• Journal of the Korean Crystal Growth and Crystal Technology
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• v.31 no.5
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• pp.203-211
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• 2021

Octacalcium phosphate(OCP, Ca₈H₂(PO₄)₆·5H₂O) is one of biodegradable calcium phosphate materials with osteoconductivity and biocompatibility. It has the advantage of rapid bone formation and resorption due to the property of stimulating stromal cells to differentiate into osteoblasts. However, if OCP is inserted in body, it is immediately decomposed without maintaining of its shape as scaffolds due to their weak cohesive force between powder. On the other hand, hydroxyapatite (HA, Ca₁₀(PO₄)₆(OH)₂), which has a crystal structure similar to that of OCP, remains in the body without decomposition until the bone defect is restored. In this study, the degradation behavior of OCP/HA disc with different amount of HA in SBF (simulated body fluid) solution was characterized in terms of the weight loss, pH variation and microstructure change with immersion duration in SBF solution. As a result, the OCP/HA disc was not quickly decomposed and maintained its own shape for 2 weeks regardless of HA content. In particular, the surface of 40HA specimen was uniformly dissolved and then CDHA (calcium deficient hydroxyapatite) phase were formed onto the surface of disc after 7 days in SBF solution. It would be suggested that the 40HA specimen would be suitable candidate material as the scaffolds for the restoration of bone defect.

• Journal of Practical Agriculture & Fisheries Research
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• v.16 no.1
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• pp.55-66
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• 2014

This study has been conducted to investigate the treatment time and concentration of GA₃ solution dipping for labor saving in 'Campbell Early' grapevine. The rachis growth at harvest was reduced by GA₃ solution dipping before 5 days flowering, and increased significantly by GA₃ solution dipping treatment at full bloom and after 5 days full bloom. GA₃ 5, 10, 20 mg·L^-1 dipping treatment before 5 days flowering and GA₃ 20 mg·L^-1 treatment of full bloom and after 5 days full bloom showed a rachis twist phytotoxicity symptom. The optimum GA₃ concentrations for rachis growth promotion without phytotoxicity were 5 mg·L^-1 and 10 mg·L^-1. The degree of compact berry, bloom, skin color, SSC and acidity at harvest by GA₃ solution dipping treatment time between concentration were not different from those of control. But the fruit berry weight was decreased by before 5 days flowering treatment when compared with control. There were no differences in full bloom and after 5 days full bloom treatment. The occurrence percent of berry cracking at before 5 days flowering and after 5 days full bloom treatment were significantly increased by GA₃ treatment. The bitter rot occurrence of berry at harvest was not affected by GA₃ treatment. Total rachis length of fruit cluster was increased by full bloom and 5 days after full bloom treatment. The length of rachis increased without reference to them position at full bloom and 5 days after bloom treatment. Accordingly, GA₃ 5 mg·L^-1 solution dipping treatment at full bloom and 5 days after full bloom were can be effectively for rachis growth promotion.

• Bulletin of the Korean Chemical Society
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• v.25 no.1
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• pp.97-100
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• 2004

Tetragonal $K_2NiF_4$-type $La_{2-2x}Sr_{2x}Cu_{1-x}Fe_xO_{4-y}$ solid-solution have been synthesized by citrate based sol-gel method. The valence state of iron was determined by Mossbauer spectroscopy and subsequent iodometric titration clearly showed that the copper ions in this solid-solution are in the mixed valence state Cu(II/III). When x ${\geq}$ 0.3, Fe(III) is competing with the mixture of Cu(II) and Cu(III) and $La_{2-2x}Sr_{2x}Cu_{1-x}Fe_xO_{4-y}$ exhibits a metallic character. No evidence for Cu(II)-O-Fe(IV) ${\leftrightarrow}$ Cu(III)-O-Fe(III) valence degeneracy was observed. In contrast, a small amount of Fe(IV) is observed with increasing x (x = 0.4 and 0.5), revealing a semiconducting behavior. These results suggest that the electronic interaction of Cu(III)-O-Fe(III) contributes greatly to the metallic character, while the electronic interaction of Cu(II)-O-Fe(IV) deteriorates the metallic character of $La_{2-2x}Sr_{2x}Cu_{1-x}Fe_xO_{4-y}$.

