• Title/Summary/Keyword: structure coexistence

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BCTZ Addition on the Microstructure, Piezoelectric/Dielectric Properties and Phase Transition of NKLN-AS Piezoelectric Ceramics (BCTZ첨가가 NKLN-AS계 압전세라믹스의 미세구조와 압전/유전특성 및 상전이현상에 미치는 효과)

  • Lee, Woong-Jae;Ur, Soon-Chul;Lee, Young-Geun;Yoon, Man-Soon
    • Korean Journal of Materials Research
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    • v.22 no.1
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    • pp.35-41
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    • 2012
  • Presently, the most promising family of lead-free piezoelectric ceramics is based on $K_{0.5}Na_{0.5}NbO_3$(KNN). Lithium, silver and antimony co-doped KNN ceramics show high piezoelectric properties at room temperature, but often suffer from abnormal grain growth. In the present work, the $(Ba_{0.85}Ca_{0.15})(Ti_{0.88}Zr_{0.12})O_3$ component, which has relaxor ferroelectric characteristics, was doped to suppress the abnormal grain growth. To investigate this effect, Lead-Free $0.95(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}NbO_3-(0.05-x)AgSbO_3-x(Ba_{0.85}Ca_{0.15})(Ti_{0.88}Zr_{0.12})O_3$[KNLN-AS-xBCTZ] piezoelectric ceramics were synthesized by ball mill and nanosized-milling processes in lead-Free $0.95(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}NbO_3-(0.05-x)AgSbO_3$ in order to suppress the abnormal grain growth. The nanosized milling process of calcined powders enhanced the sintering density. The phase structure, microstructure, and ferroelectric and piezoelectric properties of the KNLN-AS ceramics were systematically investigated. XRD patterns for the doped and undoped samples showed perovskite phase while tetragonality was increased with increasing BCZT content, which increase was closely related to the decrease of TO-T. Dense and uniform microstructures were observed for all of the doped BCZT ceramics. After the addition of BCTZ, the tetragonal-cubic and orthorhombic-tetragonal phase transitions shifted to lower temperatures compared to those for the pure KNNL-AS. A coexistence of the orthorhombic and tetragonal phases was hence formed in the ceramics with x = 0.02 mol at room temperature, leading to a significant enhancement of the piezoelectric properties. For the composition with x = 0.02 mol, the piezoelectric properties showed optimum values of: $d_{33}$ = 185 pC/N, $k_P$ = 41%, $T_C=325^{\circ}C$, $T_{O-T}=-4^{\circ}C$.

Nonlinear Irregular Waves-current Interaction on Flow Fields with Wave Breaking around Permeable Submerged Breakwater (투과성잠제 주변에서 쇄파를 동반한 불규칙파-흐름장의 상호작용)

  • Lee, Kwang-Ho;Bae, Ju-Hyun;An, Sung-Wook;Kim, Do-Sam
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.30 no.2
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    • pp.39-50
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    • 2018
  • In this study, the nonlinear interaction of irregular waves with wave breaking and currents around permeable submerged breakwater was investigated with the aid of olaFlow model which is open source CFD software published under the GPL license. The irregular wave performance of olaFlow applied in this study was verified by comparing and evaluating the target frequency spectrum and the generated frequency spectrum for applicability to irregular waves. Based on the applicability of this numerical model to irregular wave fields, in the coexistence fields of irregular waves and currents, the characteristics of wave height, frequency spectrum, breaking waves, averaged velocity and turbulent kinetic energy around porous submerged breakwater with the respect to the beach type and current direction versus wave propagation were carefully investigated. The numerical results revealed that the shape of wave breaking on the crown of the submerged breakwater and the formation of the mean flow velocity around the structure depend greatly on the current directions and the type of the beach. In addition, it was found that the wave height fluctuation due to the current direction with respect to the wave propagation is closely related to the turbulent kinetic energy.

