• 제목/요약/키워드: structure functionality

검색결과 333건 처리시간 0.025초

Development of Micro-Tubular Perovskite Cathode Catalyst with Bi-Functionality on ORR/OER for Metal-Air Battery Applications

  • Jeon, Yukwon;Kwon, Ohchan;Ji, Yunseong;Jeon, Ok Sung;Lee, Chanmin;Shul, Yong-Gun
    • Korean Chemical Engineering Research
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    • 제57권3호
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    • pp.425-431
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    • 2019
  • As rechargeable metal-air batteries will be ideal energy storage devices in the future, an active cathode electrocatalyst is required with bi-functionality on both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) during discharge and charge, respectively. Here, a class of perovskite cathode catalyst with a micro-tubular structure has been developed by controlling bi-functionality from different Ru and Ni dopant ratios. A micro-tubular structure is achieved by the activated carbon fiber (ACF) templating method, which provides uniform size and shape. At the perovskite formula of $LaCrO_3$, the dual dopant system is successfully synthesized with a perfect incorporation into the single perovskite structure. The chemical oxidation states for each Ni and Ru also confirm the partial substitution to B-site of Cr without any changes in the major perovskite structure. From the electrochemical measurements, the micro-tubular feature reveals much more efficient catalytic activity on ORR and OER, comparing to the grain catalyst with same perovskite composition. By changing the Ru and Ni ratio, the $LaCr_{0.8}Ru_{0.1}Ni_{0.1}O_3$ micro-tubular catalyst exhibits great bi-functionality, especially on ORR, with low metal loading, which is comparable to the commercial catalyst of Pt and Ir. This advanced catalytic property on the micro-tubular structure and Ru/Ni synergy effect at the perovskite material may provide a new direction for the next-generation cathode catalyst in metal-air battery system.

DTD 의존 스키마에 기반한 SGML 문서 저장 시스템 개발에 관한 연구 (A Study on Development of SGML Repository System Based on DTD-dependent Schema)

  • 김현기;노대식;강현규
    • 한국정보처리학회논문지
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    • 제6권5호
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    • pp.1153-1165
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    • 1999
  • In various fields of information technology, it is growing up the needs about dynamic content management systems to store and manage SGML(Standard Generalized Markup language) documents in a database system. In this paper, we consider the issue of storing SGML documents that having complex hierarchical structure into a database system, and then propose a data model based on ODMG(Object Database Management Group) object model in order to store SGML documents without loss of information. Because the proposed data model reflects physical element structure and logical entity structure of SGML documents, it is able to store the SGML document in a database system at the system at the element- level granularity without any information loss. And also the proposed data model can be adapted among ODMG-compliant object database management systems. Finally, we will discuss on the implementation details of SGML repository system supports the functionality of automatic database schema creation for any DTD(Document Type Definition0, the functionality of storing the SGML document, the functionality of dynamic document assembly from stored database objects to SGML document, and the functionality of indexing and searching for database objects.

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한국의 기능성 유제품 표시제도 개선방안 (Amendment Scheme of Labeling Regulation for Functionality of Dairy Products)

  • 박기환
    • Journal of Dairy Science and Biotechnology
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    • 제25권1호
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    • pp.47-54
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    • 2007
  • The labeling for functionality of food or food components are recognized globally and are essential for the growth of dairy product industry. To expand the functional claims of dairy product especially fermented milk product, the regulations restricting the labeling of functionality should be amended as soon as possible. The labeling regulations of functionality and efficacy for processed and functional foods in related Acts and subordinated statues such as definition, scope of claims, etc. were reviewed and the problems existed in the system were identified. The definition and classification of efficacy for processed food in Food Sanitation Act were analyzed to revise the labeling regulation of dairy product. A draft of amended labeling regulation for the functionality of dairy product is proposed, which provides consumers with appropriate information of beneficial effects on health purpose for human body structure and function. In order to develop the dairy products and related industries, these contents should be considered when the annexed Table 14 in the Enforcement Rule of the Processing of Livestock Products Act is amended.

