• Title/Summary/Keyword: super stability

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Current Situation and Overview of Biodiesel over the Global View (글로벌 측면에서 본 바이오디젤의 현황과 전망)

  • Lee, Moon-Yong;Lee, Jin-Hui;Kwak, Jung-Min;Kim, Jae-Kon
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.3
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    • pp.528-539
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    • 2013
  • Biodiesel is one of the most important renewable energy, since it is one of the most important alternative and eco-friendly energy source compared to fossil energy, especially for diesel engineequipped vehicles. It is now coming up for preparation of biodiesel as the alternative that applies the hetrogeneous catalyst, super critical state and various methods used in order to reduce the stages of the processes be converted and separation stages started from oil and fat which are originated from animals and wastes, and those new methods bring eco-friendly as well, though some of those are stand on research step so far. It is necessary that nation provides the tax exemption program for the supplier and strengthen the research system for the farming crops relate to fat and oil. It can improve the development of biodiesel which sustains stability against oxidation and keeps good mobility over the low temperatures in the winter season by new additives and develops new processes to show good harmony with diesel engine.

Thermal Stability of Delithiated LiCoO2-organic Electrolyte for Lithium-Ion Rechargeable Batteries (리튬이온이차전지용 LiCoO2-유기전해액의 충전상태에 따른 열적 안정성)

  • Kim, Dong-Hun;Lee, Young-Ho;Shin, Hye-Min;Chung, Young-Dong;Doh, Chil-Hoon;Jin, Bong-Soo;Kim, Hyun-Soo;Moon, Seong-In;Oh, Dae-Hui;Kim, Ki-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.5
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    • pp.421-424
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    • 2007
  • Thermal behavior of $Li_{1-x}CoO_2$ has been investigated employing DSC (Differential Scanning calorimetry) and TGA (Thermogravimetry Analyzer), and the crystal parameters were calculated from XRD (X-ray diffraction).for the commercial rectangular pouch cell(1000 mAh).The cathode materials coated over aluminium foil current collector is made up of a blend consisting of active material $LiCoO_2$(size $20\;{\mu}m$, 94 wt%), conducting material super p black (SPB, 3 wt%) and binder polyvinylidene fluoride (PVDF, 3 wt%). The anode is a mix consisting of carbon (92 wt%) and PVDF(8 wt%) coated over copper foil. The cells for the experiments were first preconditioned by cycling three times and stabilized at OCV=3.0, 3.5, 4.2, 4.35 and 4.5 V. The stabilized cathode material was used for thermal and crystal parameter investigations.

THE STABILITY OF ALL-TRANS-RETINOL IN NOVEL LIQUID CRYSTALLINE OW EMULSION

  • Kang, H.H.;Cho, J.C.;Lee, J.H.;Lee, O.S.
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.24 no.3
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    • pp.111-115
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    • 1998
  • We investigated the stability of all-trans-retinol on the liquid crystalline O/W emulsion composed of mainly alkyl polyglycerine, alkyl polyglucose and glycerine, and compared the activity of all-trans-retinol in the various forms of liquid crystal. Under certain conditions, novel liquid crystalline gel was formed around oil droplets, and layers of this liquid crystalline gel were very wide and rigid. (SWLC; Super Wide Liquid Crystal) SWLC was very helpful to stabilize retinol in O/W emulsion. After storage at 45 C for 4 weeks, all-trans-retinol in O/W emulsion composed of SWLC retained above 85% of the activity upon HPLC analysis, whereas those within no liquid crystalline emulsion gave 47% and normal liquid crystalline emulsion composed of fatty alcohols gave 40 60%. Retinol in oil phase is nealy insoluble in pure water, but in cosmetic emulsion systems can be slightly solubilized into water because emulsifiers and polyols in emulsion systems function as solubilizers. In this case, water in outer phase acts as a media for oxygen transporation$.$and thus destabilizes retinol. As a result, retinol in O/W emulsion has a tendency to become unstable. SWLC surrounding oil droplet which contains retinol is wide and rigid, therefore reduces contact between inner phase and outer phase To make SWLC, properties of emulsifiers are very important phase transition temperature should be high, and the structure of surfactants should be bulky, and their ratio should be suitable to make rigid and wide liquid crystalline gel layer in order to reduce contact between retinol in inner phase and water in outer phase.