Magnetic Circular Dichroism Study of co Thin Films on Pd(111) Surface

  • Kim, Wookje;Kim, Wondong;Kim, Hyunjo;Kim, Jae-Young;Hoon Kho;Park, J.H.;Oh, S.J.
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.169-169
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    • 1999
  • We studied magnetic properties of co thin films deposited on Pd (111) surface, which attracted much attention recently due to the perpendicular magnetic anisotropy, using magnetic circular dichroism(MCD). Special attention was paid on the effect of Pd capping and interface roughness on the direction of magnetic easy axis, and for that purpose MCD signals for all Co thicknesses were measured with two different ways : in-plane and out-of-plane geometry. In case of bare Co films deposited on smooth Pd(111) surface, no MCD signal was observed under 4$\AA$ co thickness. At 4$\AA$ Co thickness, MCD signal at the out-of-plane geometry was observed, and for thicker Co films, only in-plane MCD signal was measured. This type of magnetic easy axis transition has been reported for other cases like Co/Pt system. The effect of 5$\AA$ Pd capping on these bare Co films made an remarkable change on the transition of magnetic easy axis. Out-of-plane MCD signals exists up to 20$\AA$ Co thickness, and disappears at 24$\AA$ Co thickness. In-plane MCD signals first appears at 10$\AA$ Co thickness and gradually increases up to 24$\AA$ Co thickness. Between 10$\AA$ and 20$\AA$ Co thickness, in-plane and out-of-plane MCD signal coexist. The formation of multi-domain structure or the existence of tilted magnetic easy axis is an possible scenario for such an interesting coexistence. The effect of interface roughness was also tested by measuring MCD signal on Co films deposited on un-annealed Pd(111) surface. Out-of-plane MCD signal was observed up to 8$\AA$ Co thickness and the anisotropy of MCD signal at 4$\AA$ Co thickness was very large with respect to that of Co film deposited on the smooth substrate. Above 8$\AA$ thickness, there exists only in-plane MCD signal. From above results, it was concluded that both Pd capping and interface roughness induce and reenforce the perpendicular magnetic anisotropy. The large perpendicular magnetic anisotropy of Co/Pd multilayer system made by sputtering method can be well understood from our results.

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Magnetic Properties and Application of Caltalysts in Biginelli Reaction for the Ni and Ni@C Synthesized by Levitational Gas Condensation (LGC) (부양증발응축법으로 제조된 Ni과 Ni@C의 자성특성 및 Biginelli 합성 촉매 적용연구)

  • Uhm, Young Rang
    • Journal of the Korean Magnetics Society
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    • v.27 no.3
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    • pp.87-91
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    • 2017
  • Carbon-encapsulated Ni and metal Ni nanoparticles were synthesized by levitational gas condensation (LGC). Methane ($CH_4$) gas was used to coat the surface of the Ni nanoparticles. The Ni particles had a core diameter of 10 nm, and were covered by 2~3 nm thin carbon layers with multi-shells structure.The low magnetization comparing with the Ni nanoparticles without carbon-shell results in the coexistence of nonmagnetic carbon and a large surface spin percentage with disordered magnetization orientation for the nanoparticles. Biginelli reactions in the presence of L-proline and Ni and carbon encapsulated Ni nanoparticles were carried out to change the ratio between stereoisomers. The obtained S-enantiomers for 3,4-dihydropyrimidine (DHPM) using catalysts of Ni, and Ni@C was an excess of about ${\Delta}{\sim}7.4%$ and ${\Delta}{\sim}19.6%$, respectively. The nanopowders were fully recovered using magnet to reuse as a catalyst. The Ni@C was shown at same yield to formation of 3,4-DHPM, though it was recycled for catalyst in the reaction.

Disruption of Sex Differentiation by Exogenous Sex Steroid Hormones in Korean Rockfish, Sebastes schlegeli (외인성 성스테로이드 호르몬에 의한 조피볼락, Sebastes schlegeli의 성분화 교란)

