were increased. DE of DMMP were significantly affected by oxygen concentration under stoichiometric amount, but showed little difference over stoichiometric amount. On the basis of 30 data with conversions greater than 85%, kinetic correlations for the DE of DMMP were developed. The pre-exponential factor was $(1.10{\pm}0.76){\times}10^6$, and the activation energy was $90.66{\pm}3.87kJ/mol$, and the reaction orders for DMMP and oxygen were $1.02{\pm}0.03$, $0.32{\pm}0.03$, respectively. The model predictions agreed well with the experimental data.