• Title/Summary/Keyword: structural silica

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Effect of Stage of Growth and Cultivar on Chemical Composition of Whole Maize Plant and Its Morphological Fractions

  • Firdous, R.;Gilani, A.H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.12 no.3
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    • pp.366-370
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    • 1999
  • Samples of whole plant, leaf and stem of Akbar, Neelum, UM-81 and lZ-31 cultivars of maize fodder harvested up to 14 weeks at different growth stages were drawn and analysed for dry matter contents and various cell wall constituents such as NDF, ADF, hemicellulose, cellulose, lignin, cutin and silica. The dry matter contents of whole maize plant, leaf and stem increased significantly (p<0.01) with advancing plant age. Maximum dry matter was found in the leaf fraction of the plant. The cell wall components continued to increase significantly (p<0.001) in whole maize plant and its morphological fractions as the age advanced. Maximum values for NDF, ADF, cellulose and lignin were observed in stem followed by whole plant and leaf, whereas hemicellulose, cutin and silica contents were higher in leaf fraction of the plant. The cultivars were observed to have some effects on chemical composition of all plant fraction. The results indicated that maturity had a much greater effect on the concentration of all the structural components than did the cultivars. It was concluded that maize fodder should be cut preferably between 8th to 9th week of age (flowering stage) to obtain more nutritious and digestible feed for livestock. Among the maize cultivars, Neelum proved to be the best, due to its higher dry matter contents and lower lignin concentration.

Seismic analysis in pad concrete foundation reinforced by nanoparticles covered by smart layer utilizing plate higher order theory

  • Taherifar, Reza;Zareei, Seyed Alireza;Bidgoli, Mahmood Rabani;Kolahchi, Reza
    • Steel and Composite Structures
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    • v.37 no.1
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    • pp.99-115
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    • 2020
  • This article deals with the dynamic analysis in pad concrete foundation containing Silica nanoparticles (SiO2) subject to seismic load. In order to control the foundation smartly, a piezoelectric layer covered the foundation. The weight of the building by a column on the foundation is assumed with an external force in the middle of the structure. The foundation is located in soil medium which is modeled by spring elements. The Mori-Tanaka law is utilized for calculating the equivalent mechanical characteristics of the concrete foundation. The Kevin-Voigt model is adopted to take into account the structural damping. The concrete structure is modeled by a thick plate and the governing equations are deduced using Hamilton's principle under the assumption of higher-order shear deformation theory (HSDT). The differential quadrature method (DQM) and the Newmark method are applied to obtain the seismic response. The effects of the applied voltage to the smart layer, agglomeration and volume percent of SiO2 nanoparticles, damping of the structure, geometrical parameters and soil medium of the structure are assessed on the dynamic response. It has been demonstrated by the numerical results that by applying a negative voltage, the dynamic deflection is reduced significantly. Moreover, silica nanoparticles reduce the dynamic deflection of the concrete foundation.

Effect of molar ratios on strength, microstructure & embodied energy of metakaolin geopolymer

  • Abadel, Aref A.;Albidah, Abdulrahman S.;Altheeb, Ali H.;Alrshoudi, Fahed A.;Abbas, Husain;Al-Salloum, Yousef A.
    • Advances in concrete construction
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    • v.11 no.2
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    • pp.127-140
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    • 2021
  • In this study, twenty-five geopolymer (GP) mixes were prepared by varying the alkaline solids to Metakaolin (MK) and sodium silicate to NaOH ratios from 0.1 to 0.5 and 0.2 to 1.0, respectively, thus giving a wide range of molar ratios of silica to alumina, sodium oxide to alumina and water to sodium oxide. The compressive strength of these GP mixes was determined for four curing schemes involving oven curing at 100℃ for 24 h and three ambient curing with the curing ages of 3, 14, and 28 days. The test results revealed that for the manufacture of GP binder for structural applications of strength up to 90 MPa, the molar ratio of silica to alumina should be greater than 2.3, sodium oxide to alumina should be between 0.6 to 1.2, and water to sodium oxide should not exceed 12. The compressive strength of ambient cured GP mortar gets stabilized at 28 days of ambient curing. Experimental findings were also corroborated by GP microstructure analysis. The embodied energy of MK-based GP mortars, especially of high strength, is significantly less than the cement mortar of equivalent strength.

Isolation and structural elucidation of the herbicidal active compounds from Ligularia stenocephala M.

