• 설비공학논문집
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• 제12권4호
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• pp.381-387
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• 2000

An experimental study on the stratified fluids was carried out to investigate the flow characteristics, heat transfer through the interface of fluids, and the applications of thermal behaviors in the square cavity. The same volume of water and silicon oil was filled in it. The experiments were performed with the variations of initial temperatures and cooling surface temperatures. And the effect of vertical or horizontal cooling surface positions in the square cavity was investigated. When the cooling surface temperatures were $-4^{\circ}C$ , the supercooling phenomena were observed for both cases of cooling surface positions in the full region regardless of the initial temperature of fluid. In the square cavity with horizontal cooling surfaces, the lower the initial temperatures were, the longer the supercooling durations were, and with vertical cooling surface the lower the initial temperatures were, the shorter the supercooling durations were.

• 설비공학논문집
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• 제16권6호
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• pp.499-505
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• 2004

The objective of this study is to investigate the effect of supercooling repression on the TMA clathrate by adding ethylene glycol. For this purpose, phase change temperature, supercooling, specific heat, latent heat and rate of volume change were measured and evaluated experimentally for heat source temperatures of -6$^{\circ}C$, -7$^{\circ}C$, -8$^{\circ}C$. The results show that supercooling was decreased. Thus the experimental results are expected to be used for the increase of coefficient of performance of low temperature thermal storage system in the building.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 추계학술대회
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• pp.1746-1750
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• 2004

The objective of this study is to investigate the effect of supercooling repression on the clathrate compound by adding additives. For this purpose, phase change temperature and supercooling were measured when additives added to TMA30wt% clathrate for heat source temperature of $-6^{\circ}C$. The experimental results show that the phase change temperature with the chloroform of 0.1wt% is higher by $0.3^{\circ}C$ than TMA30wt% and the supercooling with the surfactant 0.1wt% is reduced by $9.2^{\circ}C$.

• Journal of Welding and Joining
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• 제22권2호
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• pp.78-84
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• 2004

Effects of manganese and carbon on the HAZ microstructural evolution in 500㎫ grade titanium oxide steels were investigated. Microstructural evolution primarily depends on supercooling. When cooled at 3$^{\circ}C$/s in 0.15%C-1.5%Mn steel, grain boundary and Widmanst tten ferrite formed at 640 and 62$0^{\circ}C$, respectively, followed by competitive formation of acicular ferrite and upper bainite inside of grain at 58$0^{\circ}C$. With an increase of manganese, degree of supercooling increased while critical cooling rate for the formation of gain boundary ferrite decreased. Consequently, the amount of acicular ferrite in HAZ was decreased in 2.0%Mn after initial increase in 1.0 and 1.5%Mn. Therefore, optimum supercooling should be maintained to accelerate acicular ferrite formation in titanium oxide steels. Low carbon steel, 0.11%C-1.5%Mn, showed larger amount of acicular ferrite than higher carbon steel because of effectiveness of diffusionless transformation in low carbon steel.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 춘계학술대회
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• pp.1165-1170
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• 2004

The purpose of this study is to investigate the supercooling improvement of TMA30wt% clathrate when the chloroform is added to it. For this purpose, phase change temperature and supercooling are measured and evaluated experimentally in heat source of $-7^{/circ}C$. The results show that phase change temperature and supercooling are improved. From the results, this research can provide and important data for the low temperature thermal storage.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2006년도 하계학술발표대회 논문집
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• pp.132-137
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• 2006

Supercooled type ice slurry system is hard to keep a proper supercooling degree when solution becomes supercooling state. This is the reason of the ice blockage in pipe or cooling part due to an unstable cooling state. In this study, a cooling experiment was performed to pressurized solution in a stationary state. The behaviors during the supercooled aqueous solution were investigated at fixed flow rate of brine and aqueous solution of ethylene glycol 7 mass%. Also the effect to the freezing point of supercooled aqueous solution was investigated to the different pressure 101, 202, 303, and 404 kPa. At results, the pressure of the aqueous solution in the cylinder increased the supercooling degree increased and dissolution of supercooled point decreased.

