• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.463-463
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• 2014

Dye-sensitized solar cells (DSSCs) have generated a strong interest in the development of solid-state devices owing to their low cost and simple preparation procedures. Effort has been devoted to the study of electrolytes that allow light-to-electrical power conversion for DSSC applications. Several attempts have been made to substitute the liquid electrolyte in the original solar cells by using (2,2',7,7'-tetrakis (N,N-di-p-methoxyphenylamine)-9-9'-spirobi-fluorene (spiro-OMeTAD) that act as hole conductor [1]. Although efficiencies above 3% have been reached by several groups, here the major challenging is limited photoelectrode thickness ($2{\mu}m$), which is very low due to electron diffusion length (Ln) for spiro-OMeTAD ($4.4{\mu}m$) [2]. In principle, the $TiO_2$ layer can be thicker than had been thought previously. This has important implications for the design of high-efficiency solid-state DSSCs. In the present study, we have fabricated 3-D Transparent Conducting Oxide (TCO) by growing tin-doped indium oxide (ITO) nanowire (NWs) arrays via a vapor transport method [3] and mesoporous $TiO_2$ nanoparticle (NP)-based photoelectrodes were prepared using doctor blade method. Finally optimized light-harvesting solid-state DSSCs is made using 3-D TCO where electron life time is controlled the recombination rate through fast charge collection and also ITO NWs length can be controlled in the range of over $2{\mu}m$ and has been characterized using field emission scanning electron microscopy (FE-SEM). Structural analyses by high-resolution transmission electron microscopy (HRTEM) and X-Ray diffraction (XRD) results reveal that the ITO NWs formed single crystal oriented [100] direction. Also to compare the charge collection properties of conventional NPs based solid-state DSSCs with ITO NWs based solid-state DSSCs, we have studied intensity modulated photovoltage spectroscopy (IMVS), intensity modulated photocurrent spectroscopy (IMPS) and transient open circuit voltages. As a result, above $4{\mu}m$ thick ITO NWs based photoelectrodes with Z907 dye shown the best performing device, exhibiting a short-circuit current density of 7.21 mA cm-2 under simulated solar emission of 100 mW cm-2 associated with an overall power conversion efficiency of 2.80 %. Finally, we achieved the efficiency of 7.5% by applying a CH3NH3PbI3 perovskite sensitizer.

• Proceedings of the KWS Conference
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• 2009.11a
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• pp.92-92
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• 2009

조선업을 포함한 다양한 산업 분야에서 후판 강재의 수요량 증가와 함께 사용 범위 또한 폭넓게 되고 있다. 특히, 선박의 수송효율의 극대화를 위하여 컨테이너선의 대형화가 급속하게 진행되고 있으며, 2009년 현재1,300TEU 이상의 초대형 컨테이너선이 건조되고 이다. 이처럼 용접구조물의 초대형화에 따른 사용강재 또한 고강도 극후물화 되고 있다. 현재 선박에 적용중인 고강도 강재는 EH47 강재로 YP 460MPa 급의 강재가 Hatch Coamming부에 적용중에 있으며, 강재의 두께 또한 70mm 이상이다. 이러한 고강도 극후물재의 강구조물에 적용에 따른 선급협회에서는 용접부에서의 취성균열 전파에 의한 취성파괴의 위험성이 있으므로 강재의 두께를 제한하고 더욱 엄격한 파괴인성값을 요구하고 있다. 일본선급협회(NK)를 중심으로 취성균열의 정지를 위한 모재의 요구 성능등에 관한 연구들이 진행되고 있다. 이 연구의 대부분의 전제 조건은 선박의 블럭과 블럭의 조립시에 용접부가 직선형이 아닌 계단형(Butt shift)를 하는 것으로 하고 있으므로, 국내의 조선건조 공법의 현실과는 거리감이 있다. 본 연구에서는 국내 조선사에서 수행중인 직선 이음부에 대한 시공 공법에서 취성균열이 발생하여 진전 되더라도 균열을 정지 시킬 수 있는 기술에 관한 연구를 수행하였다. 균열의 진전은 대부부의 연속면에서는 정지를 시키지 못하고 직진 전파 하여서 파괴에 도달하게 된다. 따라서 뭔가의 불연속적인 면을 임의로 생성하여야 균열을 정지 시킬 수 있다. 본 연구에서는 이러한 균열의 정지 방법으로 형상적인 측면과 재료적인 측면에서 검토를 수행하였다. 형상적인 측면에서는 균열을 정지 시키고자 하는 위치에 불연속적인 면을 만들기 위하여 일정 크기의 hole을 만들어서 균열을 정지시켰으며, 재료적인 측면에서는 고인성의 용접재료를 사용하여서 취성균열이 진행하는 경로에 인성을 높은 재료를 적용하여 불연속적인 면의 생성과 함께 인성을 높여서 균열을 정지 시키는 기술을 개발하였다. 이러한 기술의 개발을 통하여 취성균열의 전파에 의한 파괴를 방지 할 수 있으며, 용접구조물의 안전성 확보를 가능하게 하였다.