  • Lim, Chi-Hwan;Cho, Chong-Woon
    • Korean Journal of Agricultural Science
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    • v.48 no.2
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    • pp.343-351
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    • 2021
  • Screening was conducted using 200 kinds of plant extracts to explore herbicide-activated components of plant origin. We separated and purified active substances and elucidated chemical structures using Ligularia stenocephala M., which has strong activity and has not yet been studied. When the solvent fractions of the leaves of Ligularia stenocephala M. were tested for their herbicidal activity, ethyl acetate and chloroform layer showed an inhibition rate of 95.2% and 94.1%, respectively. In particular, the chloroform layer exerted more than 50% herbicidal activity at 10 ppm. From the chloroform layer with the highest herbicidal activity, we isolated three herbicidal active compounds using stepwise chromatography, specifically silica gel or octadecyl silica (ODS) column chromatography, Sep-pak cartridges, and high performance liquid chromatography (HPLC). Based on the analysis of the active compounds using electron ionization mass spectroscopy (EI-MS), 1H-NMR, and 13C-NMR, we identified the active compounds as euparin, 5,6-dimethoxy-2-isopropenylbenzofuran, and liguhodgsonal. When the herbicidal activity of the identified compounds was tested, euparin showed selective herbicidal activity for lettuce at 10-3 M, and both liguhogsonal and 5,6-dimethoxy-2-isoprophenylbenzofuran exerted selective activity for rice and Echinochloa crus-galli.

Estimation of splitting tensile strength of modified recycled aggregate concrete using hybrid algorithms

  • Zhu, Yirong;Huang, Lihua;Zhang, Zhijun;Bayrami, Behzad
    • Steel and Composite Structures
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    • v.44 no.3
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    • pp.389-406
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    • 2022
  • Recycling concrete construction waste is an encouraging step toward green and sustainable building. A lot of research has been done on recycled aggregate concretes (RACs), but not nearly as much has been done on concrete made with recycled aggregate. Recycled aggregate concrete, on the other hand, has been found to have a lower mechanical productivity compared to conventional one. Accurately estimating the mechanical behavior of the concrete samples is a most important scientific topic in civil, structural, and construction engineering. This may prevent the need for excess time and effort and lead to economic considerations because experimental studies are often time-consuming, costly, and troublous. This study presents a comprehensive data-mining-based model for predicting the splitting tensile strength of recycled aggregate concrete modified with glass fiber and silica fume. For this purpose, first, 168 splitting tensile strength tests under different conditions have been performed in the laboratory, then based on the different conditions of each experiment, some variables are considered as input parameters to predict the splitting tensile strength. Then, three hybrid models as GWO-RF, GWO-MLP, and GWO-SVR, were utilized for this purpose. The results showed that all developed GWO-based hybrid predicting models have good agreement with measured experimental results. Significantly, the GWO-RF model has the best accuracy based on the model performance assessment criteria for training and testing data.

Construction of sports-educational places using resistant and water-repellent raw materials in concrete

  • Wenbo Xu;Zhiqiang Zhu
    • Structural Engineering and Mechanics
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    • v.86 no.1
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    • pp.109-118
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    • 2023
  • Any place where exercise is common, such as a club, sports hall, or school, is considered a place for teaching sports. When doing sports, a very safe environment for sports should be chosen. The athlete should consider the safety of sports facilities and equipment, and if there is a defect, he should refrain from exercising in these places. The safety of sports facilities is very effective in creating people's sports activities, with the benefits of staying away from physical harm, enjoying sports, and having mental peace. Everyone has the right to participate in sports and recreation and to ensure that they enjoy a safe environment. The ability to manage and solve issues that may arise plays the most critical role in creating a safe environment. The quality of construction materials used for the construction of sports facilities is of great importance. In this work, the resistance and water repellency of concrete constituents for the construction of sports buildings have been investigated by nanoscience. Nano-concrete material solves the main problem of concrete surfaces, i.e., the entry of water and humidity into the structure. It also gives it a self-cleaning ability with its water repellency. Nanoparticles are placed between pores and cover the cracks, which causes roughness in the surface structure of concrete. The high roughness of the surface of the coated concrete caused its super-hydrophobicity. In hydrophobic surfaces, the higher the contact angle, the more hydrophobic the surface will be. In order to investigate the hydrophobic properties, silica nanoparticles, silica nanoparticles, and fly ash were prepared on concrete, and their properties were analyzed.

Capacity and the moment-curvature relationship of high-strength concrete filled steel tube columns under eccentric loads

  • Lee, Seung-Jo
    • Steel and Composite Structures
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    • v.7 no.2
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    • pp.135-160
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    • 2007
  • Recently, CFT column has been well-studied and reported on, because a CFT column has certain superior structural properties as well as good productivity, execution efficiency, and improved rigidity over existing columns. However, CFT column still has problems clearing the capacity evaluation between its steel tube member and high-strength concrete materials. Also, research on concrete has examined numerical values for high-strength concrete filled steel square tube columns (HCFT) to explain transformation performance (M-${\phi}$) when a short-column receives equal flexure-moment from axial stress. Moment-curvature formulas are proposed for HCFT columns based on analytic assumption described in this paper. This study investigated structural properties (capacity, curvature), through a series of experiments for HCFT with key parameters, such as strength of concrete mixed design (58.8 MPa), width-thickness ratio (D/t), buckling length to sectional width ratio (Lk/D) and concrete types (Zeolite, Fly-ash, Silica-fume) under eccentric loads. A comparative analysis executed for the AISC-LRFD, AIJ and Takanori Sato, etc. Design formulas to estimate the axial load (N)-moment (M)-curvature (${\phi}$) are proposed for HCFT columns based on tests results described in this paper.

