• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2003년도 international symposium on advanced powder metallurgy
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• pp.27-32
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• 2003

The phenomenon of electrical explosion of conductors is considered in the context of the changes in the energy and structural states of the metal at the stages of energy delivery and relaxation of the primary products of EEC. It is shown that these changes are related to the forced interaction of an intense energy flux with matter and to the subsequent spontaneous relaxation processes. The characteristics of nano-sized metal powders are also discussed.

• Bulletin of the Korean Chemical Society
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• 제24권10호
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• pp.1470-1474
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• 2003

The dynamics of the tertiary conformation of myoglobin (Mb) after photolysis of carbon monoxide was investigated at 283 K solution by probing amide I and II bands using femtosecond IR absorption spectroscopy. Time-resolved spectra in the amide region evolve with 6-12 ps time scale without noticeable subpicosecond dynamics. The spectra measured at 100 ps delay after photolysis is similar to the difference FTIR spectrum at equilibrium. Time-resolved spectra of photoexcited Mb evolve modestly and their amplitudes are less than 8% of those of photolyzed MbCO, indicating that thermal contribution to the spectral evolution in the amide region is negligible. These observations suggest that the conformational relaxation ensuing photolysis of MbCO be complex and the final deoxy protein conformation have been substantially formed by 100 ps, probably with 6- 12 ps time constant.

• Structural Engineering and Mechanics
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• 제17권5호
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• pp.727-734
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• 2004

An uncoupled computational model for analyzing the hygrothermal dynamic response of composite laminates has been developed. The constitutive equations, expressed in an integral form, and involving relaxation moduli are adopted, to describe the non-aging hygrothermorheologically simple materials. A Prony series represents the relaxation moduli is exploited in order to derive a recursive relationship, and thereby eliminate the storage problem that arises when dealing with material possessing memory. The problem is formulated in a descritized variational form. Mindlin and higher order finite elements are employed for spatial descretization, while the Newmark average acceleration scheme is exploited for temporal descritization. The adopted recursive formula uses only the details of the previous event to compute the details of the current one. Numerical results of the displacement fields of both thin and thick viscoelastic laminates problems are discussed to show up the effectiveness of Mindlin and higher-order shear theories.

• Structural Engineering and Mechanics
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• 제53권2호
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• pp.277-296
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• 2015

The objective of this paper is to investigate the surface waves in fibre-reinforced anisotropic thermoelastic medium subjected to gravity field. The theory of generalized surface waves has firstly developed and then it has been employed to investigate particular cases of waves, viz., Stoneley waves, Rayleigh waves and Love waves. The analytical expressions for displacement components, force stress and temperature distribution are obtained in the physical domain by using the harmonic vibrations. The wave velocity equations have been obtained in different cases. The numerical results are given and presented graphically in Green-Lindsay and Lord-Shulman theory of thermoelasticity. Comparison was made with the results obtained in the presence and absence of gravity, anisotropy, relaxation times and parameters for fibrereinforced of the material medium. The results indicate that the effect of gravity, anisotropy, relaxation times and parameters for fibre-reinforced of the material medium are very pronounced.

• Bulletin of the Korean Chemical Society
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• 제22권7호
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• pp.693-698
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• 2001

Ab initio density functional calculations on the structural isomers, the hydration energies, and the hydrogen bond many-body interactions for gauche-, trans-protonated ethylenediamine-(water)3 complexes (g-enH+(H2O)3, t-enH+(H2O)3) have been performed. The structures and relative stabilities of three representative isomers (cyclic, tripod, open) between g-enH+(H2O)3 and t-enH+(H2O)3 are predicted to be quite different due to the strong interference between intramolecular hydrogen bonding and water hydrogen bond networks in g-enH+(H2O)3. Many-body analyses revealed that the combined repulsive relaxation energy and repulsive nonadditive interactions for the mono-cyclic tripod isomer, not the hydrogen bond cooperativity, are mainly responsible for the greater stability of the bi-cyclic isomer.

