• Title/Summary/Keyword: sulphur dioxide

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Atmospheric Acidic Deposition: State of Acid Rain in Korea and the World (대기산성강하물: 한국과 세계의 산성비 실태)

  • Kim, Joon-Ho
    • The Korean Journal of Ecology
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    • v.28 no.3
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    • pp.169-180
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    • 2005
  • Nitrogen dioxide concentration was being grown ca. 8% per year although sulphur dioxide concentration was being reduced ca. 10% per year in Seoul from 1996 to 2003. The rainwater was heavily acidic with pH 4.19 to 4.68 in Seoul during 1980 to 1991. Acidity score on the basis of the total anion concentration of rainwater follows the higher in sequence with Seoul(Kwanaksan)(341.5 ${\mu}equiv{\cdot}L^{-1}$), Gwangneung(199.2 ${\mu}equiv{\cdot}L^{-1}$) and whole Korea mean(10.3 ${\mu}equiv{\cdot}L^{-1}$). Rainwaters from 38 sampling sites of 16 countries in the world, on the basis of the acidity score, are classified and designated as five acid rain grades(ARG): the least score is founded in Tana Rata(16.2 ${\mu}equiv{\cdot}L^{-1}$), Malaysia where has the best rain but the greatest founded in Chongquing(541.1 ${\mu}equiv{\cdot}L^{-1}$), China where has the worst rain in the world. Even though acidic deposition decrease with time in the world generally, it is expected to increase in Asia, Africa and Mid-South America.

Generation Characteristics and Prediction of Acid Rock Drainage(ARD) of Road Cut Slopes (건설현장 절취사면의 산성배수 발생특성과 잠재적 산발생능력 평가)

  • Lee, Gyoo-Ho;Kim, Jae-Gon;Lee, Jin-Soo;Chon, Chul-Min;Park, Sam-Gyu
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.03a
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    • pp.491-498
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    • 2005
  • Acid Rock Drainage(ARD) is the product formed by the atmospheric(i.e. by water, oxygen and carbon dioxide) oxidation of the relatively common iron-sulphur minerals pyrite($FeS_2$). ARD causes the acidification and heavy metal contamination of water and soil and the reduction of slope stability. In this study the generation characteristics and the prediction of ARD of various road cut slopes were studied. An attempt to classify the rocks into several groups according to their acid generation potentials was made. Acid Base Accounting(ABA) tests, commonly used as a screening tool in ARD predictions, were performed. Sixteen rock samples were classified into PAF(potentially acid forming) group and four rock samples into NAF(non-acid forming) group. The chemical analysis of water samples strongly suggested that ARD with high content of heavy metals and low pH could pollute the ground water and/or stream water.

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Korean HAEI Method-a Critical Evaluation and Suggestions (국내 시간별 대기환경지수 방법의 문제점과 개선 방안)

  • Baek Sung-Ok;Lee Yeo-Jin;Park Dae-Gwon
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.4
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    • pp.518-528
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    • 2006
  • The air quality index (AQI) is an index for reporting daily or hourly air quality to the general public. The AQI focuses on health effects that can happen within a few hours or days after breathing polluted air. Many countries have their own AQI reporting systems, and the HAEI (hourly air environment index) method is now being used in Korea. In this study, in order to compare the AQI results from different methods, we applied three methods. i.e. US AQI, Canadian AQI, and Korean HAEI, to the same air quality data-base. The data-base was constructed from 10 monitoring sites in Gyeong-buk province for the last four years since 2000. Based on the results, a critical evaluation of the Korean HAEI method was made, and a number of suggestions and recommendations were presented to improve the AQI reporting system in Korea.

Comprehensive Empirical Equation for Assessing Atmospheric Corrosion Progression of Steel Considering Environmental Parameters

  • Sil, Arjun;Kumar, Vanapalli Naveen
    • Corrosion Science and Technology
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    • v.19 no.4
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    • pp.174-188
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    • 2020
  • Atmospheric corrosion is a natural surface degradation process of metal due to changes in environmental parameters in the surrounding atmosphere. It is very sensitive to environmental parameters such as temperature, relative humidity, sulphur dioxide, and chloride, making it a major global economic challenge. Existing forecasting empirical corrosion models including the ISO standard are based on statistical analysis of experimental studies without considering the behavior of atmospheric parameters. The present study proposes a reliable global empirical model for estimating short and long-term atmospheric corrosion rates based on environmental parameters and corrosion mechanisms obtained from a parametric study. Repercussion of atmospheric corrosion rate due to individual and combined influences of environmental parameters specifies their importance in the estimation. New global empirical coefficients obtained for environmental parameters are statistically established (R2 =0.998) with 95% confidence limit. They are validated using experimental datasets of existing studies observed at 88 different continental locations. The current proposed model can predict atmospheric corrosion by means of corrosion formation mechanisms influenced by combined effects of environmental parameters, further abating applicability limitations of location and time.