• Korean Journal of Materials Research
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• v.27 no.5
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• pp.289-293
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• 2017

$Y_2Ti_2O_7$ nanoparticles (0.3 mol%) have been successfully synthesized by the co-precipitation process. The samples, adjusted to pH7 with ammonia solution as catalyst and calcined at $700{\sim}900^{\circ}C$, exhibit very fine particles with close to spherical shape and average size of 10-30 nm. It was possible to control the size of the synthesized $Y_2Ti_2O_7$ particles by manipulating the conditions. The $Y_2Ti_2O_7$ nanoparticles were coated on a glass substrate by a dipping coating process with inorganic binder. The $Y_2Ti_2O_7$ solution coated on the glass substrate had excellent adhesion of 5B; pencil hardness test results indicated an excellent hardness of 6H. The thickness of the thick film was about $30{\mu}m$. Decomposition of MB on the $Y_2Ti_2O_7$ thin film shows that the photocatalytic properties were excellent.

• Journal of Powder Materials
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• v.27 no.5
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• pp.394-400
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• 2020

Molybdenum trioxide (MoO₃) is used in various applications including sensors, photocatalysts, and batteries owing to its excellent ionic conductivity and thermal properties. It can also be used as a precursor in the hydrogen reduction process to obtain molybdenum metals. Control of the parameters governing the MoO₃ synthesis process is extremely important because the size and shape of MoO₃ in the reduction process affect the shape, size, and crystallization of Mo metal. In this study, we fabricated MoO₃ nanoparticles using a solution combustion synthesis (SCS) method that utilizes an organic additive, thereby controlling their morphology. The nucleation behavior and particle morphology were confirmed using ultraviolet-visible spectroscopy (UV-vis) and field emission scanning electron microscopy (FE-SEM). The concentration of the precursor (ammonium heptamolybdate tetrahydrate) was adjusted to be 0.1, 0.2, and 0.4 M. Depending on this concentration, different nucleation rates were obtained, thereby resulting in different particle morphologies.

• Korean Journal of Materials Research
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• v.15 no.12
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• pp.802-808
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• 2005

The hydrogen sorption speeds of $Zr_{57}V_{36}Fe_7$ amorphous alloy and its crystallized alloys were evaluated at room temperature $Zr_{57}V_{36}Fe_7$ amorphous alloy was prepared by ball milling. The amorphous alloy was crystallized through two stages. Initially, $\alpha-Zr$ solid solution was appeared from the amorphous phase. Two cubic Laves compounds were precipitated afterwards from the remained amorphous and from excessively saturated solid solution at higher temperature. The hydrogen sorption speed of the partially crystallized alloy was higher than that of amorphous. The enhanced sorption speed of partially crystallized alloy was explained in terms of surface oxygen stability which has been known to retard the activation of amorphous alloys. The retardation could be reduce by crystallization process resulting in the observed increase in sorption property.

• Smart Structures and Systems
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• v.29 no.5
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• pp.677-691
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• 2022

