• Title/Summary/Keyword: structure H

Search Result 9,094, Processing Time 0.046 seconds

Structural characterization of ladder-type cadmium(II) citrate complex, (C3H12N2)[{Cd(H2O)(C6H5O7)}2]·6H2O

  • Kim, Chong-Hyeak;Lee, Sueg-Geun
    • Analytical Science and Technology
    • /
    • v.20 no.4
    • /
    • pp.355-360
    • /
    • 2007
  • The title complex, $(C_3H_{12}N_2)[\{Cd(H_2O)(C_6H_5O_7)\}_2]{\cdot}6H_2O$, I, has been prepared and its structure characterized by FT-IR, EDS, elemental analysis, ICP-AES, and X-ray single crystallography. It is triclinic system, $P{\bar{1}}$ space group with a = 10.236(2), b = 11.318(2), c = $13.198(2){\AA}$, ${\alpha}=77.95(1)^{\circ}$, ${\beta}=68.10(1)^{\circ}$, ${\gamma}=78.12(1)^{\circ}$, V = $1373.5(3){\AA}^3$, Z = 2. Complex I has constituted by protonated 1,3-diaminopropane cations, citrate coordinated cadmium(II) anions, and free water molecules. The central cadmium atoms have a capped trigonal prism geometry by seven coordination with six oxygen atoms of three different citrate ligands and one water molecule. Citrate ligands are bridged to three different cadmium atoms. Each cadmium atom is linked by carboxylate and hydroxyl groups of citrate ligand to construct an one-dimensional ladder-type assembly structure. The polymeric crystal structure is stabilized by three-dimensional networks of the intermolecular O-H${\cdots}$O and N-H${\cdots}$O hydrogen-bonding interaction.

Seismic Analysis of Rack Structure with Fluid-Structure Interaction (유체와 구조물의 연성을 고려한 rack 구조물의 내진해석)

  • Kim, S.J.;Lee, Y.S.;Ryu, C.H.;Yang, K.H.;Jung, S.H.
    • Proceedings of the KSME Conference
    • /
    • 2001.11a
    • /
    • pp.465-470
    • /
    • 2001
  • In this study, the seismic analysis of rack structure with fluid-structure interaction is performed through use of the Finite Element Method(FEM) code ANSYS. Fluid-structure interaction can specify in terms of an hydrodynamic effect which is defined as the added mass per unit length divided by the area of the cross section. Using the Floor Response Spectrum(FRS) obtained through the time-history analysis, modal analysis and seismic analysis under Operating Basis Earthquake(OBE) and Safe Shutdown Earthquake(SSE) condition is carried out. The fluid-structure interaction effects on the rack structure are investigated.

  • PDF

Studies on coexistence phenomena of structure I and H hydrates (구조-I 및 구조-H 하이드레이트의 공존 현상 규명 연구)

  • Seo, Yu-Taek;Lee, Jong-Won;Seo, Young-Won;Lee, Huen
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2007.11a
    • /
    • pp.573-576
    • /
    • 2007
  • 가스 하이드레이트의 구조-I 및 구조-H의 공존 현상을 13C NMR과 Raman spectroscopy를 이용하여 분석하였다. 하이드레이트 생성 조건이 구조-H 영역에만 있을 때는 CH4+neohexane 혼합 하이드레이트가 구조-H만을 나타냈지만, 구조-I의 영역에서는 구조-H의 혼합 하이드레이트와 구조-I의 순수 메탄 하이드레이트가 공존하는 것을 $^{13}C$ NMR spectra를 통해 확인하였다. 이러한 현상은 구조-H 생성자로 알려진 isopentane, MCP, MCH 에서도 관찰되었으며, Raman spectroscopy를 이용해서도 확인할 수 있었다.

  • PDF

Structure-Control Combined Design with Structure Intensity

  • Park, Jung-Hyen;Kim, Soon-Ho
    • International Journal of Ocean Engineering and Technology Speciallssue:Selected Papers
    • /
    • v.6 no.1
    • /
    • pp.60-68
    • /
    • 2003
  • This paper proposes an optimum design method of structural and control systems, using a 2-D truss structure as an example. The structure is subjected to initial static loads and disturbances. For the structure, a FEM model is formed. Using modal transformation, the equation of motion is transformed into modal coordinates, in order to decrease D.O.F. of the FEM model. To suppress the effect of the disturbances, the structure is controlled by an output feedback $H_{\infty}$ controller. The design variables of the combined optimal design of the control-structure systems are the cross sectional areas of truss members. The structural objective function is the structural weight. The control objective function is the $H_{\infty}$ norm, the performance index of control. The second structural objective function is the energy of the response related to the initial state, which is derived from the time integration of the quadratic form of the state in the closed-loop system. In a numerical example, simulations have been perform. Through the consideration of structural weight and $H_{\infty}$ norm, an advantage of the combined optimum design of structural and control systems is shown. Moreover, since the performance index of control is almost nearly optimiz, we can acquire better design of structural strength.