Tolerance of Several Woody Plants to Sulphur Dioxide

  • Hwangbo, Jun-Kwon;Lee, Chang-Seok;Kim, Joon-Ho
    • Animal cells and systems
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    • v.4 no.4
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    • pp.337-340
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    • 2000
  • The photosynthetic and stomatal responses of several woody plants (Powlonia coreana, Firmiana simplex, Quercus acutissima Q. variabilis and Q. serrata) to SO$_2$ were investigated in order to understand their ecophysiological tolerance to $SO_2$ Of the plants, P, coreana showed the largest reduction in its photosynthesis in response to exposure of 0.4 ppm $SO_2$ for 20 h. Fumigation of 0.7 ppm $SO_2$ for 20 h caused complete leaf necrosis of P. coreana and f simplex, which made them unavailable for the measurement of photosynthesis. Q. variabilis exhibited the smallest reduction in photosynthesis following exposure of 0.7 ppm $SO_2$ for 20 h. Both stomatal- and non-stomatal inhibition of the plants by $SO_2$ were determined according to equations by lkeda et at. (1992). When exposed to 0.4 ppm $SO_2$ for 20 h, F. simplex and P. coreana showed the lowest stomatal and non-stomatal inhibition, respectively, while Q. variabilis and Q. serrata exhibited the lowest stomatal and non-stomatal inhibition, respectively, in response to 0.7 ppm $SO_2$ for 20 h. The data are discussed with regard to resistance mechanisms of other plants to $SO_2$ exposure and implications for restoration of declined Korean forests.

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A Study on Greenhouse Gas Emissions Characteristics of Local Government for the Achievement of the National Reduction Goal (국가 온실가스 감축목표 달성을 위한 지자체 온실가스 배출특성 연구)

  • Park, Ji Hui;Kim, Hyung Suk;Song, Kwon Bum;Yi, Sung Ju
    • Journal of Climate Change Research
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    • v.8 no.3
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    • pp.247-255
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    • 2017
  • In this study, GHG inventory on 17 local government between 2005 and 2014 is build up using 'GHG emission estimation guideline (2016. 2) for local government' developed and distributed by KECO. This covers all the sectors should be included in national GHG inventory, which are energy, industrial process, agriculture, AFOLU, and waste. In addition, six GHGs, carbon dioxide, metane, nitrous oxide, hydrofluorocarbons, perfluorocarbons, sulphur hexafluoride declared in Kyoto protocol are estimated to reflect utmost precision. Indirect esissions, such as electricity, heat and waste generation are separately estimated as well as direct emissions to help local government to establish substantial and implementable reduction measures of GHGs.

Studies on the Effects of Atmospheric Pollution in Sericulture -Injuries of Sulphur Dioxide and Cadmium on Parent Silkworms Rearing- (대기공해가 양잠에 미치는 영향에 관한 연구 -원잠종 사육에 있어서 아황산 가스 및 카드미움의 해를 중심으로-)

  • 이종철;최진협;배계선;손흥대
    • Journal of Sericultural and Entomological Science
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    • v.21 no.1
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    • pp.36-44
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    • 1979
  • Those studies were examined rearing two varieties on Japanese descent and two varieties of Chinese descent by feeding polluted mulberry leaves, non-polluted ones and water-cleaned ones respectively to find effects of air-pollution on the economic characters of silkworms and analysis of contents of Sulphur and Cadmium in the mulberry leaves and silkworms as followings; 1) Japanese descent of polluted part was delayed about 2.5 days than non-polluted part, Chinese descent was delayed about 4 days or inequal and water-cleaned part was medium in the silkworm larval duration. 2) Results of maximum weight of 5th instal, cocoon layer weight and cocoon weight were decreased in due order non-polluted, water-cleaned and polluted in the factors of mulberry 3) Pupal ratio of Japanese descent was not shown statistical significance, but Chinese descent was revealed it obviously in the factors of mulberry leaves. 4) In the resistance of polluted mulberry leaves, Chinese descent was feeble obviously than Japanese and there were some difference even through among the same varieties. 5) The content of S and Cd of polluted area mulberry leaves was increased about 30% respectively than non-polluted area. 6) The fed part of non-polluted mulberry leaves was S 0.41% and Cd 0.013 ppm water-cleaned part was S 0.47% and Cd 0.024 ppm and polluted part was S 0.52% and Cd 0.042 ppm in the contents of S and Cd of silkworm larvae. 7) The contents of S and Cd didn't make visible injury in mulberry leaves but made it seriously in silkworm larvae. 8) The injury of dust on mulberry leaves was more serious than that of quality of mulberry leaves by air-pollution in the economic characters of silkworm. 9) As above results, Chinese descent should avoid contaminated area and it rearing by water-cleaned mulberry leaves can get noticable results in inevitable case on selection of parents silkworm rearingzone.

