• Title/Summary/Keyword: sulfate resistance portland cement

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Chemical Resistance of Low Heat Cement Concrete Used in Wastewater Treatment Structures Built on Reclaimed Land (해안매립지 하수처리시설물에 적용한 저발열시멘트 콘크리트의 내화학성 평가)

  • Chung, Yongtaek;Lee, Byungjae;Kim, Yunyong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.7
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    • pp.113-119
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    • 2019
  • Concrete structures built on reclaimed land are combined with chemical erosion such as chlorine and sulfate ions from seawater. Chloride attack deteriorates the performance of the structure by corroding reinforcing bars. In addition, the waste water treatment structure has a problem that the concrete is deteriorated by the sulfate generated inside. Therefore, in this study, the characteristics and chemical resistance of low heat cement concrete used in wastewater treatment structures constructed on reclaimed land were evaluated. As a result of the experiment, the target slump and air content were satisfied under all the mixing conditions. The slump of low heat cement (LHC) concrete was higher than that of ordinary portland cement (OPC) concrete, while the air content of LHC concrete was smaller than that of OPC concrete with the same mix proportion. As a result of compressive strength test, OPC concrete showed higher strength at younger age compared to 28 days. In contrast, LHC concrete exhibited higher strength than OPC concrete at the age of 56 days. As a result of chlorine ion penetration tests, LHC-B concrete showed chlorine ion penetration resistance performance of the "very low" level at the age of 56 days. As a result of chemical resistance evaluation, when the LHC concrete is applied without epoxy treatment, chemical resistance is improved by about 18% compared to OPC concrete. In testing chemical resistance, the epoxy coated concrete exhibited less than 5% strength reduction when compared to sound concrete.

Mechanical and durability properties of fly ash and slag based geopolymer concrete

  • Kurtoglu, Ahmet Emin;Alzeebaree, Radhwan;Aljumaili, Omar;Nis, Anil;Gulsan, Mehmet Eren;Humur, Ghassan;Cevik, Abdulkadir
    • Advances in concrete construction
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    • v.6 no.4
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    • pp.345-362
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    • 2018
  • In this paper, mechanical and short-term durability properties of fly ash and slag based geopolymer concretes (FAGPC-SGPC) were investigated. The alkaline solution was prepared with a mixture of sodium silicate solution ($Na_2SiO_3$) and sodium hydroxide solution (NaOH) for geopolymer concretes. Ordinary Portland Cement (OPC) concrete was also produced for comparison. Main objective of the study was to examine the usability of geopolymer concretes instead of the ordinary Portland cement concrete for structural use. In addition to this, this study was aimed to make a contribution to standardization process of the geopolymer concretes in the construction industry. For this purpose; SGPC, FAGPC and OPC specimens were exposed to sulfuric acid ($H_2SO_4$), magnesium sulfate ($MgSO_4$) and sea water (NaCl) solutions with concentrations of 5%, 5% and 3.5%, respectively. Visual inspection and weight change of the specimens were evaluated in terms of durability aspects. For the mechanical aspects; compression, splitting tensile and flexural strength tests were conducted before and after the chemical attacks to investigate the residual mechanical strengths of geopolymer concretes under chemical attacks. Results indicated that SGPC (100% slag) is stronger and durable than the FAGPC due to more stable and strong cross-linked alumina-silicate polymer structure. In addition, FAGPC specimens (100% fly ash) showed better durability resistance than the OPC specimens. However, FAGPC specimens (100% fly ash) demonstrated lower mechanical performance as compared to OPC specimens due to low reactivity of fly ash particles, low amount of calcium and more porous structure. Among the chemical environments, sulfuric acid ($H_2SO_4$) was most dangerous environment for all concrete types.

Resistance to Sulfate Attack of Concrete Containing LCD glass powder Using Industrial By-products (산업부산물을 활용한 LCD 유리 미분말 혼입 콘크리트의 황산염침식 저항성)

  • Kim, Seong-Kyum;Song, Jae-Ho
    • Journal of the Society of Disaster Information
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    • v.15 no.2
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    • pp.239-248
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    • 2019
  • Purpose: This study aims to enhance the resistance against sulfate attack compared to ordinary Portland cement (OPC) concrete by using liquid crystal display (LCD) as binder. Method: The fundamental properties including compressive strength and porosity of concrete replaced by LCD up to 15% at increments of 5% and in turn, the weight, volume, and strength loss of LCD-mixed concrete was analyzed. Results: For the concrete substituted by 5% of LCD, it showed the highest compressive strength at 28 days of curing, and particular at immersion of $Na_2SO_4$ solution, it was achieved the lowest loss of weight, volume and strength due to an decreased porosity at capillaries. In contrast, there is no distinct difference of the sulfate attack resistance between LCD-mixed concretes under exposure of $MgSO_4$ solution, excepted for OPC concrete. Conclusion: In this study, comparison of resistance to sulfate attack between LCD-mixed concretes, and it would be proposed the possibility of LCD usage as binder through long-term verification with extended replacement ratio and identification of changes of hydrates in the cement matrix.

