• Title/Summary/Keyword: sulphide

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Determination of Optical Constants of ZnS Using Jellison-Modine Dispersion Relation (Jellison Modine 분산식을 이용한 ZnS의 광학상수 결정)

  • Park, Myung-Hee
    • Journal of Korean Ophthalmic Optics Society
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    • v.12 no.1
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    • pp.85-90
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    • 2007
  • We deposited thin films of ZnS(Zinc Sulphide), in which was used antireflection coating material of glasses-lens on silicon and slide-glass substrates using spin coating method, and measured spectra of ellipsometry angles ${\Delta}$ and ${\Psi}$ in the photon-energy range of 1.5~5.0 eV using a variable angle spectroscopic ellipsometer. The optical constants, refractive index and extinction coefficient, of ZnS were determined via the dispersion parameters extracted from the curve-fitting process based on Jellison-Modine dispersion function.

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Operational behaviour and reliability measures of a viscose staple fibre plant including deliberate failures

  • Sengar, Surabhi;Singh, S.B.
    • International Journal of Reliability and Applications
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    • v.13 no.1
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    • pp.1-17
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    • 2012
  • This Paper deals with the stochastic behavior and failure analysis of a Viscose Staple Fibre Plant which produces fibre for making clothes. The fibre making plant is a complex system with various subsystems as: Vendor (supplies Charcoal and Sulphur, raw materials for the process), Carbon di sulphide Plant, Acid Plant, Pulp Plant and Processing Plant. The considered system can completely fail due to failure of any of the subsystems. The Carbon di Sulphide Plant can fail in two different ways, due to lack of Sulphur or Charcoal. Processing Plant has the configuration 5-out-of-10: d and 6-out-of-10: f. It is also assumed that the system can fail due to workers strike and catastrophic failure. All failures follow exponential time distribution whereas all repairs follow general time distribution. Preventive Maintenance policy has been applied to reduce the failure in the system. Various reliability characteristics such as transition state probabilities, steady state behavior, reliability, availability, M.T.T.F and the cost analysis have been obtained using supplementary variable technique and Gumbel-Hougaard copula methodology.

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Effect of annealing atmosphere on the properties of chemically deposited Ag2S thin films

  • Pawar, S.M.;Shin, S.W.;Lokhande, C.D.;Kim, J.H.
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.34.2-34.2
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    • 2009
  • The silver sulphide (Ag2S) thin films have been chemically deposited from an alkaline medium (pH 8 to 10) by using a silver nitrate and thiourea as a Ag and S ion precursor sources. Ethylene Damine tetraacetic acid (EDTA) was used as a complexing agent. The effect of annealing atmosphere such as Ar, N2+H2S and O2 on the structural, morphological and optical properties of Ag2S thin films has been studied. The annealed films were characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM) and optical absorption techniques for the structural, morphological, and optical properties, respectively. XRD studies reveal that the as-deposited thin films are polycrystalline with monoclinic crystal structure, is converted in to silver oxide after air annealing. The surface morphology study shows that grains are uniformly distributed over the entire surface of the substrate. Optical absorption study shows the as-deposited Ag2S thin films with band gap energy of 0.92eV and after air annealing it is found to be 2.25 eV corresponding to silver oxide thin films.

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Mineralogical Characteristics and Removal of Heavy Metals from Gum-poong Mine Tailings (금풍광산(鑛山) 광물(鑛物)찌꺼기의 광물(鑛物)학적 특성(特性) 및 중금속(重金屬) 제거(除去))

  • Cha, Jongmun;Park, Jayhyun;Kang, Heon Chan
    • Resources Recycling
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    • v.21 no.6
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    • pp.51-57
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    • 2012
  • The objective of this study was to research the mineralogical characteristics and removal of heavy metals of tailings from Gum-poong mine. From the result of mineralogical analysis, there are several sulphide minerals such as chalcocite, aresenopyrite, pyrite, sphalerite and galena. Cd and Zn have a good positive correlation from the statistical relation between Cd and other heavy metals(Cu, Pb, Zn). Residual heavy metals(As, Cd, Cu, Pb, Zn) from the Gum-poong tailings were removed under the warning criteria from the result of froth flotation with K.A.X.(Potassium Amyl Xanthate) and Aerofloat 211.