  • PDF

Comparison of Adsorption Configurations between Phenylalanine and Tyrosine on Ge(100)

  • Im, Hui-Seon;Yang, Se-Na;Lee, Han-Gil
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2011.08a
    • /
    • pp.216-216
    • /
    • 2011
  • We will investigate the bonding configurations of phenylalanine and tyrosine adsorbed on the Ge(100) surface using CLPES and DFT calculations. First, the C 1s, N 1s, and O 1s spectra obtained at 300 K revealed that both the amine and carboxyl groups of phenylalanine and tyrosine concurrently participated in adsorption on the Ge(100) surface without bond breaking using CLPES, depending on the extent of coverage. In the second place, we confirmed that the "O-H dissociated-N dative bonded structure" is the most stable structure implying kinetically favorable structure, and the "O-H dissociation bonded structure" is another stable structure manifesting thermodynamically advantageous structure using DFT calculations. This tendency turns up both phenylalanine and tyrosine, similarly. Furthermore, through the CLPES data and DFT calculation data, we discovered that the "O-H dissociated-N dative bonded structure" and the "O-H dissociation bonded structure" are preferred at 0.30 ML and 0.60 ML, respectively. Moreover, we found that the phenyl ring of phenylalanine is located in axial position to Ge(100) surface, but the phenyl ring of tyrosine is located in parallel to Ge(100) surface using DFT calculations.

  • PDF

Analytical Study of H-Honeycomb Sandwich Core Structure Model based on Truss (트러스를 기반으로 형성된 H-벌집형 샌드위치 심재 모델의 해석적 연구)

  • Choi, Jeong-Ho
    • Journal of the Korean Society of Industry Convergence
    • /
    • v.20 no.2
    • /
    • pp.133-140
    • /
    • 2017
  • This paper is a study of the central structural unit model of the sandwich core structure. The applied model is based on the honeycomb structure formed by the truss, the H-shaped honeycomb structure formed by adding the truss of H shape to the space of the center portion, and the honeycomb structure formed by the plate. Applied material property is AISI 304 stainless steel, which has cost effectiveness and easy to get near place. The truss diameter of the model is three different type: 1mm, 2mm and 3mm. ABAQUS software is obtained to do the analysis and applied test is quasi-static loading. Boundary conditions for the analysis are that vertical direction loading at top place without any rotation and bottom surface is fixed. The test results show that the H-truss model has the highest stiffness and yield strength. Therefore, it is hoped that more and more researching for the development of a unit model in sandwich core structure has been investigating and that the developed sandwich core model can be applied into various industrial fields such as mechanical or aerospace industries.

Combined Design of Robust Control System and Structure System (강인성 제어 시스템과 구조 시스템의 통합 최적 설계)

  • Park, J.H.
    • Journal of Power System Engineering
    • /
    • v.7 no.4
    • /
    • pp.38-43
    • /
    • 2003
  • This paper proposes an optimum design problem of structural and control systems. taking a 3-D truss structure as an example. The structure is supposed to be subjected to initial static loads and time-varying disturbances. The structure is controlled by a state feedback $H_{\infty}$ controller to suppress the effect of the disturbances. The design variables are the cross sectional areas of truss members. The structural objective function is the structural weight. As the control objective, we consider two types of performance indices. The first function represents the effect of the initial loads. The second one is the norm of the feedback gain. These objective functions are in conflict with each other. Then, first, two control objective functions are transformed into one control objective by the weighting method. Next, the structural objective is treated as the constraint. By introducing the second control objective which considers the magnitude of the feedback gain, we can per limn the design which is robust in modeling errors.

  • PDF

FLUID-STRUCTURE INTERACTION ANALYSIS FOR HIGH ANGLE OF ATTACK MANEUVER MISSILE (고받음각에서 기동하는 미사일의 공력-구조 연계 해석)

  • Noh, K.H.;Park, M.Y.;Park, S.H.;Lee, J.W.;Byun, Y.H.
    • 한국전산유체공학회:학술대회논문집
    • /
    • 2007.10a
    • /
    • pp.111-114
    • /
    • 2007
  • Computational Fluid Dynamics (CFD) and the Finite Element Method (FEM) are used to perform aerodynamics analysis and structure analysis. For the fluid-structure interaction analysis, each technology should be considered as well. The process of aerodynamics-structure coupled analysis can be applied to various integrated analyses from many research fields. In this study, the aerodynamics-structure coupled analysis is performed for the missile at high angle of attack condition through the use of Computational Fluid Dynamics (CFD) and the Finite Element Method (FEM). For this purpose, the aerodynamics-structure coupled analyses procedure for the missile are established. The results of the integrated analysis are compared with rigid geometry of the missile and the effect of the deformation will be addressed.

  • PDF