• Title/Summary/Keyword: sub-elevated temperatures

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Thermal effects on the mechanical properties of cement mortars reinforced with aramid, glass, basalt and polypropylene fibers

  • Mazloom, Moosa;Mirzamohammadi, Sajjad
    • Advances in materials Research
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    • v.8 no.2
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    • pp.137-154
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    • 2019
  • In this study, thermal effects on the mechanical properties of cement mortars with some types of fibers is investigated. The replaced fibers were made of polypropylene (PP), aramid, glass and basalt. In other words, the main goal of this paper is to study the effects of different fibers on the mechanical properties of cement mortars after subjecting to normal and sub-elevated temperatures. The experimental tests used for investigating these effects were compressive, splitting tensile, and four-point bending tests at 20, 100 and $300^{\circ}C$, respectively. Moreover, the microstructures of the specimens in different temperatures were investigated using scanning electron microscope (SEM). Based on the experimental results, the negative effects of sub-elevated temperatures on four-point bending tests were much more than the others. Moreover, using the fibers with higher melting points could not improve the qualities of the samples in sub-elevated temperatures.

Thermal plasticity of growth and chain formation of the dinoflagellates Alexandrium affine and Alexandrium pacificum with respect to ocean acidification

  • Lee, Chung Hyeon;Min, Juhee;Lee, Hyun-Gwan;Kim, Kwang Young
    • ALGAE
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    • v.36 no.4
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    • pp.285-298
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    • 2021
  • The amount of CO2 absorbed by the oceans continues to rise, resulting in further acidification, altering some functional traits of phytoplankton. To understand the effect of elevated partial pressures of CO2 (pCO2) on functional traits of dinoflagellates Alexandrium affine and A. pacificum, the cardinal temperatures and chain formation extent were examined under two pCO2 (400 and 1,000 µatm) over the range of temperature expected to be associated with growth. The growth rate and chain formation extent of A. affine increased with higher pCO2, showing significant changes in cardinal temperatures and a substantial increase in middle chain-length (4-8 cells) fractionation under elevated pCO2 condition. By contrast, there were no significant differences in specific growth rate and any chain-length fractionation of A. pacificum between ambient and elevated pCO2 conditions. The observed interspecies variation in the functional traits may reflect differences in ability of species to respond to environmental change with plasticity. Moreover, it allows us to understand the shifting biogeography of marine phytoplankton and predict their phenology in the Korea Strait.

Experimental Study About Properties of Limestone-calcined-clay Cement (LC3) Concrete Under High Temperature (석회석 소성 점토 시멘트(LC3) 페이스트의 고온 내화성능에 관한 연구)

  • Wang, Xiao-Yong
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.133-134
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    • 2021
  • Limestone-calcined clay-Cement (LC3) concrete provides a solution for sustainability, durability, and profitability of concrete industry. This study shows experimental studies of the macro properties (residual compressive strength), the meso properties (mesoscopic images), and micro properties (thermogravimetric (TG) analysis, X-ray powder diffraction (XRD), FTIR spectra, Raman spectra, Mercury intrusion porosimetry, and SEM) of LC3 paste with various mixtures and at high elevated temperatures (20 ℃, 300 ℃, 550 ℃ and 900 ℃). We find (1) Regarding to macro properties, LC3 cementitious materials are at a disadvantage in compressive strength when the temperature is higher than 300 ℃. (2) Regarding to meso properties, when the temperature reached 550 ℃, all samples generated more meso cracks. (3) Regarding to micro properties, first, as the substitution amount increases, its CH content decreases significantly; second, at 900 ℃, for samples with calcined clay, a large amount of gehlenite crystalline phase was found; third, at elevated temperatures (20 ℃, 300 ℃, 550 ℃ and 900 ℃), there is a linear relationship between the residual compressive strength and the cumulative pore volume; fourth, at 900 ℃, a large amount of dicalcium silicate was generated, and damage cracks were more pronounced. The experimental results of this study are valuable of material design of fire resistance of LC3 concrete.

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Deformation of Amorphous GeSe2 Film under Uniaxial Pressure Applied at Elevated Temperatures

  • Jin, Byeong Kyou;Lee, Jun Ho;Yi, Jeong Han;Lee, Woo Hyung;Shin, Sang Yeol;Choi, Yong Gyu
    • Journal of the Korean Ceramic Society
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    • v.52 no.2
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    • pp.108-113
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    • 2015
  • In an effort to evaluate the practicability of an imprinting technique for amorphous chalcogenide film in Ge-based compositions, we investigate the deformation behavior of the surface of amorphous $GeSe_2$ film deposited via a thermal evaporation route according to varying static loads applied at elevated temperatures. We observe that, under these static loading conditions, crystallization tends to occur on its surface relatively more easily than in As-based $As_2Se_3$ films. As for the present $GeSe_2$ film, higher processing temperatures are required in order to make its surface reflect the given stamp patterns well; however, in this case, its surface becomes partially crystallized in the monoclinic $GeSe_2$ phase. The increased vulnerability of this amorphous $GeSe_2$ film toward surface crystallization under static loading, when compared with the $As_2Se_3$ counterpart, is explained in terms of the topological aspects of its amorphous structure.

