• Journal of the Korea institute for structural maintenance and inspection
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• v.15 no.1
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• pp.281-287
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• 2011

GFRP rebars could be deteriorated by concrete alkalinity. This paper focuses on the investigation of durability of GFRP rebars with ribs exposed to alkaline environment of concrete. It has been reported that the milled E-glass fibers in the ribs of GFRP rebar can increase bond strength between GFRP rebars and the concrete. In this study, the effect of milled alkaline resistant glass fibers (milled AR glass) and milled E-glass in the ribs on the durability of GFRP rebar is investigated through ISS tests and moist absorption tests of the bare rebar. To accelerate the effect of the alkalinity, high temperature($40^{\circ}C$) was applied. According to the test results, mix ratio of milled glass fibers in the ribs by weight had significant effect on durability of GFRP rebars with ribs. It is because that the high mix ratio may leads more voids in the ribs due to lower workability and formability. On the other hand, changing fiber type in the ribs from E-glass to AR-glass had no improvements on ISS strength of the GFRP rebar. Therefore, it is found that determination of proper mix ratio of milled glass fiber in the mixture for the formation of the ribs of the GFRP rebar is important.

• Journal of the Korea institute for structural maintenance and inspection
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• v.15 no.6
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• pp.195-200
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• 2011

KS F 2782 (for shotcrete accelerators) standard cross-section of tunnel construction or repair is a reinforcement used in the field of shotcrete accelerators as a criterion in assessing shotcrete performance. Thus, KS F 2782 by standard accelerator will determine the nature of the product of concrete accelerators that will be used to record variations in the product roles, through determination of the quality of the experimental method to identify only the quality of the many variables that exist. This evaluation standard has so far distinguished accelerator products in indoor experiments that do not meet quality standards but were mostly for an on-site accelerator mixed with the shotcrete after being quite satisfied with the level of quality in a certain number of products. This observation is derived from the results of an indoor experiment considered to verify whether the site is suitable for indoor experiments, and whether its actual location in the city is relevant to the accelerator quality, to find a way to test if it fits. This study centers on the material conditions of the shotcrete accelerator and a variety of experimental results, and used the Gilmore needle to compare the compressive strength and KS F 2782 specification of the accelerator as a means to ensure product quality conformity analysis and for further research experiments. In conclusion, a portion of KS F 2782 standard that fixes the problems that can be resolved from the ground up as a whole is not a review for the domestic reality. As an indoor experiment to ensure uniformity in the field when applied in a sufficient correlation, complement must be in place.

• Economic and Environmental Geology
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• v.42 no.5
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• pp.479-486
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• 2009

In natural environments, manganese (Mn) exists in the valence of +2, +3, and +4 and plays a pivotal role as a strong oxidant or reductant in the geochemical cycles of elements. Especially, Mn forms varying (oxyhydr)oxides. The oxidation state of structural Mn is characteristic to each oxide and is one of the most important factors controlling its geochemical behaviors such as solubility, sorption capacity, and redox potential. Therefore, it is important to elucidate processes governing Mn oxidation state in predicting the fate and transport of many redox sensitive elements in the environment. X-ray photoelectron spectroscopy (XPS) is a very useful method to determine the oxidation state of various elements in solid phases. In this study, the oxidation states of structural Mn in MnO, $Mn_2O_3$, $MnO_2$ were assessed based on the binding energy spectra of $Mn2p_{3/2}$ and Mn3s using XPS and were compared with those reported elsewhere. $Mn2p_{3/2}$ binding energies were determined as 640.9, 641.5, 641.8 eV for MnO, $Mn_2O_3$, $MnO_2$, respectively, which indicates that the binding energy increased with increasing Mn oxidation state. It was also noted that Ar etching may cause changes in electronic structure configuration on surface of the original sample.

