• 제목/요약/키워드: sulfate environment

검색결과 516건 처리시간 0.021초

都市大氣中 黃酸鹽과 窒酸鹽 關한 硏究 (A Study of Size Distribution of Sulfate and Nitrate in Urban Air)

  • 신상은;김승학;김희강
    • 한국대기환경학회지
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    • 제2권1호
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    • pp.33-39
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    • 1986
  • Particulate matter was collected by Andersen Air Sampler in the Seoul area during February-October, 1985, in order to investigate size distribution of sulfate and nitrate in aerosol, and conversion of sulfur dioxide to sulfate and that of nitrogen dioxide to nitrate. The size distribution of sulfate and nitrate had fine mode. The ratio of fine sulfate to total sulfate in aerosol and that of fine nitrate to total nitrate showed between 54.6% and 86%, and 55.7% and 95%, respectively, which presumably originated from gaseous reaction of sulfur dioxide and nitrogen dioxide in the atmosphere.

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RO 농축폐액의 처리를 위한 이온교환수지의 생물재생 (Bio-regeneration of Ion-exchange Resin for Treating Reverse Osmosis Concentrate)

  • 배병욱;남윤우
    • 한국물환경학회지
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    • 제30권5호
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    • pp.517-523
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    • 2014
  • In order to remove both nitrate and sulfate present in the concentrate of RO(reverse osmosis) process, a combined bio-regeneration and ion-exchange(IX) system was studied. For this purpose, both denitrifying bacteria(DNB) and sulfate reducing bacteria(SRB) were simultaneously cultivated in a bio-reactor under anaerobic conditions. When the IX column containing a nitrate-selective A520E resin was fully exhausted by nitrate and sulfate, the IX column was bio-regenerated by pumping the supernatant of the bio-reactor, which contains MLSS concentration of $125{\pm}25mg/L$, at the flowrate of 360 BV/hr. Even though the nitrate-selective A520E resin was used, the breakthrough curves of ionic species showed that sulfate was exhausted earlier than nitrate. The reason for this result is due to the fact that the concentration of sulfate in RO concentrate was 36 to 48 times higher than nitrate. The bio-reactor was successfully operated at a volumetric loading rate of 0.6 g $COD/l{\cdot}d$, nitrate-N loading rate of 0.13 g $NO_3{^-}-N/l{\cdot}d$, and sulfate loading rate of 0.08 g $SO_4{^{2-}}/l{\cdot}d$. The removal rate of SCOD, nitrate-N, sulfate was 90, 100, and 85%, respectively. When the virgin resin was fully exhausted and consecutively bio-regenerated for 2 days, 81% of nitrate and 93% of sulfate were reduced. When the virgin resin was repeatedly used up to 4 cycles of service and bio-regeneration, the ion-exchange capacity of bio-regenerated resin decreased to 95, 91, 88, and 81% of virgin resin.

Sources and Behaviors of Nitrate and Sulfate in Riverside Alluvial Aquifer

  • Choi Byoung-Young;Yun Seong-Taek;Kim Kyoung-Ho;Kim Kang-Joo
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2005년도 INTERNATIONAL SYMPOSIUM ON SOIL & GROUNDWATER ENVIRONMENT
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    • pp.271-273
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    • 2005
  • The ${\delta}^{15}N\;and\;{\delta}^{15}O$ data of nitrate indicates the sources of nitrate in oxic groundwater as a mixture of ammonia or urea-containing fertilizer and manure. The ${\delta}^{34}S_{sulfate}$ values indicate that sulfate Is mainly originated from fertilizers and soil S. In sub-oxic groundwater, the increased ${\delta}^{34}S_{sulfate}$ values evidently indicate that sulfate is gradually removed by microbial mediated sulfate reduction. However, iron reduction does not occur In this study area. Such a reversed redox sequence may occur In the presence of stable iron oxides such as hematite and goethite in alluvlal aquifer.

