• Title/Summary/Keyword: structural silica

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Sulfate Resistance of Alkali Activated Pozzolans

  • Bondar, Dali;Lynsdale, C.J.;Milestone, N.B.;Hassani, N.
    • International Journal of Concrete Structures and Materials
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    • v.9 no.2
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    • pp.145-158
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    • 2015
  • The consequence of sulfate attack on geopolymer concrete, made from an alkali activated natural pozzolan (AANP) has been studied in this paper. Changes in the compressive strength, expansion and capillary water absorption of specimens have been investigated combined with phases determination by means of X-ray diffraction. At the end of present investigation which was to evaluate the performance of natural alumina silica based geopolymer concrete in sodium and magnesium sulfate solution, the loss of compressive strength and percentage of expansion of AANP concrete was recorded up to 19.4 % and 0.074, respectively.

Optical and Structural Characteristics of Europium Doped Organic-Inorganic Hybrid Film by Sol-Gel Process (졸겔 공정을 이용하여 Europium을 doping한 유기-무기 복합막의 광학적 및 구조적 특성)

  • 김진균;오동조;김유항;황진명
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.106-106
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    • 2003
  • 최근 집적형 광소자, 레이저 재료, 자료 저장 또는 통신 기술부문에서 제어된 광학적 성질을 갖는 유기-무기 나노 복합체를 만드는 연구가 많은 관심과 주목을 받고 있다. 유기물인 PEG는 대다수의 금속염을 고정시키는 용매 역할을 하는 polymer로써 액체와 같은 특징을 나타내며 무기물인 silica의 network는 순수한 PEG 시스템보다 좋은 기계적 물성을 나타내며, 투명한 물질을 얻을 수 있게 해 준다. 이에 본 연구에서는 SiO2-PEG의 matrix에 우수한 광학적 성질을 지닌 europium을 doping하여 유기-무기 나노 복합막을 합성하여 europium의 농도와 PEG 분자량에 따른 구조적 및 광학적 성질을 알아보고자 한다.

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High Performance Concrete Mixture Design using Artificial Neural Networks (신경망을 이용한 고성능 콘크리트의 배합설계)

  • 양승일;윤영수;이승훈;김규동
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.05a
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    • pp.545-550
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    • 2002
  • Concrete is one of the essential structural materials in the construction. But, concrete consists of many materials and is affected by many factors such as properties of materials, site environmental situations, and skill of constructor. Therefore, concrete mixes depend on experiences of experts. However, it is more and more difficult to determine concrete mixes design by empirical means because more ingredients like mineral and chemical admixtures are included. Artificial Neural Networks(ANN) are a mimic models of human brain to solve a complex nonlinear problem. They are powerful pattern recognizers and classifiers, also their computing abilities have been proven in the fields of prediction, estimation and pattern recognition. Here, among them, the back propagation network and radial basis function network are used. Compositions of high-performance concrete mixes are eight components(water, cement, fine aggregate, coarse aggregate, fly ash, silica fume, superplasticizer and air-entrainer). Compressive strength and slump are measured. The results show that neural networks are proper tools to minimize the uncertainties of the design of concrete mixtures.

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Scale Morphologies for Identification of Marine Nanoflagellates (해양 미소 편모조류의 종 동정을 위한 인편 형태에 관한 연구)

  • Kim, Hyeung-Sin;Jung, Min-Min
    • ALGAE
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    • v.20 no.4
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    • pp.305-314
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    • 2005
  • 5 Haptophyta 2 Chrysophyta and 1 Prasinophyta species of scale-bearing nanoflagellates were collected in coastal water of Korea and identified by examination of their scales with Field Emission Scanning Electron Microscope (JSM-6700F). These included Chrysochromulina ahrengoti, C. simplex, C. spinifera, Prymnesium parvum, P. patelliferum, Mamiella gilva, Paraphysomonas imperforata and Pa. vestita. The surface of cells covered with unmineralised scales (5 Haptophyte and 1 Prasinophyta species) or silica scales (2 Chrysophyta species). Scale-covered flagella are found in the 1 Prasinophyta species. One of the main structural characteristics of Haptophyte is the haptonema, a filiform organelle which occurs together with the two flagella. It may be long and coiling upon irritation as in Chrysochromulina, or short and noncoiling as in Prymnesium.

Characterization and Structural Dtercination of an Antifungal Compound Produced by Pseudomonas aeruginosa KGM-100 (Pseudomonas aeruginosa KGM-100이 생산하는 항생물질의 특성 및 구조)

  • Kim, Kyung-Seok;Hong, Su-Hyung;Lee, Eun-Ju;Park, Yong-Bok;Park, Yong-Tae;Ha, Ji-Hong
    • Microbiology and Biotechnology Letters
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    • v.23 no.1
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    • pp.98-103
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    • 1995
  • During the screening of antifungal antibiotics from microbial metabolites, we selected Pseudomonas aeruginosa KGM-100 showing powerful antagonistic activity against various phytopathogenic fungi. Antibiotics KGM-100A and KGM-100B were purified from the culture broth of Pseudomonas aeruginosa KGM-100 by diaion HP-20 column chromatography, ethyl acetate extraction, silica gel column chromatography, preparative TLC and recrystallization. KGM-100A which was recrystallized in MeOH showed antimicrobial activities against a broad spectrum of fungi and bacteria. Physico-chemical properties of KGM-100A were determined and identified to be phenazine-l-carboxylic acid by UV, IR, $^{1}$H-NMR, $^{13}$C-NMR, mass spectrum, and elemental analyses.