Durability Properties and Microstructure of Ground Granulated Blast Furnace Slag Cement Concrete

  • Divsholi, Bahador Sabet;Lim, Tze Yang Darren;Teng, Susanto
    • International Journal of Concrete Structures and Materials
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    • v.8 no.2
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    • pp.157-164
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    • 2014
  • Ground granulated blast-furnace slag (GGBS) is a green construction material used to produce durable concrete. The secondary pozzolanic reactions can result in reduced pore connectivity; therefore, replacing partial amount of Portland cement (PC) with GGBS can significantly reduce the risk of sulfate attack, alkali-silica reactions and chloride penetration. However, it may also reduce the concrete resistance against carbonation. Due to the time consuming process of concrete carbonation, many researchers have used accelerated carbonation test to shorten the experimental time. However, there are always some uncertainties in the accelerated carbonation test results. Most importantly, the moisture content and moisture profile of the concrete before the carbonation test can significantly affect the test results. In this work, more than 200 samples with various water-cementitious material ratios and various replacement percentages of GGBS were cast. The compressive strength, electrical resistivity, chloride permeability and carbonation tests were conducted. The moisture loss and microstructure of concrete were studied. The partial replacement of PC with GGBS produced considerable improvement on various properties of concrete.

Effect of Fineness Levels of GGBFS on the Strength and Durability of Concrete (콘크리트의 강도 및 내구성에 대한 고로슬래그미분말 분말도의 영향)

  • Lee, Seung Tae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.4
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    • pp.1095-1104
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    • 2014
  • This paper presents the results of experimental work on both strength characteristics and durability of concrete or mortar having 50% ground granulate blastfurnace slag(GBS) with different fineness levels (4,450, 6,000 and $8,000cm^2/g$). Compressive and split tensile strength test results indicated that the concrete with a higher fineness level of GBS exhibited a better strength development due to the acceleration of latent hydraulic property at the later curing stage compared with ordinary portland cement concrete. Meanwhile, it was found that a higher fineness level of GBS showed some negative effects on the resistance against freezing-thawing action. However, incorporation of GBS to concrete, irrespective of fineness levels, significantly enhanced the chloride ions penetration resistance. The resistance against sulfate attack of mortar with GBS was greatly dependent on the attacking sources from sulfate environments.

AN EXPERIMENTAL STUDY ON THE PROPERTIES & APPLICATION FOR FLY ASH OF CONBINED HEAT POWER PLANT - FOCUSSED HIGH STRENGTH CONCRETE - (열병합발전소 플라이애쉬의 특성 및 활용방안에 관한 실험적 연구 -고강도 콘크리트를 중심으로-)

  • 권영호;백명종;이보근;박칠림
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.211-216
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    • 1994
  • This study dealt with the properties for fly ash of conbined heat power plant and application for concrete industry. For this purpose, fly ash sampled Ulsan conbined heat power plant and analyzed for physical and chemical properties. As analyzed results of fly ash, contents of $SiO_ and Al_O_ $in the fly ash of Ulsan were less than those of Thermo-electric power plant(Boryuing), but contents of CaO were tem times as much as those of Boryung, because of these differences, it is expected that pozzolanic activity of concrete using fly ash of Ulsan will be different from another fly ash. Concrete specimens were tested to evaluate concrete preformance when 10 to 50 percent of the portland cement by weight in the concrete mix was replaced with fly ash of conbined heat power plant. As test results, workability and consideration in the fresh concrete were increased and concrete strength was showed more than 400kg/$\textrm{cm}^2$ for the required age. This study would be provided valuable data for the practical utilization of fly ash(conbined heat power plant). In the future, properties of fly ash concrete including long term strength, elapsed time, pozzolanic activity, modulus of elasticity, sulfate resistance, shrinkage, freeze-thaw durability and so on will be studied.

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An Experimental Study on Early Strength and Drying Shrinkage of High Strength Concrete Using High Volumes of Ground Granulated Blast-furnace Slag(GGBS) (고로슬래그 미분말을 대량 사용한 고강도 콘크리트의 조기강도 및 길이변화 특성에 관한 실험적 연구)

  • Yang, Wan-Hee;Ryu, Dong-Woo;Kim, Woo-Jae;Park, Dong-Cheol;Seo, Chee-Ho
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.4
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    • pp.391-399
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    • 2013
  • For high strength concrete of 40~60 MPa, the effects on the early strength and concrete dry shrinkage properties replacing 60~80% of Ordinary Portland Cement with Blast Furnace Slag Powder and using the Alkali Activator (Modified Alkali Sulfate type) are considered in this study. 1% Alkali Activator to the binder, cumulative heat of hydration for 72 hours was increased approximately 45%, indicating that heat of hydration contributes to the early strength of concrete, and the slump flow of concrete decreased slightly by 3.7~6.6%, and the 3- and 7- strength was increased by 8~12%, which that the Alkali Activator (Modified Alkali Sulfate type) is effective for ensuring the early strength when manufacturing High Strength Concrete (60%) of Blast Furnace Slag Powder. Furthermore, the dry shrinkage test, both 40 MPa and 60 MPa specimens had level of length changes in order of BS40 > BS60 > BS60A > BS80A, and the use of the Alkali Activator somewhat improved resistance to dry shrinkage.