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Nanocomposite Electrode Materials Prepared from Pinus roxburghii and Hematite for Application in Supercapacitors

  • SHRESTHA, Dibyashree
    • Journal of the Korean Wood Science and Technology
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    • v.50 no.4
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    • pp.219-236
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    • 2022
  • Wood-based nanocomposite electrode materials were synthesized for application in supercapacitors by mixing nanostructured hematite (Fe2O3) with highly porous activated carbon (AC) produced from the wood-waste of Pinus roxburghii. The AC was characterized using various instrumental techniques and the results showed admirable electrochemical properties, such as high surface area and reasonable porosity. Firstly, AC was tested as an electrode material for supercapacitors and it showed a specific capacitance of 59.02 Fg-1 at a current density of 1 Ag-1, cycle life of 84.2% after 1,000 cycles (at a current density of 3 Ag-1), and energy density of 5.1 Wh/kg at a power density of 135 Wkg-1. However, when the AC was composited with different ratios of Fe2O3 (1:1, 2:1, and 1:2), there was an overall improvement in its electrochemical performance. Among the 3 ratios, 2:1 (AC:Fe2O3) had the best specific capacitance of 102.42 Fg-1 at 1 Ag-1, cycle life of 94.4% capacitance after 1,000 cycles (at a current density of 3 Ag-1), and energy density of 8.34 Wh/kg at a power density of 395.15 Wkg-1 in 6 M KOH electrolyte in a 3-electrode experimental setup with a high working voltage of 1.55 V. Furthermore, when Fe2O3 was doubled, 1:2 (AC:Fe2O3), the electrochemical capacitive performance of the electrode twisted and deteriorated due to either the accumulation of Fe2O3 particles within the composite or higher bulk resistance value of pure Fe2O3.

Storage Media for the Vehicle Heat Storage System by Using Ba(OH)2·8H2O System (Ba(OH)2·8H2O계 자동차 축열시스템의 저장매체)

  • Kim, H.C.;Song, Y.H.;Lee, C.T.
    • Applied Chemistry for Engineering
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    • v.8 no.5
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    • pp.722-728
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    • 1997
  • This study was investigated to find storage material of thermal energy storage system for a vehicle with the basic material of $Ba(OH)_2{\cdot}8H_2O$ and to test a feasibility of it. Experiment was investigated usability for long time and state change and thermal property after cycle with $Ba(OH)_2{\cdot}8H_2O$ and misxture doping additive to it. The result of this research indicated the mixture adding $Sr(OH)_2{\cdot}8H_2O$ to $Ba(OH)_2{\cdot}8H_2O$ have high feasibility as storage material for thermal energy storage system. This mixture did not exhibit the state change during 1300 cycles and the rate of decrease of heat realese energy was about 2%, relatively low value.

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Fabrication and Electrical Properties of Al2O3/GaN MIS Structures using Remote Plasma Atomic Layer Deposition (원격 플라즈마 원자층 증착법을 이용한 Al2O3/GaN MIS 구조의 제작 및 전기적 특성)

  • Yun, Hyeong-Seon;Kim, Hyun-Jun;Lee, Woo-Seok;Kwak, No-Won;Kim, Ka-Lam;Kim, Kwang-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.4
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    • pp.350-354
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    • 2009
  • $Al_{2}O_{3}$ thin films were deposited on GaN(0001) by using a Remote Plasma Atomic Layer Deposition(RPALD) technique with a trimethylaluminum(TMA) precursor and oxygen radicals in the temperature range of $25{\sim}500^{\circ}C$. The growth rate per cycle was varied with the substrate temperature from $1.8{\AA}$/cycle at $25^{\circ}C$ to $0.8{\AA}$/cycle at $500^{\circ}C$. The chemical structure of the $Al_{2}O_{3}$ thin films was studied using X-ray photoelectron spectroscopy(XPS). The electrical properties of $Al_{2}O_{3}$/GaN Metal-Insulator-Semiconductor (MIS) capacitor grown at a $300^{\circ}C$ process temperature were excellent, a low electrical leakage current density(${\sim}10^{-10}A/cm^2$ at 1 MV) at room temperature and a high dielectric constant of about 7.2 with a thinner oxide thickness of 12 nm. The interface trap density($D_{it}$) was estimated using a high-frequency C-V method measured at $300^{\circ}C$. These results show that the RPALD technique is an excellent choice for depositing high-quality $Al_{2}O_{3}$ as a Sate dielectric in GaN-based devices.