Water cycle algorithm (WCA) has been a very effective optimization technique for complex engineering problems. This study employs the WCA for simultaneous prediction of heating load (L_H) and cooling load (L_C) in residential buildings. This algorithm is responsible for optimally tuning a neural network (NN). Utilizing 614 records, the behavior of the L_H and L_C is explored and the captured knowledge is then used to predict for 154 unanalyzed building conditions. Since the WCA is a population-based algorithm, different numbers of the searching agents were tested to find the most optimum configuration. It was observed that the best solution is discovered by 500 agents. A comparison with five newly-developed benchmark optimizers, namely equilibrium optimizer (EO), multi-tracker optimization algorithm (MTOA), slime mould algorithm (SMA), multi-verse optimizer (MVO), and electromagnetic field optimization (EFO) revealed that the WCANN predicts the desired parameters with considerably larger accuracy. Obtained root mean square errors (1.4866, 2.1296, 2.8279, 2.5727, 2.5337, and 2.3029 for the L_H and 2.1767, 2.6459, 3.1821, 2.9732, 2.9616, and 2.6890 for the L_C) indicated that the most reliable prediction was presented by the proposed model. The EFONN, however, provided a more time-effective solution. Lastly, an explicit predictive formula was elicited from the WCANN.

• Nuclear Engineering and Technology
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• v.55 no.6
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• pp.2206-2214
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• 2023

The existing wet reconversion processes for the recovery of scraps generated in manufacturing of nuclear fuel are complex and require several unit operation steps. In this study, it is attempted to simplify the recovery process of high-quality fuel-grade UO₂ powder. A novel wet reconversion process for uranyl nitrate hexahydrate solution is suggested by using a newly developed pulsed fluidized bed reactor, and the resultant chemical characteristics are evaluated for the intermediate ammonium uranate hydrate product and subsequently converted UO₂ powder, as well as the compliance with nuclear fuel specifications and advantages over existing wet processes. The UO₂ powder obtained by the suggested process improved fuel pellet properties compared to those derived from the existing wet conversion processes. Powder performance tests revealed that the produced UO₂ powder satisfies all specifications required for fuel pellets, including the sintered density, increase in re-sintered density, and grain size. Therefore, the processes described herein can aid realizing a simplified manufacturing process for nuclear-grade UO₂ powders that can be used for nuclear power generation.

• Corrosion Science and Technology
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• v.21 no.5
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• pp.418-421
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• 2022

Stir-accelerated corrosion test of a high chromium cast iron was attempted in 0.1 mol dm^-3 H₂SO₄ + 0.05 mol dm^-3 HCl + 10 wt% SiC solution for 48 h at room temperature or at 45 ℃. The high chromium cast iron was composed of 2.8 wt% C and 27 wt% Cr and balanced with Fe. The high chromium cast iron was positioned into a 500 mL beaker with stirring of the solution at 1050 rpm using a magnetic hot plate. The corrosion rate was increased by agitating the solution. In addition, the corroded depth of the high chromium cast iron surface was increased by agitating the solution. The surface morphology of the high chromium cast iron after the stir-accelerated corrosion test revealed that a dendritic austenite phase partially remained in the corroded region after agitating the solution, indicating that solution movement during agitating could accelerate the corrosion rate of the high chromium cast iron.

• Korean Journal of Agricultural Science
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• v.49 no.3
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• pp.629-641
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• 2022

This research was conducted to secure fundamental data for development of a recirculating hydroponic system. To achieve this, Lycopersicum esculentum var. 'Dafnis' and 'TY Tiny' were grown with Yamazaki hydroponic solution and the inorganic element concentrations of plant leaves and nutrient solution of supplied and drained were analyzed periodically. The T-N and P contents in both varieties of tomato leaves showed gradual decreasing tendencies with the passage of time. The 'TY Tiny' tomato had higher contents of those two nutrients than 'Dafnis' tomato in the late stage. The K content of 'Dafnis' tomato was high in the early growth stage, but low in the late stage. However, that of 'TY Tiny' tomatoes rose in the late stage. The Ca content gradually increased in both varieties of tomato in the latter stages. The EC of the drained nutrient solution in both varieties of tomato showed increasing tendencies as time had passed, but the pH was get lowered in the drained solution. The concentrations of NO₃-N, K, Ca, Mg, Na, Fe, and B, except PO₄-P in the drained nutrient solution were generally higher than those in the supplied solution, especially in the period of October through December. The above results can be used for controlling of nutrient concentrations in the recirculated hydroponic cultivation of tomato.