  • Kwon, Joon-Yeong;Lee, Chan-Hee;Kim, Ju-Yeong;Kim, Sang-Hun;Kim, Dae-Jung;Han, Hyoung-Kyun;Lim, Han-Kyu;Byun, Sun-Gyu
    • Development and Reproduction
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    • v.10 no.4
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    • pp.247-254
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    • 2006
  • It is well publicized that the existence of various endocrine disrupting chemicals threatens normal sexual development of many sedentary marine fishes in the coastal areas. However, a suitable marine fish species for efficient monitoring of this threatening has yet to be identified. One of the difficulties in estimating the effect of endocrine disruption in marine fish is the absence of clear distinction between testicular and ovarian structures at the early stages of sex differentiation. In search of a potential test species, we have investigated the microscopic structures of sexually undifferentiated and differentiated gonads and the susceptibility of gonadal differentiation to exogenous sex steroids during the sex differentiation period in a sedentary marine rockfish, Sebastes schlegeli. Male gonads in this species contained dark pigmentation that made them distinct from female gonads. Treatment either with $estradiol-17\;{\beta}(E_2)$ or $17\;{\alpha}-methyltestosterone$ (MT) significantly altered the sex ratios with the complete sex changes or the occurrence of ovotestis that was easily identified by the mixed structure of dimorphic gonads (coexistence of ovarian cavity/primary oocytes and dark pigmentation/seminiferous tubules). Results in this study suggest that S. schlegeli can be developed as a monitoring/test fish species for endocrine disruption in marine fish in the coastal areas.

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The World View of the Middle Ages Fantasy Game (중세 판타지 게임의 세계관 연구)

  • Seo, Seong-Eun
    • The Journal of the Korea Contents Association
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    • v.9 no.9
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    • pp.114-124
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    • 2009
  • 73 percent of online games in Korea hold perspectives of medieval times in them. So far in history, about a millennium in medieval times is said to be a period of darkness and savagery, but it is newly revived in the digital virtual world. Such phenomenon is paradoxical and meaningful to often bring out 'medieval times' as a theme for online games, which are revealed by up-to-date technologies in present days. This research examines the background of views of medieval times appeared in online games and how they are realized. Medieval fantasy games have appeared because people dream about escaping from pre-modem times and have fantasy about medieval times. Moreover, perspectives of medieval times have enormously influenced background epics, quest stories, creation of characters in a game scenario. The dual structure having coexistence of nature and super naturalness acts an important role to set up the epic for medieval fantasy games. And medieval romance literature, which has a three-step quest narrative of 'targeting - adventure and fight - achievement' is reflected in a quest story of medieval fantasy games. The strict pyramid system represented by feudalism forms a meaningful metaphor for designing characters, and players organize communities for online games through horizontal collective consciousness in such vertical system of history at the same time.

Recent Progress and Tasks of Arms Control in South and North Korea (최근 남북한 군비통제의 추진현황과 과제)

  • Kim, Kang-nyeong
    • Korea and Global Affairs
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    • v.3 no.2
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    • pp.87-130
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    • 2019
  • This paper aims to analyze the recent progress(current situation) and tasks of arms control in North and South Korea. To this end the paper is composed of 5 chapters titled instruction; recent progress(current situation) of arms control in South and North Korea; constraints and tasks of arms control on the Korean peninsula; and conclusion. One of the most important tasks for the establishment of a peace structure for the coexistence of the Korean people in the 21st century is the realization of military control in order to resolve the acute military confrontation situation and mutual threats. With the 2018 PyeongChang Winter Olympics, the North-South summit and the subsequent talks for peace and denuclearization on the Korean Peninsula, the North Korea-US summit, and subsequent talks are creating conditions for trust building and arms control between the two Koreas. The military trust between the two Koreas and operational arms control are being achieved through the declaration of the April 27 Panmunjom and the 'Military Agreement for the Implementation of the Panmunjom Declaration.' However, since there are constraints on the control of arms control, such as the persistence of hostility and distrust of the two Koreas, the defense treaty between the two Koreas and neighboring countries, the competition of neighboring countries and the complex interests of the Korean peninsula, Trust Building is important. We should resolve the issue of arms control between the two Koreas, taking into account the trend of international arms control over the internal and external dynamics of the Korean peninsula gradually and carefully, with a vision of long-term unification security.