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Preparation of PVDF Hollow Fiber Membrane and Absorption of SO2 from Flue Gas Using Bench Scale Gas-Liquid Contactor (PVDF 중공사막 제조 및 벤치규모 기-액 접촉기를 이용한 SO2 흡수특성)

  • Park, Hyun-Hee;Jo, Hang-Dae;Kim, In-Won;Lee, Hyung-Keun
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.521-528
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    • 2008
  • The micro-porous asymmetric PVDF hollow fiber membranes for gas-liquid contactor were prepared by the dry-jet wet phase inversion process and the characteristics of hollow fiber membranes were evaluated by the gas permeation method and scanning electron microscope. The chemical absorbent for removal of $SO_2$ gas was sodium hydroxide at bench scale hollow fiber membrane contactor. The experiments were performed in a counter-current mode of operation with gas in the shell side and liquid in the fiber lumen of the module to examine the effect of various operating variables such as concentration of absorbent, gas flow rate, L/G ratio and concentration of inlet $SO_2$ gas on the $SO_2$ removal efficiency using PVDF hollow fiber membrane contactor. Membrane mass transfer coefficient($k_m$) was calculated by mathematical modeling. The volumetric overall mass transfer coefficient increased with increasing the concentration of absorbent and L/G ratio. The increase of the absorbent concentration and L/G ratio not only provides more sufficient alkalinity but also decreases liquid phase resistance. The volumetric overall mass transfer coefficient increased with increasing gas flow rate due to decreasing the gas phase resistance.

The Influences of Concentration Distribution and Movement of Air Pollutants by Sea Breeze and Mist around Onsan Industrial Complex (온산공업단지 주변의 박무와 해풍발생이 대기오염물질의 이동 및 농도분포에 미치는 영향)

  • Lee, Hyung-Don;Lee, Gou-Hong;Kim, In-Deuk;Kang, Ji-Soon;Oh, Kwang-Joong
    • Clean Technology
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    • v.19 no.2
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    • pp.95-104
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    • 2013
  • Onsan Industrial Complex located in a nearby the Ulsan Petrochemical Complex and in the east of the coast. For this reason, air pollution substances emitted by Onsan Industrial Complex especially tend to have an effect on meteorological factors such as sea breeze. In this study, we assessed the frequency of sea breeze and mist using the meteorological data, and analyzed potential temperature and upper wind condition for assessment of atmospheric pollution concentration influenced by meteorological phenomena in a nearby the Onsan industrial complex. From an analysis results, when mist and sea breeze happened, each higher concentration phenomenon of $PM_{10}$ and $SO_2$ appeared each 57.2%, 71.8% and 46.6%, 57.7% respectively. Hence, we confirmed that meteorological phenomena such as mist and sea breeze had an effect on high concentration of air pollution substances in the research area. Analytical result of meteorological data in upper layer using potential temperature and wind condition, we confirmed that advection of air pollution substances emitted in Ulsan Petrochemical Complex by sea breeze have an effect on high concentration in Onsan Industrial Complex and nearby the residential area. In particular;concentration in Onsan Industrial Complex were higher than the average concentration by a factor of more than over 1.5 times when sea breeze by stable condition in atmospheric layer appeared.

Quality Improvement of Dried Persimmons Slices during Storage Period using SO2 Treated Pads (SO2 살균패드처리에 의한 감말랭이의 저장 중 품질 변화)

  • Oh, Sung-Il;Kim, Chul-Woo;Lee, Uk
    • Journal of Korean Society of Forest Science
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    • v.105 no.1
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    • pp.108-114
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    • 2016
  • The effects of $SO_2$ treated pads ($SO_2$ 0, 0.5, 1, and 2 g/kg) on the quality of dried persimmons slices were investigated. The $SO_2$ treated pads for storage did not affect to weight, moisture loss rate, and soluble solid contents of dried persimmons slices. The color change after storage for 12 weeks was the highest (value = 3.5) in control ($SO_2$ 0 g/kg), whereas that was the lowest (value = 2.0) under $SO_2$ 2 g/kg condition. When we measured the browning degree after 12 weeks, they showed O.D. 0.24, 0.22, 0.20, and 1.7 in serial dilution treated pads with $SO_2$ 0, 0.5, 1, and 2 g/kg, respectively. The decaying rate was the highest (7.0%) in control after 12 weeks storage, whereas it did not show any spoilage in $SO_2$ 1 g/kg and 2 g/kg treated condition for whole storage period. The concentration of residual $SO_2$ in dried persimmons slices was detected within a safe range of 20.3~40.3 ppm. Therefore, the shelf-life of dried persimmons slices was lengthened in $SO_2$ treated pads (especially in $SO_2$ 2 g/kg) for inhibiting of browning and decaying.