• Journal of the Korean Wood Science and Technology
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• v.35 no.6
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• pp.1-12
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• 2007

For the purpose of effective utilization of domestic second-grown larch as structural members, post and beam construction applying traditional construction to Japanese larch glulam members was adopted with processing by machine pre-cut method. In general, horizontal shear test by KS F 2154 is conducted to assess the horizontal shear properties of the wooden structure by post and beam construction. The frame was consisted of post and beam member with appropriate fasteners, and members have their own processed parts (notch, hole, etc.) that can be well-connected each other. The shear wall was consisted of the frame with screw-nail sheathed panel (OSB). The results of horizontal shear loading tests without vertical loads conducted on the frame and the shear wall structures, the maximum strengths were about 1.9 kN/m and about 9.7 kN/m, the shear rigidities were about 167 kN/rad, 8198 kN/rad, respectively. The strength proportion of the frame specimen was about 20% of the wall's and about 2% in initial stiffness. Nail failures are remarkable on the shear wall specimen with punching shears and shear failures. The shear load factor for the shear wall specimen by the method of Architectural Institute of Japan was 1.5, which was obtained by the bi-linear method. Loading method should be considered to obtain smooth load-deformation relationship. For the better shear performance of the structures, column base and post and beam connections and sheathed panel should be further examined as well.

• Journal of the Korean Magnetics Society
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• v.16 no.1
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• pp.45-50
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• 2006

Oxygen-deficient anatase and rutile titanium dioxide $(TiO_{2-\delta})$ thin films were prepared by a sol-gel method and their structural, electronic, and magnetic properties were investigated. Both anatase and rutile $TiO_{2-\delta}:Fe$ Fe films exhibited ferromagnetism at room temperature for a limited range of Fe doping. For the same amount of Fe doping, the anatase sample exhibited a higher magnetic moment than the rutile one. Result of conversion electron Mossbauer spectroscopy measurements indicates that $Fe^{3+}$ ions substituting the octahedral $Ti^{4+}$ sites mainly contribute to the room-temperature ferromagnetism. Some of the anatase $TiO_{2-\delta}:Fe$ films exhibited p-type character but the observed feromagnetism turns out to be independent of the hole concentration. The room-temperature ferromagnetism can be explained in terms of a direct ferromagnetic coupling between two neighboring $Fe^{3+}$ ions via an electron trapped in oxygen vacancy in $TiO_{2-\delta}:Fe$.

• Korean Journal of Materials Research
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• v.13 no.8
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• pp.519-523
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• 2003

We report the synthesis of cubic spinel $ZnCo_2$$O_4$thin films and the tunability of the conduction type by control of the oxygen partial pressure ratio. Zinc cobalt oxide films were grown on$ SiO_2$(200 nm)/Si substrates by reactive magnetron sputtering method using Zn and Co metal targets in a mixed Ar/$O_2$atmosphere. We found from X-ray diffraction measurements that the crystal structure of the zinc cobalt oxide films grown under an oxygen-rich condition (the $O_2$/Ar partial pressure ratio of 9/1) changes from wurtzite-type $Zn_{1-x}$ $Co_{X}$O to spinel-type $ZnCo_2$$O_4$with the increase of the Co/Zn sputtering ratio,$ D_{co}$ $D_{zn}$ . We noted that the above structural change accompanied by the variation of the majority electrical conduction type from n-type (electrons) to p-type (holes). For a fixed $D_{co}$ $D_{zn}$ / of 2.0 yielding homogeneous spinel-type $_2$O$ZnCo_4$films, the type of the majority carriers also varied, depending on the$ O_2$/Ar partial pressure ratio: p-type for an $O_2$-rich and n-type for an Ar-rich atmosphere. The maximum electron and hole concentrations for the Zn $Co_2$ $O_4$films were found to be 1.37${\times}$10$^{20}$ c $m^{-3}$ and 2.41${\times}$10$^{20}$ c $m^{-3}$ , respectively, with a mobility of about 0.2 $\textrm{cm}^2$/Vs and a high conductivity of about 1.8 Ω/$cm^{-1}$ /.