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Synthesis and Optical Properties of Poly(2-ethynylpyridinum bromide) Having Glycidyl Functionality

  • Gal, Yeong-Soon;Lee, Won-Chul;Lee, Sang-Seob;Bae, Jang-Soon;Kim, Bong-Shik;Jang, Sang-Hee;Jin, Sung-Ho;Park, Jong-Wook
    • Macromolecular Research
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    • 제8권3호
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    • pp.131-136
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    • 2000
  • The synthesis of poly(2-ethynylpyridine) having glycidyl functionality was performed by the direct polymerization of 2-ethynylpyridine and epibromohydrin under mild reaction conditions without any initiator and catalysts. The polymerization proceeded well to give the resulting poly(2-ethynylpyridinium bromide) with a glycidyl functionality having relativity high molecular weight in high yields. The polymer structure was characterized by various instrumental methods to have the conjugated polymer backbone structure having glycidyl functionality. This ionic polymer was completely soluble in water, methanol, DMF, DMSO, and N,N-dimethylacetamide, but insoluble in THF, toluene, acetone, nitrobenzene, and n-hexane. This polymer system exhibited the UV-visible absorption around 300 and 520 nm and red photoluminescence spectrum around 725 nm.

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식품의 조리.가공 공정 중 phytochemical 및 기능성의 변화 (Changes in Phytochemical Stability and Food Functionality during Cooking and Processing)

  • 김현정;전향숙
    • 한국식품조리과학회지
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    • 제22권3호통권93호
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    • pp.402-417
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    • 2006
  • Research interest on functional food and phytochemicals has mainly focused on their health effects, mechanism of action and structure-activity relationship for the development of nutraceuticals. Considering the intake of phytochemicals via the normal diet, further information is required on changes in food functionality or individual phytochemicals that occur during the cooking or processing of foods, in order to increase the intake of these bioactive compounds, because many of the unit-operating procedures involved in cooking or food processing may result in physicochemical changes of food constituents. This study reviews the changes of selected phytochemicals, i.e. flavonoids, organosulfur compounds and carotenoids, or food functionality by major cooking or processing procedures such as heating, fermentation, and pH changes. In general, heating has a negative effect on food functionality, although in some cases, mild heating increases bioactive phytochemical contents. Some phytochemicals, including anthocyanins and catechins, are stabilized in lower pH conditions. The structures of phytochemicals, including isoflavones and catechins, are changed by fermentation. The loss of bioactive compounds may be decreased by recently developed cooking or processing methods such as microwave cooking or use of high hydrostatic pressure. However, the effects of cooking and processing procedures on food functionality and phytochemicals are so diverse and dependent on test conditions that further research efforts are needed to form accurate conclusions on the effects of cooking and processing of foods.

Design & Implementation of Enhanced Groupware Messenger

  • Park, HyungSoo;Kim, HoonKi;Na, WooJong
    • 한국컴퓨터정보학회논문지
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    • 제23권4호
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    • pp.81-88
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    • 2018
  • In this paper, we present some problems with the Groupware Messenger functionality based on dot net 2.0 and implement a new design structure to solve them. They include memory leakage, slow processing, and client window memory crash. These problems resulted in the inconvenience of using instant messaging and the inefficient handling of office tasks. Therefore, in this paper, instant messaging functionality is implemented according to a new design architecture. The new system upgrades dot net 4.5 for clients and deploys the new features based on MQTT for the messenger server. We verify that the memory leak problem and client window memory crash issues have been eliminated on the system with the new messenger functionality. We measure the amount of time it takes to bind data to a set of messages and evaluate the performance, compared to a given system. Through this comparative evaluation, we can see that the new system is more reliable and performing.

Evaluation of Porcine Myofibrillar Protein Gel Functionality as Affected by Microbial Transglutaminase and Red Bean [Vignia angularis] Protein Isolate at Various pH Values

