• 한국가스학회:학술대회논문집
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• 한국가스학회 2001년도 추계학술발표회 논문집
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• pp.58-68
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• 2001

Microbiologically influenced corrosion (MIC) of carbon steel gas pipeline in soil environments was investigated at field and laboratory MIC is very severe corrosion and it is not easy to distinguish this corrosion from Inorganic corrosion because of its localized, pitting-type character Therefore, it is important to provide proper assessment techniques for the prediction, detection, monitoring and mitigation of MIC. It is possible to predict the MIC risk, i.e., the activity of sulfate-reducing bacteria (SRB) through the analysis of soil environments. Chemical, microbiological and surface analysis of corrosion products and metal attacked could reveal the possibility of the occurrence of MIC. Various electrochemical and surface analysis techniques could be used for the study of MIC. Among these techniques, thin-film electrical resistance (ER) type sensors are promising to obtain localized corrosion rate of MIC induced by SRB. It is also important to study the effect of cathodic protection (CP) on the MIC In case of coated pipeline, the relationship between coating disbondment and the activity of SRB beneath the disbanded coating is also important.

• Corrosion Science and Technology
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• 제14권6호
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• pp.267-272
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• 2015

The performance of three tubular materials (C-90, L-80, and N-80) was evaluated in a synthetic brine inoculated with sulfate-reducing bacteria (SRB) in the absence and presence of biocides. A flow loop was used in the evaluation of the three alloys. Morphological examination of the alloy surfaces after exposure to SRB and after biocide treatment was performed by scanning electron microscopy (SEM) to determine the nature of any localized corrosion. The SE images of the coupon samples showed a marked difference between the biocide-treated and untreated samples. Small pits were observed on the ultrasonically cleaned surfaces of the three alloys after exposure to SRB. The biocide treatment reduced the number of SRB on the surfaces of the alloys. Results indicated that C-90 and L-80 alloys exhibited better MIC resistance than N-80 under the conditions used in this study.

• 콘크리트학회논문집
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• 제16권1호
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• pp.1-9
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• 2004

본 논문은 고로슬래그미분말을 혼화한 콘크리트의 염화물 침투 및 철관 발청 성능을 평가한 것이다. 실험에는 1종 보통포틀랜드시멘트와 5종 내황산염시멘트 사용하였으며, 고로슬래그는 이들 시멘트 대신에 각각 $25\%$, $40\%$ 및 $55\%$를 치환하였다. 촉진 염화물 침투 시험결과에 대한 평가는 ASTM C 1202에 규정에 따랐으며, 철근 발청은 건습반복에 의한 촉진 시험에 의해 수행되었다. 시험체는 콘크리트로 제작하였으며, 각각 수중양생 28일, 56일 및 91일간 실시하였다. 모든 콘크리트 시험체는 3일간 염수 침지한 후 4일간 건조로에서 건조시키는 것을 1 cycle로 정하여 30 cycle에서 시험을 종료하는 것으로 하였다. 염수 침지 조건은 수온 $40^{\circ}C$, NaCl $3^{\circ}C$로 하였으며, 시험체의 건조는 건조로를 사용하여 $60^{\circ}C$에서 건조시키는 것으로 하였다. 시험결과, 고로슬래그미분말을 혼화한 1종 시멘트를 사용한 콘크리트 시험체의 염소이온 확산계수는 무치환의 경우에 비해 상당히 감소하였으며, 5종 시멘트를 사용한 경우에 있어서는 1종 시멘트를 사용한 시험체에 비해 염소이온의 확산계수는 증가하는 것으로 나타났다. 촉진시험에 의한 철근 발청은 고로슬래그미분말의 사용에 의해 상당한 저항성을 갖고 있으며, 5종 시멘트를 사용한 경우에는 철근 발청이 증가하는 현상을 나타내었다.

• 펄프종이기술
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• 제37권3호
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• pp.59-65
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• 2005

There are accumulations of remained chemical additives and contaminants in the process water of semi-closed linerboard mill. High temperature of the process water aggravates the anaerobic digestion of contaminated process water and causes the generation of hazardous gases, which are from the biological reaction of varied additives and contaminants. The hydrogen sulfide in the gases easily combine with moisture in the air, and become sulfuric acid, which causes corrosion of paper machinery. This hydrogen sulfide is from the reduction of sulfate ions in the process water, and the sulfate ions are mostly from the alum. We changed the alum to PAC (Poly Aluminum Chloride). The results were preventing generation of hydrogen sulfide, and equivalent sizing effect by the use of PAC.

• 한국광물학회지
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• 제26권4호
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• pp.219-228
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• 2013

방사성 폐기물을 지하에 장기 보관하는 금속 용기에 관한 생지화학적 부식 특성을 알아보기 위해 주철과 구리로 된 금속재료를 환원조건 하에서 디설프리칸스 황산염환원미생물과 3개월간 반응시켰다. 금속재료의 화학적/광물학적 변화를 알아보기 위해 주기적으로 용존 금속이온들의 농도를 측정하였으며, 실험이 종료된 이후 금속 시편 및 표면 이차생성물들을 전자현미경을 이용하여 분석하였다. 디설프리칸스가 없는 조건에서는 금속재료의 부식이 매우 미약하였으나, 미생물이 있는 경우에는 부식이 상대적으로 컸다. 관찰된 생지화학적 부식 산물은 주로 맥키나와이트와 황화구리 같은 검은색의 금속황화물이었으며, 표면에서 쉽게 분리되거나 콜로이드화되어 부유하였다. 특히, 구리 시편의 경우 용액 상에 용존 철이 존재할 때 세균에 의한 구리 부식의 가속화가 관찰되었는데, 이는 구리 표면에 다른 종의 황화철이 성장하면서 구리 간의 결속력을 약화시켰기 때문인 것으로 보인다.