Global Trends of Sciences Information on the Sour Gas (사워가스 학술정보 동향)

  • Cho, Jin Dong
    • Economic and Environmental Geology
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    • v.48 no.1
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    • pp.89-101
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    • 2015
  • The sour gas is natural gas containing components such as hydrogen sulphide and carbon dioxide that form acids when mixed with water. Element sulfur precipitates from sour gas when reservoir pressure and temperature decrease. According to the International Energy Agency, about 43% of the world's natural gas reserves(2,580 tcf or 73.057 tcm), excluding North America, are sour. The sour gas is often derived from the Germanic word 'sauer or acidic' and the etymology referred to as 'sour'. Sour gas requires special handling and infrastructure because it contains significant amounts of hydrogen sulphide, making it highly corrosive, flammable and explosive, and there fore more costly and dangerous to process. So the business of sour gas is affected by two important factors: the economic value of the gas, and the methods used in its production. According to be analyzed in the academic literature to sour gas(2000~2014) by the program of 'web of science', the research activities 145 papers in sour gas.

A Study on a Chaotic Oscillator Circuit with CdS Cell (CdS 셀을 이용한 카오스 발진기 회로 연구)

  • 박민서;정동호;정경택
    • Proceedings of the IEEK Conference
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    • 2000.06e
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    • pp.73-76
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    • 2000
  • We study the Chua oscillator circuit by considering a negative resistor as a characteristic parameter which controlled by the CdS(Cadmium Sulphide) cell. This is a new way to observe several chaotic phenomena with the same initial condition continuously. Since we can control the internal resistance of the CdS cell by an additional circuit, our autonomous chaotic oscillator circuit makes it possible to measure the voltage value continuously and automatically.

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MICROENVIRONMENT IN OYSTER FARM AREA 1. On the Eutrophication and Raft Density in Geoje Bay (굴 양식장의 미세환경에 관한 연구 1. 거제만의 양식장밀도 및 부영양화에 관하여)

  • CHO Chang Hwan;KIM Yong Sool
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.10 no.4
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    • pp.259-265
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    • 1977
  • After a great mortality owing to abnormal oceanographical condition and fungal disease in 1973 hanging cultch lines per raft has been reduced to 450 from 558, and oyster production per raft has also been decreased. It seems to be result of dense culture of oysters and its resulting accumulation of waste materials on the sea bottom in the farm area. The present study was carried out to investigate the effect of rearing density and the degree of eutrophication in Geoje Bay for 6 months from June through November in 1977. Total area of this bay is about $48.9\;km^2$, and the area of registered oyster farms as of November in 1977 is around $10.9\;km^2$, which is about $22.3\%$ of this bay. Water Quality during summer season was shown as transparency 5.5 m, COD 1.5ppm, degree of oxygen saturation $90.6\%$ in upper and middle layers and $82.2\%$ near bottom, chlorophyll-a 3.0 mg/m^3, and phytoplankton $8.7\times10^4\;cells/l$. In superficial mud in August COD was 35.4 mg/g, total sulphide 0.24 mg/g, and phaeophytin $43.7\;{\mu}g/g$dry mud. These values indicate that water qualify in this bay is so far excellent but quantities of chemical oxygen demend and sulphide in bottom mud show maximum level or a little over eutrophication standard.

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Geology and Ore deposits of Songgwang Mine (송광광산(松廣鑛山)의 지질광상(地質鑛床))