Synthesis of CoFe2O4 Magnetic Nanoparticles by Thermal Decomposition

  • Soundararajan, D.;Kim, Ki Hyeon
    • Journal of Magnetics
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    • v.19 no.1
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    • pp.5-9
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    • 2014
  • The amine functionalized $CoFe_2O_4$ nanoparticles were prepared by thermal decomposition method at reflux temperatures $160^{\circ}C$ and $172^{\circ}C$. The obtained $CoFe_2O_4$ nanoparticles at $160^{\circ}C$ reflux temperature show aggregation free poly-dispersed nanoparticles in 4-15 nm range. In an elevated reflux temperature of $172^{\circ}C$, $CoFe_2O_4$ show aggregated poly-dispersed nanoparticles in the size range of 20-46 nm. The saturation magnetization value at 300 K exhibited 51 emu/g at reflux temperature of $160^{\circ}C$. However, the sample synthesized at an elevated temperature of $172^{\circ}C$ has shown a coercive field value of 560 Oe with saturation magnetization of 68 emu/g.

Review on Carbonation Curing and Thermal Stability of Calcium Sulfoaluminate Cement (칼슘설포알루미네이트 시멘트의 탄산화 양생과 열 안정성에 관한 검토)

  • Wu, Xuanru;Kunal Krishna, Das;Jang, Jeong Gook
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.53-54
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    • 2023
  • In recent decades, climate change has become an issue of global importance. The calcium sulfoaluminate (CSA) cement emits lower CO2 than the Portland cements while manufacturing. However, ettringite, which is a main hydration product of CSA cement, starts dehydrating at a temperature above 100℃, hence it may limit the CSA cement for high temperature application. Recently, an early carbonation curing of cement-based material has been extensively studied in terms of carbon neutralization. The carbonation curing of CSA cement has a potential to transform the AFt and AFm phases into calcium carbonate, and the transformation of unstable hydrates to stable hydrates can increase the resistance to elevated temperature. This review study summarizes and discusses the carbonation curing effect of CSA cement and the thermal stability of CSA cement exposed to elevated temperatures.

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A Novel Process for Recovery of Key Elements from Commercial Cathode Material of End-of-Life Lithium-Ion Battery

  • Jei-Pil Wang
    • Archives of Metallurgy and Materials
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    • v.66 no.3
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    • pp.745-750
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    • 2021
  • A novel process to recover lithium and manganese oxides from a cathode material (LiMn2O4) of spent lithium-ion battery was attempted using thermal reaction with hydrogen gas at elevated temperatures. A hydrogen gas as a reducing agent was used with LiMn2O4 powder and it was found that separation of Li2O and MnO was taken place at 1050℃. The powder after thermal process was washed away with distilled water and only lithium was dissolved in the water and manganese oxide powder left behind. It was noted that manganese oxide powder was found to be 98.20 wt.% and the lithium content in the solution was 1,928 ppm, respectively.

High Temperature Deformation Behavior and Estimation for Formability of Zr55Cu30Al10Ni5 Bulk Metallic Glass (Zr계 비정질 합금의 고온 변형거동과 성형성 예측)

  • Jun, H.J.;Lee, K.S.;Chang, Y.W.
    • Transactions of Materials Processing
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    • v.16 no.4 s.94
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    • pp.309-312
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    • 2007
  • Deformation behavior of $Zr_{55}Cu_{30}Al_{10}Ni_5$(at. %) bulk metallic glass(BMG) fabricated by suction casting method has been investigated at elevated temperatures in this study. The BMG was first verified to have an amorphous structure with the analysis of X-ray diffraction(XRD) and differential scanning calorimetry(DSC) data. A series of compression tests has consequently been performed in the region of supercooled liquid temperature to investigate the behavior of high temperature deformation. A transition from Newtonian to non-Newtonian flow appeared to take place depending upon both the strain rate and test temperature. A processing map based on a dynamic materials model has been constructed to estimate a feasible forming condition for this BMG alloy.

Effect of elevated pCO2 on thermal performance of Chattonella marina and Chattonella ovata (Raphidophyceae)

  • Lim, Myeong Hwan;Lee, Chung Hyeon;Min, Juhee;Lee, Hyun-Gwan;Kim, Kwang Young
    • ALGAE
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    • v.35 no.4
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    • pp.375-388
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    • 2020
  • Ocean acidification and warming, identified as environmental concerns likely to be affected by climate change, are crucial determinants of algal growth. The ichthyotoxic raphidophytes Chattonella species are responsible for huge economic losses and environmental impact worldwide. In this study, we investigated the impact of CO2 on the thermal performance curves (TPCs) of Chattonella marina and Chattonella ovata grown under temperatures ranging from 13 to 34℃ under ambient pCO2 (350 μatm) and elevated pCO2 (950 μatm). TPCs were comparable between the species or even between pCO2 levels. With the exception of the critical thermal minimum (CTmin) for C. ovata, CTmin for C. marina and the thermal optimum (Topt) and critical thermal maximum (CTmax) for both species did not change with elevation of pCO2 levels. While CO2 enrichment increased the maximum photosynthetic rates (Pmax) up to 125% at the Totp of 30℃, specific growth rates were not significantly different under elevated pCO2 for the two species. Overall, C. ovata is likely to benefit from climate change, potentially widening its range of thermal tolerance limit in highly acidic waters and contributing to prolonged phenology of future phytoplankton assemblages in coastal waters.