Structural Properties and Diffusion Behaviors of Liquid Silica at Finite Temperatures (특정 온도에서 용융 실리카의 확산거동 및 구조분석)

  • Lee, Byoung-Min
    • Journal of the Korean Ceramic Society
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    • v.44 no.6 s.301
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    • pp.319-324
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    • 2007
  • The structural properties of $SiO_2$ liquid at finite temperatures have been investigated by molecular dynamics (MD) simulations utilizing the Tersoff interatomic potential. During cooling process, the $SiO_2$ liquid structure quenched with a cooling rate of $1.0{\times}10^{11}K/sec$ shows the traditional properties observed in the experiments. The coordination defects of system decrease with decreasing temperature up to 17%. The $SiO_2$ glass quenched up to 1600 K contains defects consisting of the fivefold coordination of Si, and the threefold coordination of O atoms. The calculated diffusion coefficients which are calculated by monitoring. the mean-square displacement of atoms drop to almost zero below 3000 K ($<10^{-6}\;cm^2/sec$) but has a fluctuations at low temperature. The structure properties of $SiO_2$ liquid shows a significant dependence on the temperature during cooling process. Bond-angle distribution at around $120^{\circ}$ originate from the O and Si atoms consisting of the over-coordinated O atoms.

Durability and Bioassay of a Sulfur Polymer Surface Protecting Agent for Concrete Structures (콘크리트 구조물용 유황폴리머 표면보호재의 내구성능 및 생물독성)

  • Seok, Byoung-Yoon;Lee, Byung-Jae;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.6
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    • pp.29-36
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    • 2015
  • In this study, to examine the use of sulfur polymer as a coating agent for concrete, durability and hazard evaluations were performed. The result of the evaluation indicated that the chemical resistance of the coating agent for concrete was outstanding against acidic, base, and alkaline solutions. The evaluation of the bond strength after an accelerated weathering test depending on the mixing condition indicated that the most outstanding strength characteristic was obtained when silica powder and fly ash were mixed at the same time. The bond strength exceeded 1 MPa in every mixing condition even after the repeated hot and cold treatment of the coating agent specimen for concrete, and the SFS mix proportion showed the highest bond strength. The examination of the accelerated carbonation and chloride ion penetration resistance of the concrete coated with the coating agent indicated that the specimen coated with the coating agent using silica powder as a filler showed the most outstanding durability. When a fish toxicity test was performed to examine the hazard of the use of the functional polymer as a coating agent for concrete, the functional polymer was found to have no effect on the organisms. When the chemical resistance, freezing and thawing resistance, carbonation, and chloride ion penetration resistance of the coating agent were considered, substituting silica powder and fly ash as the fillers of the functional polymer by 20%, respectively, was the optimal level in the range of this study.

Basic Properties of Polymer Cement Composites with Polymer Dispersions and Cement for Crack Repair (폴리머 디스퍼전과 시멘트로 만든 균열보수용 폴리머 시멘트 복합체의 기초적 성질)

  • Young-Kug Jo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.5
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    • pp.97-104
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    • 2023
  • The aim of this study was to produce polymer cement composites (PCCs) composed of polymer dispersion and cement as crack repair materials for RC structures, and to investigate their fundamental properties. The test mixtures for the study were based on EVA and SAE polymer dispersions, and the water-cement ratio was determined while varying the polymer-cement ratio(P/C) in four different levels (20%, 60%, 80%, and 100%) to achieve the desired viscosity of PCCs considering their fillability as crack repair materials. Additionally, silica fume was incorporated into P/C 80% and 100% specimens to enhance their stiffness. The basic properties of PCCs as crack repair materials, such as viscosity, flowability, fillability, tensile strength, elongation, and modulus of elasticity, were examined. The results showed that P/C depending on the type of polymer significantly affected the viscosity and flowability, and appropriate w/c ratios were needed to achieve the desired viscosity for the mixture design with consideration of fillability as crack repair materials for RC structures. All designed mixtures in this study exhibited excellent fillability. The tensile strength and elongation of PCCs satisfied the KS regulation for cement- polymer modified waterproofing coatings. The incorporation of silica fume improved the tensile strength and modulus of elasticity of PCCs. Depending on the type of polymer, mixtures using SAE showed better fundamental properties as crack repair materials for RC structures compared to those using EVA. In conclusion, SAE-based P/C 80% or 100% with the addition of up to 30% silica fume can be recommended as suitable mixtures for crack repair of RC structures.