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깔짚에서 발생되는 가스와 휘발성지방산에 대한 황산알루미늄과 비교 시 혼합 홍삼박제제의 평가: 축산환경 경영관점에서 (Evaluation of Mixed Korean Red Ginseng Marc with Aluminum Sulfate on Gas Concentration and VFA in Poultry Litter in Comparison with Aluminum Sulfate: In Terms of Livestock and Environment Managements)

  • 최인학
    • 한국환경과학회지
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    • 제24권4호
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    • pp.549-554
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    • 2015
  • This study was conducted to determine the effects of mixed Korean red ginseng marc with aluminum sulfate on gas concentration and volatile fatty acid (VFA) in poultry litter during 4 weeks in terms of livestock and environment managements. A total of 240 broiler chicks were randomly allocated to four treatments in four replications and 15 birds per replicate. The four treatments was mixed to rice hull under each pen at 0, 10 g or 20 g red ginseng marc + 90g aluminum sulfate, and 100g aluminum sulfate per kg poultry litter (rice hulls). Carbon dioxide, methane, acetic acid, and propionic acids were measured weekly. The results that could be available include: First, during the experimental period, carbon dioxide emissions were not remarkably different among treatments. Second, no differences were observed among treatments in methane emissions at 2 weeks through 4 weeks, but at 1 week, the reduction in methane emissions was in following order: 100 g aluminum sulfate > 20 g red ginseng marc + 90 g aluminum sulfate > 10 g red ginseng marc + 90 g aluminum sulfate > control. Third, in spite of statistically differences, treatment with 10 g or 20 g red ginseng marc + 90g aluminum sulfate, and 100g aluminum sulfate reduced acetic acid and propionic acid as a function of time, except acetic acid in aluminum sulfate treatment at 2 and 4 weeks. In conclusion, the results indicated that like aluminum sulfate, using 10 g or 20 g red ginseng marc with aluminum sulfate was effective in decreasing methane and propionic acid released from poultry litter.

Performance of FRP confined and unconfined geopolymer concrete exposed to sulfate attacks

  • Alzeebaree, Radhwan;Gulsan, Mehmet Eren;Nis, Anil;Mohammedameen, Alaa;Cevik, Abdulkadir
    • Steel and Composite Structures
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    • 제29권2호
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    • pp.201-218
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    • 2018
  • In this study, the effects of magnesium sulfate on the mechanical performance and the durability of confined and unconfined geopolymer concrete (GPC) specimens were investigated. The carbon and basalt fiber reinforced polymer (FRP) fabrics with 1-layer and 3-layers were used to evaluate the performances of the specimens under static and cyclic loading in the ambient and magnesium sulfate environments. In addition, the use of FRP materials as a rehabilitation technique was also studied. For the geopolymerization process of GPC specimens, the alkaline activator has selected a mixture of sodium silicate solution ($Na_2SiO_3$) and sodium hydroxide solution (NaOH) with a ratio ($Na_2SiO_3/NaOH$) of 2.5. In addition to GPC specimens, an ordinary concrete (NC) specimens were also produced as a reference specimens and some of the GPC and NC specimens were immersed in 5% magnesium sulfate solutions. The mechanical performance and the durability of the specimens were evaluated by visual appearance, weight change, static and cyclic loading, and failure modes of the specimens under magnesium sulfate and ambient environments. In addition, the microscopic changes of the specimens due to sulfate attack were also assessed by scanning electron microscopy (SEM) to understand the macroscale behavior of the specimens. Results indicated that geopolymer specimens produced with nano-silica and fly ash showed superior performance than the NC specimens in the sulfate environment. In addition, confined specimens with FRP fabrics significantly improved the compressive strength, ductility and durability resistance of the specimens and the improvement was found higher with the increased number of FRP layers. Specimens wrapped with carbon FRP fabrics showed better mechanical performance and durability properties than the specimens wrapped with basalt FRP fabrics. Both FRP materials can be used as a rehabilitation material in the sulfate environment.