  • Jang, Ho Sik;Lee, Hong Chul;Chin, Koo Bok
    • 한국축산식품학회지
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    • 제35권6호
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    • pp.841-846
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    • 2015
  • This study was investigated to determine the effect of microbial transglutaminase (MTG) with or without red bean protein isolate (RBPI) on the porcine myofibrillar protein (MP) gel functionality at different pH values (pH 5.75-6.5). Cooking yield (CY, %), gel strength (GS, gf), differential scanning calorimetry (DSC), and scanning electron microscopy (SEM) were determined to measure gel characteristics. Since no differences were observed the interaction between 1% RBPI and pH, data were pooled. CY increased with the addition of 1% RBPI, while it was not affected by pH values. GS increased with increased pH and increased when 1% RBPI was added, regardless of pH. There were distinctive endothermic protein peaks, at 56.55 and 75.02℃ at pH 5.75, and 56.47 and 72.43℃ at pH 6.5 in DSC results, which revealed decreased temperature of the first peak with the addition of 1% RBPI and increased pH. In SEM, a more compact structure with fewer voids was shown with the addition of 1% RBPI and increased pH from 5.75 to 6.5. In addition, the three-dimensional structure was highly dense and hard at pH 6.5 when RBPI was added. These results indicated that the addition of 1% RBPI at pH 6.5 in MTG-mediated MP represent the optimum condition to attain maximum gel-formation and protein gel functionality.

Neural network structure design using genetic algorithm

  • Murata, Junichi;Tanaka, Kei;Koga, Masaru;Hirasawa, Kotaro
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1995년도 Proceedings of the Korea Automation Control Conference, 10th (KACC); Seoul, Korea; 23-25 Oct. 1995
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    • pp.187-190
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    • 1995
  • A method is proposed which searches for optimal structures of Neural Networks (NN) using Genetic Algorithm (GA). The purpose of the method lies in not only finding an optimal NN structure but also leading us to the goal of self-organized control system that acquires its structure and its functionality by itself depending on its environment.

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Assembly of Biomimetic Peptoid Polymers

  • 남기태
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 춘계학술발표대회
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    • pp.10.2-10.2
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    • 2011
  • The design and synthesis of protein-like polymers is a fundamental challenge in materials science. A biomimetic approach is to explore the impact of monomer sequence on non-natural polymer structure and function. We present the aqueous self-assembly of two peptoid polymers into extremely thin two-dimensional (2D) crystalline sheets directed by periodic amphiphilicity, electrostatic recognition and aromatic interactions. Peptoids are sequence-specific, oligo-N-substituted glycine polymers designed to mimic the structure and functionality of proteins. Mixing a 1:1 ratio of two oppositely charged peptoid 36 mers of a specific sequence in aqueous solution results in the formation of giant, free-floating sheets with only 2.7 nm thickness. Direct visualization of aligned individual peptoid chains in the sheet structure was achieved using aberration-corrected transmission electron microscopy. Specific binding of a protein to ligand-functionalized sheets was also demonstrated. The synthetic flexibility and biocompatibility of peptoids provide a flexible and robust platform for integrating functionality into defined 2D nanostructures. In the later part of my talk, we describe the use of metal ions to construct two-dimensional hybrid films that have the ability to self-heal. Incubation of biomimetic peptoid polymers with specific divalent metal ions results in the spontaneous formation of uniform multilayers at the air-water interface. We anticipate that ease of synthesis and transfer of these two-dimensional materials may have many potential applications in catalysis, gas storage and sensing, optics, nanomaterial synthesis, and environmentally responsive scaffolds.

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자중조절 기능이 있는 해상풍력 지지구조의 하중 및 구조해석 (Load and Structural Analysis of an Offshore Wind-Turbine Foundation with Weight Control Functionality)

  • 오민우;김동현;김기하;김석태
    • KEPCO Journal on Electric Power and Energy
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    • 제2권3호
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    • pp.453-460
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    • 2016
  • 해상풍력터빈 시스템은 크게 상부의 풍력터빈과 하부의 지지구조로 구성된다. 해상풍력발전은 육상용 풍력발전보다 우수하다는 평가가 지배적이지만 육상용 풍력발전에서 고려되지 않는 파랑에 의한 주기적인 하중이 추가로 고려되기 때문에 다양한 외부 환경조건에 대하여 높은 안정성 확보가 요구된다. 본 연구에서는 전산유체역학 기법을 활용하여 설계된 해상풍력 하부구조에 대한 하중해석을 수행하고 유한요소해석을 통해 설계된 자중조절형 해상풍력 기초에 대한 구조 건전성을 검토하였다.