• 한국자동차공학회논문집
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• 제15권1호
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• pp.23-28
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• 2007

This study aims to find out cooling characteristics of TMA(Tri-Methyl-Amine, $(CH_3)_3N$) 25wt%-water clathrate compound with ethanol($CH_3CH_2OH$) such as supercooling, phase change temperature and specific heat. For this purpose, ethanol is added as per weight concentration and cooling experiment is performed at $-6{\sim}-8^{\circ}C$, cooling heat source temperature, and it leads the following result. (1) Phase change temperature is decreased due to freezing point depression phenomenon. Especially, it is minimized as $3.8^{\circ}C$ according to cooling source temperature in case that 0.5wt% of ethanol is added. (2) If 0.5wt% of ethanol is added, average supercooling degree is $0.9^{\circ}C$ and minimum supercooling is 0.8, $0.7^{\circ}C$ according to cooling heat source temperature. The restraint effect of supercooling is shown. (3) Specific heat shows tendency to decrease if ethanol is added. It is $3.013{\sim}3.048\;kcal/kg^{\circ}C$ according to cooling heat source temperature if 0.5wt% of ethanol is added. Phase change temperature higher than that of water and inhibitory effect against supercooling can be confirmed through experimental study on cooling characteristics of TMA 25wt%-water clathrate compound by adding additive, ethanol. This can lead to shorten refrigerator operation time of low temperature latent heat storage system and improve COP of refrigerator and efficiency of overall system. Therefore energy can be saved and efficiency can be improved much more.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회B
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• pp.2471-2475
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• 2007

Clathrate compound is the material that host in hydrogen bond forms cage and guest is included into it and combined. Crystallization of hydrate is generated at higher temperature than that of ice from pure water. And physical properties according to temperature are stable and congruent melting phenomenon is occurred without phase separation. But clathrate compound still had supercooling problem occurred in the course of phase change and supercooling should be minimized because it affects efficiency of equipment very much. Therefore, various studies on additives to restrain this or heat storage methods are needed. In this study was investigated the cooling characteristics of the TMA-water clathrate compound including TMA (Tri-methyl-amine, $(CH_3)_3N)$ of 20${\sim}$25 wt% as a low temperature latent heat storage material. And ethanol$(CH_3CH_2OH)$ was added and its cooling characteristics were studied experimentally to restrain supercooling of TMA-water clathrate compound.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2009년도 춘계학술발표대회 논문집
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• pp.296-301
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• 2009

The ice storage system uses water for low temperature latent heat storage. However, a refrigerator capacity is increased and COP is decreased due to supercooling of water in the course of phase change from solid to liquid. This study investigates the cooling characteristics of the TMA-water clathrate compound including TMA (Tri-methyl-amine, $(CH_3)_3N)$ of $20{\sim}25wt%$ as a low temperature latent heat storage material. The results showed that the phase change temperature and the specific heat is increased and the supercooling degree is decreased as the weight concentration of TMA increased. Especially, the clathrate compound containing TMA 25wt% has the average phase change temperature of $5.8^{\circ}C$, the supercooling degree of $8.0^{\circ}C$ and the specific heat of 3.499 kJ/kgK in the cooling process. This can lead to reduction of operation time of refrigerator in low temperature latent heat storage system and efficiency improvement of refrigerator COP and overall system. Therefore, energy saving and improvement of utilization efficiency are expected.

• 설비공학논문집
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• 제6권4호
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• pp.354-364
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• 1994

Experiments have carried out to investigate the effects of parameters, such as mass ratio of R141b-to-water, stirrer speed, brine inlet temperature, brine flowrate, and additives, on the performance of the cool storage system using R141b clathrate. The cool storage system in this experiment was composed of storage tank, refrigerator, and heater. The results show that the mass ratio of R141b-to-water, 1 : 3~1 : 3.5 gives the best performance and the stirring speed has optimum point as 600rpm. At this speed impeller Reynolds number is $1.01{\times}10^5$. The lower the inlet brine temperature and the highter the brine flowrate, the better performance. The addition of metal powder turned out to reduce the degree of supercooling. The supercooling reduction was proportional to the amount of the metal power. However when metal powder was added more than 0.1 wt%, there was no additional supercooling reduction. The surfactants shortened the time consumed for cool storage to the half of no surfactant added case.