• Korean Journal of Heritage: History & Science
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• v.46 no.3
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• pp.68-77
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• 2013

This report is based on the investigation of potholes which are formed by fluvial erosion. A pothole is called so because it is a hole that looks like a coffeepot. The results of previous studies are applied to the 'Jakgwaecheon Porthole' of this study. The study is focused on the dimension and morphology of the Pothole and investigates the effects of stream sediments, river flow, geological structural lines, etc. on the formation of potholes. As a result of measuring 61 potholes in this area, we recognized that the elliptical dish-shaped cross sections are dominant and inferred that their longitudinal direction on the plain is affected by the direction of the stream flow. Also, 'Jakgwaecheon Pothole' is very characterized in terms of scale and morphology. Furthermore, it is harmonious with the beautiful landscape, humanity, and historical values and it can be suggested that it is qualified to be registered as a geoheritage structure.

• Journal of The Korean Society of Grassland and Forage Science
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• v.22 no.2
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• pp.145-152
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• 2002

To compare the Carbon metabolic response to high temperature stress in Zoysiagrass [Zoysia matrella (L.) Merr.] and Creeping bentgrass (Agrostis palustris Huds) with respect to heat tolerance, C metabolites were determined from April to September. Sampling was carried out on an established golf course (Muan Country Club, Chonnam, Korea). Shoot mass(g Dry weight per hole cup) of creeping bentgrass started to decrease from June and recovered from August whereas that of zoysiagrass was less varied. Chlorophyll content in creeping bentgrass was significantly higher than zoysiagrass until July, and then decreased by 43% from July to August. Zoysiagrass contained higher soluble sugar than creeping bentgrass throughout experimental period. Soluble sugar in zoysiagrass increased about 58% from April to May, and less varied until August. Soluble sugar in creeping bentgrass slightly increased until July and sharply decreased at August. Starch concentration in zoysiagrass continuously decreased to September after a significant increase from April to May. A remarkable fluctuation in both starch and fluctuation concentration was observed between June and August showing high accumulation for June to July and high degradation for July to August. These results suggest that through creeping bentgrass suffers much severely from high temperature stress than zoysiagrass especially June to August. An active accumulation and degradation in nonstructural carbohydrate in creeping bentgrass during this period might be associated with heat stress.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.33 no.2
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• pp.112-121
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• 1988

Soybean seed coat consisted of three layers, and the aleurone layer was attached to the innermost part of seed coat. It showed the different morphological characteristics with single cell layer compared with many cell layers in barley aleurone layer. The structural difference in aleurone cell among varieties was not detected in this experiment. The hole of middle part of hilum consisted of net formed material in order to pass water and gas. In the experiment, it was not studied whether the varieties with hard seed consist of the same structure or not, but the detailed study on this would be necessary. The activity of acid phosphatase showed a tendency to increase in process of imbibition in distilled water. There was no significant difference in the enzyme activity among the varieties tested, but the enzyme activity of Danyoupkong was slightly higher than that of Hwanggeumkong. In germinability, Danyoupkong is higher than Hwangkeumkong, so it might be attributed to the higher activity. There was no difference in acid phosphatase activity between released from the aleurone cell and accumulated in the aleurone cell from 6 to 12 hours incubation of the medium in the absence of GA$_3$, but the difference was detected after 12 hours incubation. And enzyme activity was the highest in the 18 hours incubation. The increase in the release of acid phosphatase from the aleurone cell would be considered as passive diffusive effect due to the increase in turgo pressure of aleurone cell. The acid phosphatase released from aleurone layer increased greatly after 24 hours incubation of the medium in the presence of GA$_3$ and the accumulation within the aleurone cell decreased linearly after 18 hours incubation. The result indicates that GA$_3$ enhance the rate of enzyme release from aleurone layer, suggests that the aleurone cell wall be digested by the introduction of GA and the digested wall act as the channels for enzyme release.