A Facile Process for Surface Modification with Lithium Ion Conducting Material of Li2TiF6 for LiMn2O4 in Lithium Ion Batteries

  • Kim, Min-Kun;Kim, Jin;Yu, Seung-Ho;Mun, Junyoung;Sung, Yung-Eun
    • Journal of Electrochemical Science and Technology
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    • v.10 no.2
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    • pp.223-230
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    • 2019
  • A facile method for surface coating with $Li_2TiF_6$ which has a high lithium-ion conductivity, on $LiMn_2O_4$ spinel cathode material for high performance lithium ion batteries. The surface coating is performed by using a co-precipitation method with $Li_2CO_3$ powder and $H_2TiF_6$ solution under room temperature and atmospheric pressure without special equipment. Total coating amount of $Li_2TiF_6$ is carefully controlled from 0 to 10 wt.% based on the active material of $LiMn_2O_4$. They are evaluated by a systematic combination of analyses comprising with XRD, SEM, TEM and ICP. It is found that the surface modification of $Li_2TiF_6$ is very beneficial to high cycle life and excellent rate capability by reducing surface failure and supporting lithium ions transportation on the surface. The best coating condition is found to have a high cycle life of $103mAh\;g^{-1}$ at the 100th cycle and a rate capability of $102.9mAh\;g^{-1}$ under 20 C. The detail electrochemical behaviors are investigated by AC impedance and galvanostatic charge and discharge test.

Effect of interval exercise versus continuous exercise on excess post-exercise oxygen consumption during energy-homogenized exercise on a cycle ergometer

  • Jung, Won-Sang;Hwang, Hyejung;Kim, Jisu;Park, Hun-Young;Lim, Kiwon
    • Korean Journal of Exercise Nutrition
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    • v.23 no.2
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    • pp.45-50
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    • 2019
  • [Purpose] The purpose of this study was to confirm that the difference in excess post-exercise oxygen consumption (EPOC) during exercise of the spending the same calories between the continuous and interval exercise. [Methods] Thirty-four healthy college students who did not regularly exercise volunteered to participate in our study. Continuous exercise was performed on an ergometer for 30 min at 60% of maximal oxygen consumption (VO2 max). Interval exercise was performed on a cycle ergometer at 80% VO2 max for 2 min initially, followed by 40% VO2 max for 1 min, and 80% VO2 max for 3 min. This was repeated six times for a total of 26 min. [Results] The major findings were as follows: (1) energy consumption during exercise was not significantly different between continuous exercise and interval exercise groups; (2) EPOC was higher in interval exercise than in continuous exercise for all dependent variables (i.e., total oxygen consumption, total calories, summation of heart rate); and (3) there were no significant differences in the lipid profile between continuous and interval groups. [Conclusions] Our study confirmed that after equalizing energy expenditure for continuous and interval exercise on a cycle ergometer in subjects in their twenties, interval exercise results in higher EPOC than continuous exercise. These data suggest that interval exercise may be more effective than continuous exercise in reducing body fat, for a given amount of energy expenditure.

Design of closed-loop nitrogen Joule-Thomson refrigeration cycle for 67 K with sub-atmospheric device

  • Lee, C.;Lee, J.;Jeong, S.
    • Progress in Superconductivity and Cryogenics
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    • v.15 no.1
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    • pp.45-50
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    • 2013
  • Closed-loop J-T (Joule-Thomson) refrigeration cycle is advantageous compared to common open loop $N_2$ decompression system in terms of nitrogen consumption. In this study, two closed-loop pure $N_2$ J-T refrigeration systems with sub-atmospheric device for cooling High Temperature Superconductor (HTS) power cable are investigated. J-T cooling systems include 2-stage compressor, 2-stage precooling cycle, J-T valve and a cold compressor or an auxiliary vacuum pump at the room temperature. The cold compressor and the vacuum pump are installed after the J-T valve to create sub-atmospheric condition. The temperature of 67 K is possible by lowering the pressure up to 24 kPa at the cold part. The optimized hydrocarbon mixed refrigerant (MR) J-T system is applied for precooling stage. The cold head of precooling MR J-T have the temperature from 120 K to 150 K. The various characteristics of cold compressor are invstigated and applied to design parameter of the cold compressor. The Carnot efficiency of cold compressor system is calculated as 16.7% and that of vacuum pump system as 16.4%. The efficiency difference between the cold compressor system and the vacuum pump system is due to difference of enthalpy change at cryogenic temperature, enthalpy change at room temperature and different work load at the pre-cooling cycle. The efficiency of neon-nitrogen MR J-T system is also presented for comparison with the sub-atmospheric devices. These systems have several pros and cons in comparison to typical MR J-T systems such as vacuum line maintainability, system's COP and etc. In this paper, the detailed design of the subcooled $N_2$ J-T systems are examined and some practical issues of the sub-atmospheric devices are discussed.