• Corrosion Science and Technology
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• 제16권5호
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• pp.227-234
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• 2017

Reference electrodes are generally implemented for the purpose of monitoring the cathodic protection potentials of buried or immersed metallic structures. In the market, many types of reference electrodes are available for this purpose, such as saturated calomel, silver/silver chloride and copper/copper sulfate. These electrodes contain a porous ceramic junction plate situated in the cylindrical body bottom to permit ionic flux between the internal electrolyte (of the reference electrode) and the external electrolyte. In this work, the copper/copper sulfate reference electrode was modified by replacing the porous ceramic junction plate for a metallic platinum wire. The main purpose of this modification was to avoid the ion copper transport from coming from the inner reference electrode solution into the surrounding electrolyte, and to mitigate the copper plating on the coupon surfaces. Lab tests were performed in order to compare the performance of the two mentioned reference electrodes. We verified that the experimental errors associated with the measurements conducted with developed reference electrode would be negligible, as the platinum surface area exposed to the surrounding electrolyte and/or to the reference electrolyte are maintained as small as possible.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 봄 학술발표회 논문집(I)
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• pp.789-792
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• 1999

Reinforced concrete structures covered creek for road vehicle located in urban areas have been experiencing corrosion of concrete and reinforcing steel caused by $H_2S$ gases generated by anaerobic bacterial. H2S gases react with oxygen and water to form sulfuric acid ($H_2SO_4$). This acid chemically attacks concrete, and sulfate ions penetrate into the concrete, causing rebar corrosion. In this work, to determine the conditions of RC culvert boxes which were constructed in the 1970s, various tests were conducted, including carbonation depth, compressive strength, half-cell potential measurements, and XRD analyses. Results indicated that the concrete deterioration was caused by sulfate attack and rebar corrosion. This paper discusses the evaluation on the durability of reinforced concrete structures covered creek for road vehicle.

• 대한화학회지
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• 제57권2호
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• pp.264-271
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• 2013

Corrosion inhibition of mild steel used in water station in 35 ppm aluminum sulfate and 10 ppm chloride solution by Camellia sinensis leaves extract was studied using weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy techniques at $30^{\circ}C$. Results show that the inhibition efficiency increases with increasing concentration of the extract and decreases with increasing temperature. Inhibitive effect was afforded by adsorption of the extract's components which was found to accord with Langmuir adsorption isotherm. Inhibition mechanism is deduced from the temperature dependence of the inhibition efficiency and was further corroborated by the values of activation parameters obtained from the experimental data.

• Corrosion Science and Technology
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• 제6권3호
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• pp.140-146
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• 2007

In the paper, with corrosion velocity measurement and metallographic observation on specimens after sulfuric acid/ferric sulfate boiling experiment, intergranular corrosion tendency of the new type ultra low carbon stainless steel developed by ourselves which experienced solution treatment at different temperatures was evaluated. A VHX 500 super depth field tridimensional microscope was used to observe corrosion patterns on the sample surfaces. The depth and width of grain boundary corrosion groove were measured by the tridimensional microscope, which indicated that the corrosion degrees of the samples which received solution treatment at different temperatures are quite different. Transgranular corrosion at different degree occurred along with forged glide lines. After comparison it was proved that the stainless steel treated at $1100^{\circ}C$ performs very well against intergranular corrosion.

• 보존과학연구
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• 통권32호
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• pp.89-98
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• 2011

철 부식화합물은 부식인자들과 함께 다양한 결정구조를 가지며 2가지 이상의 부식화합물들이 혼합되어 존재하므로 각각의 특성을 밝혀내기가 매우 어렵다. 본 연구는 표준 철 부식물을 대상으로 Raman Micro-Spectroscopy 분석을 실시하여 표준 Raman Data 확보를 목적으로 수행하였다. 표준 철 부식물에 대한 신뢰성을 향상시키기 위하여 SEM-EDS 분석과 XRD 분석을 추가로 실시하였다. SEM-EDS 분석결과 모두 표준 철 부식물의 구성성분과 일치하였으나 Goethite의 경우 철 이외의 비철금속 성분이 검출되었다. XRD 분석 결과 모두 표준 철 부식물의 구조와 일치 하였으나 Iron sulfate($FeSO_4{\cdot}6H_2O$)의 경우 Rozenite($FeSO_4{\cdot}4H_2O$)로 확인되었다. Raman Micro-Spectroscopy 분석결과 기존에 연구되었던 수산화철, 산화철의 Wavenumber에서 새로운 peak이 발견되었는데 이는 레이저 파장의 변화에 따른 것으로 사료 된다. 염화철과 황산철에서 Wavenumber가 새롭게 확인되어 표준 Raman Data 8건을 확보하였다. Raman Micro-Spectroscopy는 적은양의 시료를 이용하여 물질의 특성과 구조를 비교적 간단하게 분석 할 수 있어 미세한 부분이나 시료의 양이 한정된 문화재에 활용도가 높을 것으로 판단된다.