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http://dx.doi.org/10.5806/AST.2007.20.4.355

Structural characterization of ladder-type cadmium(II) citrate complex, (C3H12N2)[{Cd(H2O)(C6H5O7)}2]·6H2O  

Kim, Chong-Hyeak (Center for Chemical Analysis, Korea Research Institute of Chemical Technology)
Lee, Sueg-Geun (Center for Chemical Analysis, Korea Research Institute of Chemical Technology)
Publication Information
Analytical Science and Technology / v.20, no.4, 2007 , pp. 355-360 More about this Journal
Abstract
The title complex, $(C_3H_{12}N_2)[\{Cd(H_2O)(C_6H_5O_7)\}_2]{\cdot}6H_2O$, I, has been prepared and its structure characterized by FT-IR, EDS, elemental analysis, ICP-AES, and X-ray single crystallography. It is triclinic system, $P{\bar{1}}$ space group with a = 10.236(2), b = 11.318(2), c = $13.198(2){\AA}$, ${\alpha}=77.95(1)^{\circ}$, ${\beta}=68.10(1)^{\circ}$, ${\gamma}=78.12(1)^{\circ}$, V = $1373.5(3){\AA}^3$, Z = 2. Complex I has constituted by protonated 1,3-diaminopropane cations, citrate coordinated cadmium(II) anions, and free water molecules. The central cadmium atoms have a capped trigonal prism geometry by seven coordination with six oxygen atoms of three different citrate ligands and one water molecule. Citrate ligands are bridged to three different cadmium atoms. Each cadmium atom is linked by carboxylate and hydroxyl groups of citrate ligand to construct an one-dimensional ladder-type assembly structure. The polymeric crystal structure is stabilized by three-dimensional networks of the intermolecular O-H${\cdots}$O and N-H${\cdots}$O hydrogen-bonding interaction.
Keywords
cadmium ion; citrate ligand; 1,3-diaminopropane; crystal structure; ladder-type assembly;
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