• Structural Engineering and Mechanics
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• 제78권3호
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• pp.297-303
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• 2021

In this paper, a mathematical model is used to the evaluation of thermoelastic interactions in fiber-reinforced material with a spherical cavity. With the goal of establishing the generalized thermoelastic model with thermal relaxation time are exploited. inner surface of the spherical cavity is tractions free and loaded by the uniform step in temperature. The finite element scheme is used to get the problem numerical solutions. The numerical results have been discussed graphically to show the impacts of the presence and the absence of reinforcement.

• 한국자기공명학회논문지
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• 제22권4호
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• pp.76-81
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• 2018

Investigation of the protein-protein interaction mode at atomic resolution is essential for understanding on the underlying functional mechanisms of proteins as well as for discovering druggable compounds blocking deleteriou interprotein interactions. Solution NMR spectroscopy provides accurate and precise information on intermolecular interactions even for weak and transient interactions, and it is also markedly useful for examining the change in the conformation and dynamics of target proteins upon binding events. In this mini-review, we comprehensively describe three unique and powerful methods of solution NMR spectroscopy, paramagnetic relaxation enhancement (PRE), pseudo-contact shift (PCS), and residual dipolar coupling (RDC), for the study on protein-protein interactions.

• 한국자기공명학회논문지
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• 제23권2호
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• pp.40-45
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• 2019

The phase transition temperatures and thermodynamic properties of $(NH_4)_2MnCl_4{\cdot}2H_2O$ grown by the slow evaporation method were studied using differential scanning calorimetry and thermogravimetric analysis. A structural phase transition occurred at temperature $T_{C1}$ (=264 K), whereas the changes at $T_{C2}$ (=460 K) and $T_{C3}$ (=475 K) seemed to be chemical changes caused by thermal decomposition. In addition, the chemical shift and the spin-lattice relaxation time $T_{1{\rho}}$ were investigated using $^1H$ magic-angle spinning nuclear magnetic resonance (MAS NMR), in order to understand the role of $NH_4{^+}$ and $H_2O$. The rise in $T_{1{\rho}}$ with temperature was related to variations in the symmetry of the surrounding $H_2O$ and $NH_4{^+}$.

• Structural Engineering and Mechanics
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• 제82권4호
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• pp.469-476
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• 2022

A mathematical model of Lord-Shulman photo-thermal theorem induced by pulse heat flux is presented to study the propagations waves for plasma, thermal and elastic in two-dimensional semiconductor materials. The medium is assumed initially quiescent. By using Laplace-Fourier transforms with the eigenvalue method, the variables are obtained analytically. A semiconductor medium such as silicon is investigated. The displacements, stresses, the carrier density and temperature distributions are calculated numerically and clarified graphically. The outcomes show that thermal relaxation time has varying degrees of effects on the studying fields.

• Corrosion Science and Technology
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• 제11권2호
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• pp.48-55
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• 2012

Clamping force of a high strength bolt is reduced by a certain period of time after the initial set-up. In case of special treatments on faying surfaces such as protective coating, clamping force is relaxed more severely. Tests for slip critical joints subject to various faying surface parameters were conducted. Five different surface treatments were tested including mill scale surface, blast surface, rust surface and coated surfaces. Each specimen was composed of F10T M20 of high strength bolts and steel plates. Based on the result of slip coefficient test, blast treatment surface showed 0.59, rust treatment surface showed 0.54 and inorganic zinc treatment surface exhibited 0.44. Clean mill treatment surface and red lead paint treatment surface were 0.23, 0.21 respectively. It is identified that the slip coefficient in Korean structural design guide should be determined for various surface conditions. Subsequently from long term relaxation test of ASTM A 490 high strength bolts, relaxation of no-coated surfaces such as blast, clean mill, rust treatment, the loss of initial clamping load was 10.5%, 13.6% and 7.9% for 1,000 hours, while the loss of initial clamping force was reached as 15.0%, 18.7% more than the required redundancy 10% in case of inorganic zinc and red lead painted treatment. It is required that the limit of relaxation on coated faying surface should be established separately for various surfaces.