Episodic Particulate Sulfate and Sulfur Dioxide on the Southwestern Japan Coast in March and April 2010

  • Nagatani, Tetsuji;Yamada, Maromu;Kojima, Tomoko;Zhang, Daizhou
    • Asian Journal of Atmospheric Environment
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    • 제6권1호
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    • pp.41-52
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    • 2012
  • Particulate sulfate in $PM_{2.5}$, sulfur dioxide ($SO_2$) and size-segregated aerosol particle number concentrations were measured at a site ($32^{\circ}19'N$, $129^{\circ}59'E$) on the southwestern Japan coast from 5 March to 10 April, 2010. Results show frequent episodic increases of sulfate and $SO_2$. Compared to the average concentration of sulfate $4.4{\pm}2.7\;{\mu}g\;m^{-3}$ in the whole observation period, episodic sulfate reached $10.5-20.1\;{\mu}g\;m^{-3}$. The variation of sulfate always synchronized with aerosol particles in the size range of $0.1-0.5 {\mu}m$, indicating the episodic sulfate was a consequence of the increase of the sub-micron particles. $SO_2$ did not have remarkable increase in any episodes of sulfate increase. During the passage of low pressure systems which loaded Asian dust in postfrontal air, concentrated sulfate appeared right behind the front but before dust arrival, suggesting the dominance of dust-free particulate sulfate. Weather and backward trajectory analyses revealed that air parcels with high sulfate passed eastern and northeastern China or Korean peninsula before arriving at the site. In contrast, those with high $SO_2$ passed an active volcano, Mt. Sakurajima, about 100 km in the south, suggesting the $SO_2$ was more likely from the volcanic emission. The ratio of sulfate to total sulfur compounds $({SO_4}^{2-})/({SO_4}^{2-}+SO_2)$ was 0.31-0.89 in continentally originated air while was 0.25-0.43 in the air having passed the volcano, showing more efficient conversions of $SO_2$ to sulfate in the air from the continent. The close dependence of the conversion on humidity in the continentally originated air was confirmed.

다양한 환경요인과 난분해성 유기물에 따른 고온산화 및 UV산화방식 총 유기탄소 산화율 변화 (Influences of Environmental Conditions and Refractory Organic Matters on Organic Carbon Oxidation Rates Measured by a High Temperature Combustion and a UV-sulfate Methods)

  • 정헌재;이보미;이근헌;신현상;허진
    • 한국물환경학회지
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    • 제32권1호
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    • pp.98-107
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    • 2016
  • This study examined the effects of environmental conditions and the presence of refractory organic matter on oxidation rates of total organic carbon (TOC) measurements based on high temperature combustion and ultraviolet-sulfate methods. Spectroscopic indices for prediction of oxidation rates were also explored using the UV spectra and fluorescence excitation-emission matrix (EEM) of humic acids. Furthermore, optimum TOC instrument conditions were suggested by comparing oxidation rates of a standard TOC material under various conditions. Environmental conditions included salts, reduced ions, and suspended solids. Salts had the greatest influence on oxidation rates in the UV-sulfate method. However, no effect was detected in the high temperature combustion method. The UV-sulfate method showed lower humic substance oxidation rates, refractory natural organic matter, compared to the other methods. TOC oxidation rates for the UV-sulfate method were negatively correlated with higher specific-UV absorbance, humification index, and humic-like EEM peak intensities, suggesting that these spectroscopic indices could be used to predict TOC oxidation rates. TOC signals from instruments using the UV-sulfate method increased with increasing chamber temperature and increasing UV exposure durations. Signals were more sensitive to the former condition, suggesting that chamber temperature is important for improving the TOC oxidation rates of refractory organic matter.

