• Title/Summary/Keyword: structural disordering

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A Study on the Methodology of the Plasticity Enhancement of Amorphous Alloys (비정질 합금의 소성 증가 방법에 대한 연구)

  • Park, K.W.;Lee, C.M.;Lee, K.B.;Lee, J.C.
    • Transactions of Materials Processing
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    • v.17 no.7
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    • pp.486-490
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    • 2008
  • This study demonstrates that preloading via the elastostatic compression imposed on amorphous alloys at room temperature induces homogeneous plastic strain associated with structural disordering. This structural disordering causes disorder, which at room temperature creates excess free volume and in turn enhances the plasticity. In this study, we investigated the effects of various parameters, such as stress level, flow rate and preloading time, on the degree of the structural disordering at room temperature. On the basis of the present findings, we proposed a method of enhancing the plasticity of amorphous alloys.

Structural Disordering and Relaxation Process in an Amorphous Alloy (비정질 합금의 구조완화 및 구조무질서화)

  • Kim, Hyun-Su;Yoon, Kyeu-Sang;Lee, Jae-Chul
    • Korean Journal of Metals and Materials
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    • v.49 no.11
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    • pp.823-830
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    • 2011
  • Structural change in an amorphous alloy was measured by applying a load below the global yield stregth at ambient temperatures. It was observed that the magnitude of the apparent structural change occuring in the amorphous alloy is determined by the compatative relationship between the stress-induced disordering process and the thermally-activated relaxation process. Structural disorder was observed to take place even at a stress well below the global yield, and the degree of the disorder was increased abruptly at the earlier stage of loading and saturated with time. In the mean time, unlike the previous belief, the relaxation process was observed to occur even at embient temperatures, and the degree of the relaxation was observed to increase linearly with time. The analytical equation predicting the structural change was proposed.

Energy Absorption Capability of Amorphous Alloys During Homogeneous Deformation (균일변형시 비정질 합금의 에너지 흡수력 평가)

  • Park, Kyoung-Won;Lee, Chang-Myeon;Lee, Hong-Gi;Lee, Jae-Hoon;Lee, Jae-Chul
    • Korean Journal of Metals and Materials
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    • v.46 no.9
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    • pp.572-576
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    • 2008
  • Elastostatic compression tests were carried out on amorphous alloys to evaluate their energy absorption capability during homogeneous deformation at room temperature. Experiments demonstrated that a compressive stress below the global yield imposed on amorphous alloys for extended periods causes homogeneous plastic strain associated with the irreversible structural disordering. During the disordering process, free volume was created, dissipating the externally applied strain energy and the rate of creation was found to converge to a saturated value. We evaluated the capability of energy absorption of amorphous alloys during homogeneous deformation using recent theories on the evolution of the structural state.

Effect of the Compositional Modulation on the Plasticity of Amorphous Alloys: Shear Localization Viewpoint Interpretation (비정질 합금의 조성분리가 소성에 미치는 영향: 변형국부화 관점에서의 해석)

  • Lee, Mi-Rim;Park, Kyoung-Won;Sa, Hyun-Je;Lee, Jae-Chul
    • Korean Journal of Metals and Materials
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    • v.47 no.11
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    • pp.687-693
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    • 2009
  • Experiments have demonstrated that a moderate amount of Be added to $Zr_{57.5}Cu_{38.3}Al_{4.2}$ amorphous alloy enhances the plasticity of the alloy. In particular, $Zr_{54}Cu_{36}Al_{4}Be_{6}$ alloy exhibited 19% of strain to fracture along with a strength exceeding 2 GPa. Energy dispersive x-ray spectroscopy conducted on the $Zr_{54}Cu_{36}Al_{4}Be_{6}$ alloy exhibited the presence of compositional modulation, indicating that nm-scale phase separation had occurred at local regions. In this study, the role played by the nm-scale phase separation on the plasticity was investigated in terms of structural disordering, structural softening and shear localization in order to better understand the structural origin of the enhanced plasticity shown by the developed alloy.

Application of CBED Techniques of Energy Filtering TEM for Si-Al Disordering Study of Albite (알바이트의 Si-Al 배열상태 연구를 위한 에너지여과 투과전자현미경의 CBED법 적용)

  • Lee Young Boo;Kim Youn Joong;Lee Joung Hoo
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.4
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    • pp.327-338
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    • 2004
  • XRD studies on annealed Na-feldspar (Amelia albite) at $1100^{\circ}C$ showed rapid structural changes due to Si-Al disordering, which resulted in phase transformations from low albite to high albite by 4-days annealing test. TEM SAED analyses on the annealed samples revealed a trend of structural changes, but estimation of the structural state was difficult due to a large deviation of the SAED data. Optimum conditions of CBED analyses on albite was established by employing a cooling specimen holder, 120 kV of acceleration voltage, 37 Jim of condenser aperture size and 25 nm of spot size. A proper orientation showing distinct changes of HOLZ lines corresponding to the structure changes of albite turned out to be close to the [418] direction with $-1.2^{\circ}$ tilting, where the width of two HOLZ lines in low albite was opposite to those in high albite.

Fe-based Amorphous Alloy with High Strength and Toughness Synthesized based on nm-scale Phase Separation (nm-수준의 상분리를 이용하여 제조한 고강도 고인성 철계 비정질 합금)

  • Lee, Kwang-Bok;Park, Kyoung-Won;Yi, Sang-Ho;Lee, Jae-Chul
    • Korean Journal of Metals and Materials
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    • v.48 no.1
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    • pp.1-7
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    • 2010
  • Experiments have demonstrated that the addition of a moderate amount of V to $Fe_{52}Co_{(20-x)}B_{20}Si_4Nb_4V_x$ amorphous alloy enhances the plasticity of the alloy. In particular, $Fe_{52}Co_{17.5}B_{20}Si_4Nb_4V_{2.5}$ alloy withstood a maximum of 8.3% strain prior to fracture along with a strength exceeding 4.7 GPa. Energy dispersive x-ray spectroscopy conducted on the $Fe_{52}Co_{17.5}B_{20}Si_4Nb_4V_{2.5}$ alloy exhibited evidence of compositional modulation, indicating that nm-scale phase separation had occurred at local regions. In this study, the role played by nm-scale phase separation on the plasticity was investigated in terms of structural disordering and shear localization in order to better understand the structural origin of the enhanced plasticity shown by the developed alloy.

Magnetization Behavior of Ultra-thin FexCo1-x Alloy on Cr (100) Surface

  • Hossain, M.B.;Kim, C.G.;Chun, B.S.;Kim, W.;Hwang, C.Y.
    • Proceedings of the Korean Magnestics Society Conference
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    • 2013.05a
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    • pp.15-16
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    • 2013
  • Magnetization behavior of ultra thin $Fe_xCo_{1-x}$ alloy (where x varies from 0 to 100) has been investigated as functions of composition on Cr (100) substrate by using in situ surface magneto optical Kerr effect (SMOKE). It's always show in plane uniaxial magnetic anisotropy at room temperature (RT) & Low temperature (LT). It is observed that composition dependent coercive force maximum at about 30 at % Co and 70 at % Co atomic ratio and minimum near equiatomic site. The relative magnetic moments as composition variation also show magnetization collapse near equiatomic site. The magnetization behaviors of Fe-Co alloy on Cr (100) due to composition varies are supported the order-disordering as well as structural stability bcc (ferromagnetic)/fcc (anti-ferromagnetic) phase stability magnetism.

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