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A STUDY ON THE COLOR STABILITY AND SHEAR BOND STRENGTH OF DENTURE REPAIR RESINS (의치 수리용 레진의 색안정성과 결합강도에 관한 연구)

  • Jin, Tai-Ho
    • The Journal of Korean Academy of Prosthodontics
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    • v.33 no.1
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    • pp.24-31
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    • 1995
  • This study was performed to investigate the color stability and shear bond strength of denture repair resins. The denture base resins used in this study were Premium Super-20(Lang Dental Mfg. Co., Inc.,.U.S.A.) as heat curing resin, Triad VLC Denture Base(Dentsply/York Division, U.S.A.), Triad Reline Material(Dentsply/York Division, U.S.A.), Repair Acrylic(Lang Dental Mfg. Co., Inc.,. U.S.A.), Toughron Rebase (MikiChemical Product, Kyoto, Japan), and Tokuso Rebase(Tokuyama Soda Co., Ltd., Japan) as denture repair resin. After fabrication of specimens, they stored for 20 months, then color changes and shear bond strength were measured by colorimeter(Model TC-6FX, Tokyo Denshoku Co.) and Instron Universial Test Machine. The results were as follows : 1. There were changes of $L^{\ast},\;a^{\ast},\;b^{\ast}$ and $DE^{\ast}$ in Triad VLC Denture Base after 20 months. 2. There were changes of $a^{\ast}$ in Toughron Rebase and Tokuso Rebase, and $b^{\ast}$ in Tokuso Rebase after 20 months. 3. The shear bond strength of Repair Acrylic and Toughron Rebase were higher than that of Tokuso Rebase and Triad Reline Material.

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Deformation and failure mechanism exploration of surrounding rock in huge underground cavern

  • Tian, Zhenhua;Liu, Jian;Wang, Xiaogang;Liu, Lipeng;Lv, Xiaobo;Zhang, Xiaotong
    • Structural Engineering and Mechanics
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    • v.72 no.2
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    • pp.275-291
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    • 2019
  • In a super-large underground with "large span and high side wall", it is buried in mountains with uneven lithology, complicated geostress field and developed geological structure. These surrounding rocks are more susceptible to stability issues during the construction period. This paper takes the left bank of Baihetan hydropower station (span is 34m) as a case study example, wherein the deformation mechanism of surrounding rock appears prominent. Through analysis of geological, geophysical, construction and monitoring data, the deformation characteristics and factors are concluded. The failure mechanism, spatial distribution characteristics, and evolution mechanism are also discussed, where rock mechanics theory, $FLAC^{3D}$ numerical simulation, rock creep theory, and the theory of center point are combined. In general, huge underground cavern stability issues has arisen with respect to huge-scale and adverse geological conditions since settling these issues will have milestone significance based on the evolutionary pattern of the surrounding rock and the correlation analyses, the rational structure of the factors, and the method of nonlinear regression modeling with regard to the construction and development of hydropower engineering projects among the worldwide.

Adaptive second-order nonsingular terminal sliding mode power-level control for nuclear power plants

  • Hui, Jiuwu;Yuan, Jingqi
    • Nuclear Engineering and Technology
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    • v.54 no.5
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    • pp.1644-1651
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    • 2022
  • This paper focuses on the power-level control of nuclear power plants (NPPs) in the presence of lumped disturbances. An adaptive second-order nonsingular terminal sliding mode control (ASONTSMC) scheme is proposed by resorting to the second-order nonsingular terminal sliding mode. The pre-existing mathematical model of the nuclear reactor system is firstly described based on point-reactor kinetics equations with six delayed neutron groups. Then, a second-order sliding mode control approach is proposed by integrating a proportional-derivative sliding mode (PDSM) manifold with a nonsingular terminal sliding mode (NTSM) manifold. An adaptive mechanism is designed to estimate the unknown upper bound of a lumped uncertain term that is composed of lumped disturbances and system states real-timely. The estimated values are then added to the controller, resulting in the control system capable of compensating the adverse effects of the lumped disturbances efficiently. Since the sign function is contained in the first time derivative of the real control law, the continuous input signal is obtained after integration so that the chattering effects of the conventional sliding mode control are suppressed. The robust stability of the overall control system is demonstrated through Lyapunov stability theory. Finally, the proposed control scheme is validated through simulations and comparisons with a proportional-integral-derivative (PID) controller, a super twisting sliding mode controller (STSMC), and a disturbance observer-based adaptive sliding mode controller (DO-ASMC).