• Economic and Environmental Geology
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• v.44 no.4
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• pp.313-320
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• 2011

The Taebaegsan Mineralized District is the most prospective region for the useful mineral commodities such as a coal, non-metallic, metallic mineral in South Korea. From a general point of view, Cambro- Ordovician limestone formations, Myobong slate and Pungchon (Daegi) limestone, are the most fertilizable formations in the Taebaegsan Mineralized District. The geology around Weondong mine area consists mainly of Carboniferous-Triassic formations and Cambro-Ordovician formations intruded by rhyolite/quartz porphyry. The great overthrusted fault of N40~$50^{\circ}E$ direction, so called Weondong overthrust fault, is observed in the central part of the mine area and the NS fault system cuts the overthrusted fault. By postulating from the favorable geological and structural condition around Weondong area, the possibility of deep seated hidden ore bodies is expected. In 2010, on the basis of the results of LOTEM and CSAMT survey, the cross-hole survey was performed for the investigation of the hidden polymetallic ore body in the deep parts of the Weondong mine area and the grade of the newly-discovered orebody is as follows; (1) The cut-off grade for lead-zinc 3%; an weighted average grade 5.50% (2.7 m), (2) The cutoff grade for copper 0.1%; an weighted average grade 0.91% (14.65 m), (3) The cut-off grade for iron 30%; an weighted average grade 38.18% (3.3 m), (4) $WO_3$ for each cut-off grade(0.01%, 0.05%, 0.1%); an weighted average grade 0.29 wt. % (8.8 m), 1.15 wt. % (2.1 m), 1.97 wt. % (1.2 m), (5) $MoS_2$ for each cut-off grade(0.01%, 0.1%); an weighted average grade 0.15 wt. % (6.3S m), 0.28 wt. % (3.15 m), (6) $Ta_2O_5$ for each cut-off grade (0.01%, 0.1%); an weighted average grade 0.13% (19.S m), 1.11% (1.8 m), (7) $Nb_2O_5$ for each cut-offgrade (0.01%, 0.1%); an weighted average grade 0.06% 11.5 m), 0.15% (3.0 m).

• Journal of Intelligence and Information Systems
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• v.20 no.1
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• pp.177-193
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• 2014

Over the past decade, there has been a rapid diffusion of electronic commerce and a rising number of interconnected networks, resulting in an escalation of security threats and privacy concerns. Electronic commerce has a built-in trade-off between the necessity of providing at least some personal information to consummate an online transaction, and the risk of negative consequences from providing such information. More recently, the frequent disclosure of private information has raised concerns about privacy and its impacts. This has motivated researchers in various fields to explore information privacy issues to address these concerns. Accordingly, the necessity for information privacy policies and technologies for collecting and storing data, and information privacy research in various fields such as medicine, computer science, business, and statistics has increased. The occurrence of various information security accidents have made finding experts in the information security field an important issue. Objective measures for finding such experts are required, as it is currently rather subjective. Based on social network analysis, this paper focused on a framework to evaluate the process of finding experts in the information security field. We collected data from the National Discovery for Science Leaders (NDSL) database, initially collecting about 2000 papers covering the period between 2005 and 2013. Outliers and the data of irrelevant papers were dropped, leaving 784 papers to test the suggested hypotheses. The co-authorship network data for co-author relationship, publisher, affiliation, and so on were analyzed using social network measures including centrality and structural hole. The results of our model estimation are as follows. With the exception of Hypothesis 3, which deals with the relationship between eigenvector centrality and performance, all of our hypotheses were supported. In line with our hypothesis, degree centrality (H1) was supported with its positive influence on the researchers' publishing performance (p<0.001). This finding indicates that as the degree of cooperation increased, the more the publishing performance of researchers increased. In addition, closeness centrality (H2) was also positively associated with researchers' publishing performance (p<0.001), suggesting that, as the efficiency of information acquisition increased, the more the researchers' publishing performance increased. This paper identified the difference in publishing performance among researchers. The analysis can be used to identify core experts and evaluate their performance in the information privacy research field. The co-authorship network for information privacy can aid in understanding the deep relationships among researchers. In addition, extracting characteristics of publishers and affiliations, this paper suggested an understanding of the social network measures and their potential for finding experts in the information privacy field. Social concerns about securing the objectivity of experts have increased, because experts in the information privacy field frequently participate in political consultation, and business education support and evaluation. In terms of practical implications, this research suggests an objective framework for experts in the information privacy field, and is useful for people who are in charge of managing research human resources. This study has some limitations, providing opportunities and suggestions for future research. Presenting the difference in information diffusion according to media and proximity presents difficulties for the generalization of the theory due to the small sample size. Therefore, further studies could consider an increased sample size and media diversity, the difference in information diffusion according to the media type, and information proximity could be explored in more detail. Moreover, previous network research has commonly observed a causal relationship between the independent and dependent variable (Kadushin, 2012). In this study, degree centrality as an independent variable might have causal relationship with performance as a dependent variable. However, in the case of network analysis research, network indices could be computed after the network relationship is created. An annual analysis could help mitigate this limitation.