• Title/Summary/Keyword: sublimation method

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A study on the Analogy between Heat Transfer and Mass Transfer (열전달과 물질전달의 유사성에 관한 연구)

  • 유성연;노종광;정문기
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.10
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    • pp.2624-2633
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    • 1993
  • Mass transfer experiment by naphthalene sublimation method has great advantages in measurement of local transfer coefficients in the region of a three dimensional flow or for a model of complex geometry, which is considered to be very difficult with conventional heat transfer measurements. Mass transfer data obtained by naphthalene sublimation technique are converted to the heat transfer data through heat/mass transfer analogy. This analogy is valid for a simple or laminar flow, but new insight is needed when applying to a turbulent flow or complex flow such as separation, reattachment and recirculation, The purpose of this research is to investigate how geometries and flow conditions incorporate heat/mass transfer analogy. Mass transfer experiments are performed using naphthalene sublimation technique for a flat plate, a circular cylinder, and rectangular cylinders. And mass transfer data are compared with earlier heat transfer measurements for the same geometries. Usefulness of analogy relation between heat and mass transfer is examined with these results.

Effects of Freeze Dry Control Parameters on the Sublimation Drying Time of Garlic paste (동결건조 제어변수가 마늘의 승화건조시간에 미치는 영향)

  • Park, N.H.;Bae, S.C.
    • Journal of Biosystems Engineering
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    • v.18 no.2
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    • pp.122-132
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    • 1993
  • Effects of physical properties of garlic paste and freeze dry control parameters on the sublimation drying time were investigated to verify optimal operating method in freeze drying. A mathematical model of freeze drying by sublimation was suggested and used to estimate the drying time of garlic paste. Under various conditions, the drying time of garlic paste was calculated using the computer program for the suggested model. Among the physical properties of garlic paste, melting temperature was evaluated the most important factor in affecting the drying time. In supplying methods of the required heat energy for sublimation, it would be the best way to control the upper plate temperature and the lower plate temperature independently.

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Characterization of 6H-SiC Single Crystals grown by Sublimation Method

  • Kim, Hwa-Mok;Kang, Seung-Min;Kyung Joo;Auh, Keun-Ho
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.06a
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    • pp.261-263
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    • 1997
  • 6H-SiC single crystals were successfully grown by the self-designed sublimation apparatus and the optimum growth condition was established. The grown SiC crystals were about 33mm in diameter and 10mm in length. Carrier concentration and doping type of undopped 6H-SiC wafer grown by sublimation method were 1016∼1017/㎤ and n-type Crystallinity of grown 6H-SiC wafer was better than of Acheson seed by data of Raman spectroscopy and Double Crystal XRD. We continue to characterize the grown 6H-SiC wafer in more detail and so we will grow the high-quality 6H-SiC single crystal wafer.

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Low temperature deposition of carbon nanofilaments using vacuum-sublimated $Fe(CO)_5$ catalyst with thermal chemical vapor deposition

  • Kim, Nam-Seok;Kim, Kwang-Duk;Kim, Sung-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.1
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    • pp.18-22
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    • 2007
  • Carbon nanofilaments were deposited on silicon oxide substrate by thermal chemical vapor deposition method. We used $Fe(CO)_5$ as the catalyst for the carbon nanofilaments formation. Around $800^{\circ}C$ substrate temperature, the formation density of carbon nanofilaments could be enhanced by the vacuum sublimation technique of $Fe(CO)_5$, compared with the conventional spin coating technique. Finally, we could achieve the low temperature, as low as $350^{\circ}C$, formation of carbon nanofilaments using the sublimated Fe-complex nanograins with thermal chemical vapor deposition. Detailed morphologies and characteristics of the carbon nanofilaments were investigated. Based on these results, the role of the vacuum sublimation technique for the low temperature deposition of carbon nanofilaments was discussed.