STEM II를 이용한 한국과 중국동부 지역의 대기오염물질 이동/화학/침착 모사에 관한 연구 (Application of the STEM II to air pollutant transport/chemistry/ deposition in the Korea and Eastern China Area)

  • 이상인;조석연;심상규
    • 한국대기환경학회지
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    • 제11권2호
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    • pp.163-170
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    • 1995
  • The STEM II(Sulfur Transport Eulerian Model II) was adapted to investigate air pollutant transport phenomena between Eastern China and Korea. The movement of the high concentration region was clearly identified for the sulfate but was mot visible for SO$_{2}$. The 10.sim. 16 times more amount of SO$_{2}$ is transported to Korea compared to that of the local emission while the amount of the sulfate transported to Korea is 1 .sim. 1.3 times more than that of the sulfate produced by photo-chemical reaction in Korea. APTIs(Air Pollutant Transport Indices) for SO$_{2}$ and sulfate are approximately 0.85, which implies that the most of the SO$_{2}$ and sulfate existed in Korea are transported from Eastern China.

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Sulfate Reduction for Bioremediation of AMD Facilitated by an Indigenous Acid- and Metal-Tolerant Sulfate-Reducer

  • Nguyen, Hai Thi;Nguyen, Huong Lan;Nguyen, Minh Hong;Nguyen, Thao Kim Nu;Dinh, Hang Thuy
    • Journal of Microbiology and Biotechnology
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    • 제30권7호
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    • pp.1005-1012
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    • 2020
  • Acid mine drainage (AMD) has been a serious environmental issue that threatens soil and aquatic ecosystems. In this study, an acid-tolerant sulfate-reducing bacterium, strain S4, was isolated from the mud of an AMD storage pond in Vietnam via enrichment in anoxic mineral medium at pH 5. Comparative analyses of sequences of the 16S rRNA gene and dsrB gene involved in sulfate reduction revealed that the isolate belonged to the genus Desulfovibrio, and is most closely related to Desulfovibrio oxamicus (with 99% homology in 16S rDNA sequence and 98% homology in dsrB gene sequence). Denaturing gradient gel electrophoresis (DGGE) analyses of dsrB gene showed that strain S4 represented one of the two most abundant groups developed in the enrichment culture. Notably, strain S4 was capable of reducing sulfate in low pH environments (from 2 and above), and resistance to extremely high concentration of heavy metals (Fe 3,000 mg/l, Zn 100 mg/l, Cu 100 mg/l). In a batch incubation experiment in synthetic AMD with pH 3.5, strain S4 showed strong effects in facilitating growth of a neutrophilic, metal sensitive Desulfovibrio sp. strain SR4H, which was not capable of growing alone in such an environment. Thus, it is postulated that under extreme conditions such as an AMD environment, acid- and metal-tolerant sulfate-reducing bacteria (SRB)-like strain S4 would facilitate the growth of other widely distributed SRB by starting to reduce sulfate at low pH, thus increasing pH and lowering the metal concentration in the environment. Owing to such unique physiological characteristics, strain S4 shows great potential for application in sustainable remediation of AMD.

염류집적 농경지의 전기동력학적 정화 (Electrokinetic Restoration of Saline Agricultural Land)

  • 조성웅;김도형;양중석;정근욱;백기태
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제17권4호
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    • pp.19-26
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    • 2012
  • The influence of operation time on electrokinetic restoration was investigated to remove salts from sulfate-accumulated greenhouse soil. Operation time is directly related to the process cost, therefore, we determined the relationship between operation time and removal of salts. Nitrate and sodium were removed almost completely within 2 weeks, chloride and calcium was removed in proportion to the operation time. Sulfate was accumulated at the center of anode and cathode. The soil electrical conductivity (EC), an indicator for soil salinity, showed similar shape with the residual sulfate after electrokinetic treatment. The soil EC was not changed after 2 weeks, however, the energy consumption increased with operation time. Based on the experimental results, most salts except sulfate were removed within 2 weeks, but sulfate was not removed during same time period. For the further removal of sulfate, longer operation time is in need.