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An apt material model for drying shrinkage and specific creep of HPC using artificial neural network

  • Gedam, Banti A.;Bhandari, N.M.;Upadhyay, Akhil
    • Structural Engineering and Mechanics
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    • v.52 no.1
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    • pp.97-113
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    • 2014
  • In the present work appropriate concrete material models have been proposed to predict drying shrinkage and specific creep of High-performance concrete (HPC) using Artificial Neural Network (ANN). The ANN models are trained, tested and validated using 106 different experimental measured set of data collected from different literatures. The developed models consist of 12 input parameters which include quantities of ingredients namely ordinary Portland cement, fly ash, silica fume, ground granulated blast-furnace slag, water, and other aggregate to cement ratio, volume to surface area ratio, compressive strength at age of loading, relative humidity, age of drying commencement and age of concrete. The Feed-forward backpropagation networks with Levenberg-Marquardt training function are chosen for proposed ANN models and same implemented on MATLAB platform. The results shows that the proposed ANN models are more rational as well as computationally more efficient to predict time-dependent properties of drying shrinkage and specific creep of HPC with high level accuracy.

A Novel Method for the Fabrication of Monodispersed Carbon Nanospheres and Their Crosslinked Forms

  • Im, Ji-Eun;Lee, Ha-Na;Li, Jing;Kim, Yong-Rok
    • Bulletin of the Korean Chemical Society
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    • v.35 no.3
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    • pp.871-874
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    • 2014
  • Monodispersed carbon nanospheres (CNSs) were fabricated by a novel method and their structural properties were investigated. CNSs were prepared by the pyrolysis of nanospherical polystyrenes (PS). With the coating of $SiO_2$ shell, PS particles were effectively separated during pyrolysis process which resulted to CNSs with an average diameter of 40 nm. Moreover, CNSs could be crosslinked with each other through the bondings between the functional groups on their surfaces. Morphology of the fabricated carbon spheres and their crosslinked form were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and fourier transform infrared spectroscopy (FT-IR).

Structural Elucidation and Antimicrobial Activity of an Antibiotic, Echinomycin, Produced by Actinomycetes KGT-37 (Actinomycetes KGT-37 균주가 생산하는 항생물질 Echinomycin의 구조해석 및 항균활성)

  • 여운형;김영호;윤봉식;박은경
    • Korean Journal Plant Pathology
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    • v.12 no.3
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    • pp.302-306
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    • 1996
  • 항균물질을 생산하는 방선균 KGT-37를 인삼밭 토양에서 분리하여 배양액으로부터 항균물질을 분리하고 silica gel column chromatography, preparative TLC, HPLC로 정제하였다. \ulcornerH-\ulcornerH COSY, HMQC, HMBC등 NMR 분석결과 KGT-37이 생산하는 항균물질은 cyclic depsipeptide계의 항생물질인 echinomycin으로 동정되었으며 이 연구에서 지금까지 assign되지 않았던 \ulcornerH과\ulcornerC의 NMR signal이 완전히 assign되었다. 이 항균활성물질은 감자더뎅이병균인 Streptomyces scabies과 Corynebacterium lilium을 포함하는 그람 양성 세균에 특히 강한 항균활성을 보였으며, 도열병균 및 점무늬낙엽병균 등 병원곰팡이에도 항균활성을 나타내었다.

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Structural Analysis of a Cavitary Region Created by Femtosecond Laser Process

  • Fujii, Takaaki;Goya, Kenji;Watanabe, Kazuhiro
    • Journal of Power System Engineering
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    • v.19 no.3
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    • pp.5-10
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    • 2015
  • Femtosecond laser machining has been applied for creating a sensor function in silica glass optical fibers. Femtosecond laser pulses make it possible to fabricate micro structures in processed regions of a very thin glass fiber line because femtosecond laser pulses can extremely minimize thermal effects. With the laser machining to optical fiber using a single shot of 210-fs laser at a wavelength of 800 nm, it was observed that a processed region surrounded a thin layer which seemed to be a hollow cavity monitored by scanning electron microscopy (SEM). This study aims at a theoretical investigation for the processed region by using a numerical analysis in order to embed sensing function to optical fibers. Numerical methods based finite element method (FEM) has been used for an optical waveguide modeling. This report suggests two types modeling and describes a comparative study on optical losses obtained by the experiment and the numerical analysis.

Characterization of SnO2 thin films grown by pulsed laser deposition under transverse magnetic field

  • Park, Jin Jae;Kim, Kuk Ki;Roy, Madhusudan;Song, Jae Kyu;Park, Seung Min
    • Rapid Communication in Photoscience
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    • v.4 no.3
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    • pp.50-53
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    • 2015
  • $SnO_2$ thin films were deposited on fused silica substrate by pulsed laser deposition under transverse magnetic field. We have explored the effects of magnetic field and ablation laser wavelength on the optical properties of laser-induced plasma plume and structural characteristics of the deposited $SnO_2$ films. Optical emission from the plume was monitored using an optical fiber to examine the influence of magnetic field on the population of the excited neutral and ionic species and their decay with times after laser ablation. Also, we employed photoluminescence, x-ray diffraction, and UV-Vis absorption to characterize $SnO_2$ films.