Electrosynthesis and Electrochemical Properties of Metal Oxide Nano Wire/ P-type Conductive Polymer Composite Film

  • Siadat, S.O. Ranaei
    • Journal of Electrochemical Science and Technology
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    • v.6 no.3
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    • pp.81-87
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    • 2015
  • This study introduces a facile strategy to prepare metal oxide/conducting polymer nanocomposites that may have promising applications in energy storage devices. Ploy aniline/nano wire manganese dioxide (PANI/NwMnO2) was synthesized by cyclic voltammetry on glassy carbon electrode. Morphology and structure of the composite, pure PANI, MnO2 nanowires were fully characterized using XRD and SEM analysis. Electrochemical studies shows excellent synergistic effect between PANI and MnO2 nanowires which results in its capacitance increase and cycle stability against PANI electrode. Specific capacitances of PANI/NwMnO2 and PANI were 456 and 190 F/g respectively. The electrochemical performance of electrodes studied using cyclic voltammetry, Galvanostatic charge/discharge and impedance spectroscopy.

A Study on the Economic Evaluation Model of Splice of Reinforcement Bar(SD500) (초고강도 철근이음의 경제성 평가모델 개발에 관한 연구)

  • Kim, Jae-Yeob;Kim, Dae-Won
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.1
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    • pp.71-76
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    • 2008
  • Recently, the high-rise apartment housings have become a prototype of the urban residential dwelling in Korea and the numbers of one have steadily been increasing. According to this trend, the strength of the construction materials is also fortified to assure the stability and durability of the buildings. Specially, Re-bar of SD500 type is largely used at the construction sites of high-rise building. This study analyzes the current usage of SD500 high-strength re-bar at domestic construction sites. Through the result of this analysis, we develop Economic Evaluation Model that measure economic efficiency of lap splice and coupler splice, which are most commonly used in connection SD500. The evaluation method was applied to construction sites in Seoul in December 2006, and the result revealed that coupler splice is relatively superior in terms of cost efficiency when the re-bar diameter is longer and the concrete strength is lower.

Manufacture of Lapping Wheel for Electrolytic Dressing and Evaluation of Electrolytic Characteristics (연속 전해드레싱용 래핑지석의 제작 및 전해 특성 평가)

  • 최재영;이은상;송지복
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.11a
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    • pp.914-917
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    • 2000
  • Application of ceramics, carbide, ferrite has grown considerably due to significant improvement in their mechanical properties such as light weight, chemical stability , super wear resistance and electronical. Despite these character, the me of advanced material has not increased because of poor machinability. The method of using of metal bond wheel was proposed. But it is difficult that metal bond wheel can be dressed. Recently, the technology of in-process electrolytic dressing is developed to solve this problem. This method need wheel for electrolytic dressing, power supply and electrolyte. But development of wheel for electrolytic dressing is the most need. The aim of this study is development of wheel for electrolytic and appraisement of CIB-diamond lapping wheel

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Fabrication of Stable Water/Oil Separation Filter Using Effect of Surface Wettability (표면 젖음성을 이용한 물/오일 분리막 제작)

  • Kim, Dohyeong;An, Taechang
    • Journal of Sensor Science and Technology
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    • v.25 no.3
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    • pp.213-217
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    • 2016
  • The superhydrophobic and superoleophobic meshes surfaces have been used in various applications such as self-cleaning, anti-icing, gas exchange, oil-water separation, sound-wave penetrable anti-wetting structures, etc. In particular, there are many studies for oil-water separation with environmental issues. Because of high pressure and dynamic environment, oil-water separation filters must have stable surface properties as super-hydrophobicity and superoleophobicity. The oleophobicity of surface depends on the surface chemistry and roughness of the surface. The roughness of oleophobic surface enhances its static contact angle and stability. The multi-scale hierarchical structure provides a stable superhydrophobic state by maintaining a Cassie state. In this research, we fabricated a superoleophobic mesh with a multi-scale hierarchical structure to increase the pressure resistance and adjusted a size of the mesh hole.