A study on the Jeonwonsasiga of Shin Gye Young - focused on the 'Jesuk' - (신계영의 <전원사시가> 고찰 - '제석(除夕)'의 의미를 중심으로 -)

  • Kim Sang-Jean
    • Sijohaknonchong
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    • v.24
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    • pp.113-137
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    • 2006
  • This paper is a study on the Jeonwonsasiga of Shin Gye Young. Jeonwonsasiga is as a out of Sasiga-Line(사시가계) Yeonsijo(연시조), the singing Spring. Summer. Autumn, Winter and Jesuk. The meanwhile, a study on the Jeonwonsasiga is in the relations with other literary works, or a history of Siga in 17th century. A out of specific character's of Jeonwonsasiga is the singing Spring, Summer, Autumn, Winter and Jesuk about order. Jesuk with a New year's Eve, is the stand for a watch night.'Chun Ha Chu Dong(Spring, Summer, Autumn, Winter, 춘하추동)' are included in the Sasi of One Year(일년 사시), And the Jesuk is included in the Sasi of one day(하루 사시). Buy the way, Jeonwonsasiga make an equal about all of two. And then, this paper is focused on the 'Jesuk'. The role of Jesuk is coexistence together with the Sasi of One Year and the Sasi of one day. That is to say, Jeonwonsasiga's singing from the 1st works to the 8st works are the Sasi of One Year in the surface. But, singing the Sasi of One Day of 'Dan Ju Mo Ya(단주모야)' in the inside story. And Jesuk is a finished role the mean's of literary works. And this provide an opportunity which can be speaker's recognition of Jeonwon (전원). The Jeonwonsasiga of ten works are have a value of Yeonsijo in continyal structure. And so. it is to be watched sense of proportion of Yeonsijo in the 17th century.

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Modularization of Automotive Product Architecture: Evidence from Passenger Car (자동차 아키텍처의 모듈화: 승용차 사례를 중심으로)

  • Kwak, Kiho
    • Journal of Technology Innovation
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    • v.27 no.2
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    • pp.37-71
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    • 2019
  • How has the passenger car's architecture evolved? In the meantime, the discussions on the car architecture have been mixed, i.e., integral, modular, and the coexistence of two types. Therefore, in this study, we aim to develop two indices can measure the degree of modularization of passenger car and its all modules using global trade data. By applying the indices to the framework of architecture positioning that reflects the hierarchical structure of a product, we examined that the degree of modularization of the passenger car architecture has been enhanced. Meanwhile, the degree of modularization differs across the modules that make up the car. Specifically, we observed the higher degree of modularization in front-end, cockpit and seat modules. Whereas, we found that body module had a relatively low degree of modularization. In particular, we observed that the platform of passenger car has notably modularized due to carmakers' efforts to achieve model diversification and reduction of cost and period in new product development at the same time. Interestingly, we showed that three modules, i.e., engine, chassis (relatively less modularized), and transmission (relatively highly modularized), had a different level of modularization, even if they commonly make up the platform. We contribute to the suggestion for analytical approaches that examine the degree of modularization and its progress longitudinally. In addition, we propose the necessity of decomposition of a system into elements in a study of product architecture, considering the possibly distinctive progress of modularization across the elements.

Analysis of bifurcation characteristics for the Seolmacheon experimental catchment based on variable scale of source basin (수원 유역의 변동성 규모를 기반으로 한 설마천 시험유역의 분기 특성 해석)

  • Kim, Joo-Cheol;Jung, Kwan Sue
    • Journal of Korea Water Resources Association
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    • v.54 no.5
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    • pp.289-299
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    • 2021
  • This study analyzes bifurcation characteristics of the Seolmacheon experimental catchment by extracting the shape variation of channel network due to variable scale of source basin or threshold area. As the area of source basin decreases, a bifurcation process of channel network occurs within the basin of interest, resulting in the elongation of channel network (increase of total channel length) as well as the expansion of channel network (increase of the source number). In the former case, the elongation of channel reaches overwhelms the generation of sources, whereas, in the latter case, the drainage path network tends to fulfill the inner space of the basin of interest reflecting the opposite trend. Therefore, scale invariance of natural channel network could be expressed to be a balanced geomorphologic feature between the elongation of channel network and the expansion of channel network due to decrease of source basin scale. The bifurcation structure of the Seolmacheon experimental catchment can be characterized by the coexistence of the elongation and scale invariance of channel network, and thus a further study is required to find out which factor is more crucial to rainfall transformation into runoff.