The Embedded Atom Method Analysis of the Palldium (Palladium의 Embedded Atom Method 개발)

  • 정영관;김경훈;김세웅;이성희;이근진;박규섭
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.05a
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    • pp.652-655
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    • 2002
  • The embedded atom method based on the density functional theory is used for calculating ground state properties of realistic metal systems. In this paper, we had corrected constitutive formulae and parameters on the palladium for the purpose of doing Embedded Atom Method analysis. And then we have computed the properties of the palladium on the fundamental scale of the atomic structure. In result, simulated ground state properties, such as the lattice constant, elastics constants and the sublimation energy, show good agreement with Daw's simulation data and with experimental data.

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The Embedded Atom Method Analysis of the Nickel (Nickel의 Embedded Atom Method 해석)

  • 정영관;김경훈;이근진;김종수
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.572-575
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    • 1997
  • The embedded atom method based on density functional theory was developed as a new means for calculating ground state properties of realistic metal system by Murray S. Daw, Stephen M. Foiles and Michael I. Baskes. In the paper, we had corrected constitutive formulae and parameters on the nickel for the purpose of doing Embedded Atom Method analysis. And then we have computed the properties of the nickel on the fundamental scale of the atomic structure. In result, simulated ground state properties, such as the lattice constant, elastics constants and sublimation energy, show good agreement with Daw's simulation data and with experimental data.

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Growth and Characteristics for $CdS_{0.69}Se_{0.31}$ single crystal by sublimation method (승화법에 의한 $CdS_{0.69}Se_{0.31}$ 단결정 성장과 특성)

  • Hong, Kwang-Joon;You, Sang-Ha;Kim, Jang-Bok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.157-158
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    • 2006
  • $CdS_{0.69}Se_{0.31}$ single crystal grown by sublimation method. Hall effect measurement were carried out by the Van der Pauw method. The measurement values under the temperature were found to be carrier density $n\;=\;1.95\;{\times}\;10^{23}m^3$, Hall coefcient $RH\;=\;-3.21\;{\times}\;10^{-5}m^3/c$, conductivity ${\sigma}\;=\;362.41\;{\Omega}^{-1}m^{-1}$, and Hall mobility ${\mu}\;=\;1.16\;{\times}\;10^{-2}m^2/v.s$.

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Characterizations of Two-step Matrix Application Procedures for Imaging Mass Spectrometry

  • Shimma, Shuichi
    • Mass Spectrometry Letters
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    • v.6 no.1
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    • pp.21-25
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    • 2015
  • In this paper, I describe the importance of matrix spraying conditions in imaging mass spectrometry (IMS) to obtain successful imaging results. My developed matrix application methodology, which is a "two-step matrix application" sequentially combined with matrix sublimation and spraying matrix solution can provide high reproducibility and high ion yield compared with a conventional direct spraying method. However, insufficient IMS results were obtained occasionally despite the two-step method. Therefore, I wanted to characterize the methodology to continuously provide high quality data. According to my results, the sublimation time was not a strict parameter, and the most important step was the first spraying condition. This means that the extraction conditions from the tissue section and co-crystallization of the matrix were the most important factors.

Thermodynamic Properties of Bismuth Trifluoride from Vapour Pressure Measurements (증기압 측정으로부터 BiF3의 열역학적 계산)

  • ;S. Blairs
    • Journal of the Korean Ceramic Society
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    • v.31 no.6
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    • pp.685-693
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    • 1994
  • Sublimation vapour pressures and sublimation enthalpy of anhydrous bismuth trifluoride have been measured by the continuous gravimetric Cnudsen-effusion method from 639-7 to 782.8 K. Additional effusion measurements have also been made from 750.6 to 863.1 K by the torsion-effusion method. Based on a correlation of subHo298.15 and subSo298.15, a recommended P(T) equation has been obtained for BiF3(s); logP= -C/T+5.2375logT-3.205$\times$10-3+4.661$\times$104/T2+1.348 where P is in Pa, T in Kelvin, subHo298.15 in kJ mol-1 and C=( subHo298.15-13.5149)/1.9146$\times$10-2. Condensation coefficients and their temperature dependence have been derived from the effusion measurements.

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