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http://dx.doi.org/10.4313/JKEM.2009.22.4.350

Fabrication and Electrical Properties of Al2O3/GaN MIS Structures using Remote Plasma Atomic Layer Deposition  

Yun, Hyeong-Seon (청주대학교 전자공학과)
Kim, Hyun-Jun (청주대학교 전자공학과)
Lee, Woo-Seok (청주대학교 전자공학과)
Kwak, No-Won (청주대학교 전자공학과)
Kim, Ka-Lam (청주대학교 전자공학과)
Kim, Kwang-Ho (청주대학교 전자공학과)
Publication Information
Journal of the Korean Institute of Electrical and Electronic Material Engineers / v.22, no.4, 2009 , pp. 350-354 More about this Journal
Abstract
$Al_{2}O_{3}$ thin films were deposited on GaN(0001) by using a Remote Plasma Atomic Layer Deposition(RPALD) technique with a trimethylaluminum(TMA) precursor and oxygen radicals in the temperature range of $25{\sim}500^{\circ}C$. The growth rate per cycle was varied with the substrate temperature from $1.8{\AA}$/cycle at $25^{\circ}C$ to $0.8{\AA}$/cycle at $500^{\circ}C$. The chemical structure of the $Al_{2}O_{3}$ thin films was studied using X-ray photoelectron spectroscopy(XPS). The electrical properties of $Al_{2}O_{3}$/GaN Metal-Insulator-Semiconductor (MIS) capacitor grown at a $300^{\circ}C$ process temperature were excellent, a low electrical leakage current density(${\sim}10^{-10}A/cm^2$ at 1 MV) at room temperature and a high dielectric constant of about 7.2 with a thinner oxide thickness of 12 nm. The interface trap density($D_{it}$) was estimated using a high-frequency C-V method measured at $300^{\circ}C$. These results show that the RPALD technique is an excellent choice for depositing high-quality $Al_{2}O_{3}$ as a Sate dielectric in GaN-based devices.
Keywords
Aluminum oxide; MIS; GaN; RPALD; Interlace trap density;
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1 C. Ostermaier, H. C. Lee, S. Y. Hyun, S. I. Ahn, K. W. Kim, H. I. Cho, J. B. Ha, and J. H. Lee, 'Interface characterization of ALD deposited $Al_2O_3$ on GaN by CV method', Phys. Stat. Sol., Vol. 5, No. 6, p. 1992, 2008   DOI   ScienceOn
2 M. D Groner, F. H Fabreguette, J. W Elam, and S. M George, 'Low-temperature $Al_2O_3$ atomic layer deposition', Chem. Mater., Vol. 16, p. 639, 2004   DOI   ScienceOn
3 J. F Moulder, W. F Stickle, P. E Sobol, and K. D Bomben, 'Handbook of X-ray Photoelectron spectroscopy, Perkin-elmer Corporation', Eden Prairie, MN, p. 55, 1992
4 L. M Terman, 'An investigation of surface states at a silicon/silicon oxide interface employing metal-oxide-silicon diodes', Solid-State Electronics, Vol. 5, Issue 5, p. 285, 1962   DOI   ScienceOn
5 K. H Kim, Y. S Kim, S. H Jeong, and S. W. Jung, 'Fabrication and properties of an epitaxial AIN film on a SiC substrate by using reactive RF magnetron sputtering', J. Korean Phys. Soc., Vol. 48, No. 2, p. 275, 2006
6 B. Gaffey, L. J. Guido, X. W. Wang, and T. P. Ma, 'High-quality oxide/nitride/oxide gate insulator for GaN MIS structures', IEEE Electron Devices Lett., Vol. 48, Issue 3, p. 458, 2001   DOI   ScienceOn
7 F. Ren, C. R. Abernathy, J. D. MacKenzie, B. P. Gila, S. J. Pearton, M. Hong, M. A. Marcus, M. J. Schurman, A. G. Baca, and R. J. Shul, 'Demonstration of GaN MIS diodes by using AlN and $Ga_2O_3(Gd_2O_3)$ as dielectrics', Solid-State Electronics, Vol. 42, Issue 12, p. 2177, 1998   DOI   ScienceOn
8 T. Hashizume, E. Alekseev, D. Pavlidis, K. S. Boutros, and J. Redwing, 'Capacitance–voltage characterization of AlN/GaN metal–insulator–semiconductor structures grown on sapphire substrate by metalorganic chemical vapor deposition', Appl. Phys, Lett., Vol. 88, Issue 4, p. 1983, 2000
9 H. C. Casey Jr, G. G. Fountain, R. G. Alley, B. P. Keller, and S. P. DenBaars, 'Low interface trap density for remote plasma deposited $SiO_2$ on n-type GaN', J. Appl. Phys. Lett., Vol. 68, Issue 13, p. 1850, 1996   DOI
10 M. Hong, K. A. Anselm, J. Kwo, H. M. Ng, J. N. Baillargeon, A. R. Kortan, J. P. Mannaerts, A. Y. Cho, C. M. Lee, J. I. Chyi, and T. S. Lay, 'Properties of $Ga_2O_3(Gd_2O_3)$/ GaN metal–insulator–semiconductor diodes', J. Vac. Sci. Technol., Vol. 18, Issue 3, p. 1453, 2000   DOI   ScienceOn
11 Y. C. Chang, H. C. Chiu, Y. J. Lee, M. L. Huang, K. Y. Lee, M. Hong, Y. N. Chiu and J. Kwo, and Y. H. Wang, 'Structural and electrical characteristics of atomic layer deposited high $HfO_2$ on GaN', Appl. Phys. Lett., Vol. 90, Issue 23, p. 232904, 2007   DOI   ScienceOn
12 Y. Q. Wu, T. Shen, P. D. Ye, and G. D. Wilk, 'Photo - assisted capacitance - voltage characterization of high - quality atomic - layer - deposited $Al_2O_3$/GaN metal - oxide - semiconductor structures', Appl. Phys., Vol. 90, p. 143504, 2007
13 T. P. Chow and R. Tyagi, 'Wide bandgap compound semiconductors for superior high-voltage unipolar power devices', IEEE Trans. Electron Devices, Vol. 41, Issue 8, p. 1481, 1994   DOI   ScienceOn