  • Hong, Man Seup
    • Economic and Environmental Geology
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    • v.2 no.3
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    • pp.58-67
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    • 1969
  • Songgwang lead zinc mine is located in about 12km to the north-east of Jeonju City. Geology of the mine and its visinity is consisted of Jeonju series belonged to so-called Okcheon system, Seodaesan tuff formation, Silla series, and the quartz porphyry intruded into these formations. Jeonju series comprising 3 formations; that is, of Sadaeri, Sindong, and Girinbong. Jeonju series is generally distributed in southern part of the area, striking NNW, and diping NE $30^{\circ}$, or NW $30^{\circ}$. It is deformed to form synclinorium and anticlinorium plunging to the north with low angle. In the northern part of the area, Jeonju series was cut by Sinpeongri-fault of NEE direction near Sinpeongri. In the north side of the fault, it is overturned and shows NEE or NWW strikes and NW $60^{\circ}$ dips. At the west of Songgwangri, it is cut by 3 thrusts; the two are almost parallel each other, and the third oneis manifested by the fact that the lower black shale zone thrusted over the upper limestone. Songgwangri thrust, so named, is a post-mineral fault and its plane represents a premineral slip plane. Enrichment of are took place along the bedding plane or fissure parallel to it, as seen in adit No. 1 or No. 2 along the floor of the thrust, and along the sheared zone or the brecciated zone oblique to the plane near the thrust in crystalline limestone of Sindong formation as observed in the underground levels of inclined slope. Ore minerals are chiefly zincblende, galena, pyrrhotite, arsenopyrite, acompanied pyrite and chalcopyrite, and contain Au and Ag. In earlier stage of mineralization, the limestone was recrystalized, and sulphide minerals were enriched in the· permiable zone said above by pyrometasomatism, and in later stage the limestone was affected chloritization and sericitization. However hydrothermal replacement was weak, so that enrichment did not took place. It seems that minerallizing materials came up through the premineral slip plane and injected, and replaced the limestone in permiable zone said above with sulphide are minerals. Then Songgwangri thrust took place and, the lower black shale zone thrusted upon crystalline limestone.

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Effect of Zr Addition on the Mechanical Properties and MnS Morphology of Cr-Mo Plastic Mold Steel (Cr-Mo계 금형강의 기계적 성질과 MnS 형상 변화에 미치는 Zr첨가의 영향)

  • Kim, Nam-Kyu;Jeon, Ho-Sung;Lee, Oh-Yeon
    • Journal of the Korean Society for Heat Treatment
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    • v.23 no.4
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    • pp.191-197
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    • 2010
  • Zr addition is known as effective method to improve the anisotropy of steel due to the elongated MnS inclusions which are observed in hot forged steels. The aim of this research is to investigate the effect of Zr addition on the mechanical properties and manganese sulphide morphology of 0.27%C-Cr-Mo plastic mold steel. The ingots were prepared by vacuum induction melting and forged to ${\Phi}35mm$ round bar. Forged bars were quenched and tempered at $560{\sim}640^{\circ}C$ for 1 hour. Jominy test, microstructual observation, tensile test and Charpy impact test were conducted. The morphology of MnS inclusions was changed by Zr addition. The shape of MnS inclusions was not so much lengthened and controlled not to be elongated by Zr inclusions which surround the MnS inclusions. Tensile strength and yield strength of the tempered steels were not nearly affected by the addition of Zr, but elongation and reduction of area were decreased. Especially, the toughness of Zr added steels was deteriorated with increasing of Zr content. From the results of this study, it is assumed that anisotropy of steels was improved by the addition of Zr. However, impact toughness of the steel was significantly decreased by the excessive Zr addition (over 0.066%).

Dissolution of Pb from the Complex Sulphide Concentrates Containing Galena and Arsenopyrite by Alkaline Oxidative Leaching (황비철광(黃砒鐵鑛)과 방연광(方鉛鑛)의 혼합황화광(混合黃化鑛)의 알카리산화(酸化)에 의한 Pb침출(浸出))

  • Youn, Ki-Byoung
    • Resources Recycling
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    • v.17 no.3
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    • pp.42-47
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    • 2008
  • In this work, the dissolution behavior of Pb from the complex sulphide concentrates containing Galena and Arsenopyrite by alkaline oxidative leaching was studied. The influences of leaching temperature, oxygen partial pressure, leaching time and NaOH concentration of leaching solution were examined at the leaching conditions in the range of $100^{\circ}C{\sim}140^{\circ}C$ temperature, $40psi{\sim}100psi\;PO_2$ and $0.5M{\sim}2M$ NaOH concentration. The optimum result was obtained at the leaching condition of leaching temperature $120^{\circ}C$, 100psi $PO_2$, leaching time 30min. and 2M NaOH concentration of leaching solution.