A Study on Quantity of CO2 Emission about Remodeling Cycle at High-rise Apartment housing (초고층 공동주택 세대내 개보수 주기에 따른 이산화탄소 배출량 연구)

  • Kim, Dayoo;Kang, Seungyi;Je, Haeseong
    • KIEAE Journal
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    • v.10 no.3
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    • pp.75-80
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    • 2010
  • The goal of this study is to figure out the remodeling cycle at high-rise apartment housing and to analysis on quantity of $CO_2$ emission about remodeling cycle. The process of research is as follow; 1) Estimate the remodeling cycle through survey targeting residents at high-rise apartment building. 2) Simulate conditions on the high-rise apartment housing. 3) Calculate quantity of energy consumption and $CO_2$ emission 4) Derive elements that are on high level of environmental load evaluation. The main results of this study is as follow; 1) The cycle of finishing such as wallpaper is shorter than the cycle of building equipment such as elements in a toilet. 2) According to result of calculating $CO_2$ emission, fabric wallpaper and mortar are main factors that impact on the environment. The results is important to show reference points on quantitative measuring evaluation for the environmental-friendly extent.

Low-power/high-speed DCT structure using common sub-expression sharing (Common sub-expression sharing을 이용한 고속/저전력 DCT 구조)

  • Jang, Young-Beom;Yang, Se-Jung
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.29 no.1C
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    • pp.119-128
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    • 2004
  • In this paper, a low-power 8-point DCT structure is proposed using add and shift operations. Proposed structure adopts 4 cycles for complete 8-point DCT in order to minimize size of hardware and to enable high-speed processing. In the structure, hardware for the first cycle can be shared in the next 3 cycles since all columns in the DCT coefficient matrix are common except sign. Conventional DCT structures implemented with only add and shift operation use CSD(Canonic Signed Digit) form coefficients to reduce the number of adders. To reduce the number of adders further, we propose a new structure using common sub-expression sharing techniques. With this techniques, the proposed 8-point DCT structure achieves 19.5% adder reduction comparison to the conventional structure using only CSD coefficient form.

An Analysis of the Performance of a Combined Expander-Compressor Unit for a CO2 Automotive Air Conditioning Cycle (차량용 CO2 에어컨 사이클 성능 향상을 위한 일체형 팽창기-압축기 성능 해석)

  • Choi, Jae Woong;Lim, Jeong Taek;Kim, Hyun Jin
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.30 no.3
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    • pp.107-115
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    • 2018
  • A design combining the use of a compressor and expander was introduced in order to improve the cycle performance of a $CO_2$ automotive air conditioning system. Both the compressor and expander used were of rotary vane type and were designed to share a common shaft in a housing. Numerical simulation was carried out to evaluate the merit of the combined unit. In a typical automotive air conditioning operating conditions, the COP of the system was improved by 8.7% by the application of the combined unit. The compressor input was reduced by 5.2% through use of the expander output. In addition, about 3.06% increase in the cooling capacity was obtained through isentropic expansion in the expander. Our study noted that, as the pressure difference between the gas cooler and the evaporator becomes larger, the COP of the system improved increases unless the mass flow rate in the expander exceeds that in the compressor.

Comparison of Performance in CO2 Cooling System with an Ejector for Various Operating Conditions (다양한 운전조건에서 이젝터를 적용한 CO2 냉동기의 성능비교)

  • Kang, Byun;Cho, Hong-Hyun
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.7
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    • pp.505-512
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    • 2011
  • Recently, many researchers have analyzed the performance of the transcritical $CO_2$ refrigeration cycle in order to identify opportunities to improve the system energy efficiency. The reduction of the expansion process losses is one of the key issues to improve the efficiency of the transcritical $CO_2$ refrigeration cycle. In this study, the analytical study on the performance characteristics of $CO_2$ cycle with an ejector carried out with a variation of outdoor temperature, gascooler inlet air velocity, evaporator inlet air velocity, and evaporator inlet air temperature. As a result, the system performance could be improved over 85% by using an ejector for various operating condition because of the reduction of compressor work. Moreover, the cooling capacity increased about 18% for variable outdoor condition. Therefore, the high performance of an ejector system could be maintained for wide operating conditions and system reliability could be improved compared to that of a basic system.