• Journal of the Korea institute for structural maintenance and inspection
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• v.25 no.5
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• pp.15-23
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• 2021

In this paper, service life for RC(Reinforced Concrete) substructure subjective to carbonation was evaluated through deterministic and probabilistic method considering field investigation data and Design Code(KDS 14 20 40). Furthermore changes in service life with increasing COV(Coefficient of Variation) and equivalent safety index meeting the same service life were studied. From the investigation, the mean and its COV of cover depth were evaluated to 70.0 ~ 90.0 mm and 0.2, respectively. With intended failure probability of 10.0 % and 70 mm of cover depth, service life decreased to 137 years, 123 years, and 91 years with increasing COV of 0.05, 0.1, and 0.2, respectively. In the case of 80 mm of cover depth, it changes to 179 years, 161 years, and 120 years with increasing COV. The equivalent safety index meeting the same service life from deterministic method showed 1.66 ~ 3.43 for 70 mm of cover depth and 1.61 ~ 3.24 for 80 mm of cover depth, respectively. The various design parameters covering local environment and quality condition in deterministic method yields a considerable difference of service life, so that determination of design parameters are required for exposure conditions and parameter variation.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.2
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• pp.1-9
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• 2019

GGBFS(Ground Granulated Blast Furnace Slag), one of the representative concrete mineral admixtures, improves the long-term durability and engineering performance of concrete by latent hydraulic activity. In this study, considering 3 levels of W/B(0.37, 0.42, 0.47) and GGBFS replacement ratio(0 %, 30 %, 50 %), durability performances for chloride attack are evaluated, and equations which predict behavior of accelerated chloride diffusion are proposed. Also, the relationship between accelerated chloride diffusion coefficient and passed charge is evaluated. In target curing day, accelerated chloride diffusion tests(Tang's method, ASTM C 1202) and compressive strength(KS F 2405) are performed. In the 730 day's results of accelerated chloride diffusion coefficient, GGBFS concrete has up to 28 % of decreasing ratio compared to OPC concrete, and in those of passed charge, GGBFS concrete has up to 29 % of decreasing ratio compared to OPC concrete. Also, it is deemed that the impact of variation of W/B is less in GGBFS concrete than in OPC concrete. The equations which predict accelerated chloride diffusion coefficient and passed charge are drawn, based on the characteristics of mixture and test results. The equation which predicts passed charge shows slightly higher coefficient of determination than that which predicts accelerated chloride diffusion coefficient.

• Journal of the Korean GEO-environmental Society
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• v.12 no.3
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• pp.5-12
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• 2011

In this paper, after studying structural performance for the representative corrugated steel plate used in Korea, we proposed the optimum shape for section of corrugated steel plate considering a width of steel plates that can be produced currently in the factory. Using AISI(1986) in examination for the performance of the corrugated steel plate, we determined the mechanical limit of the optimum sections considering shear force and bending moment of corrugated steel plate and also determined the geometric limit of them considering formability, shapes and ratio between width of steel plate before forming and that after forming. As a result of examination for performance of steel plate applying algorithm for searching optimal sections algorithm developed in this study to the existing representative corrugated steel plate, allowable force and moment of inertia indicated the maximum values at bending radius 76mm and internal bending angle $50^{\circ}$. And as an application result of the optimum design system that used SS490 with 1,550mm of width and 4,700mm of length considering current production situation in Korea, we developed the new section with more than 2 times of structural performance comparing with existing corrugated steel plate.

• Journal of Microbiology and Biotechnology
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• v.17 no.12
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• pp.1970-1975
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• 2007

Squalene synthase plays an important role in the cholesterol biosynthetic pathway. Inhibiting this enzyme in hypercholesterolemia can lower not only plasma cholesterol but also plasma triglyceride levels. A squalene synthase inhibitor was screened from Prunus mume fruit, and then purified via sequential processes of ethanol extraction, HP-20 column chromatography, ethyl acetate extraction, silica gel column chromatography, and crystallization. The squalene synthase inhibitor was identified as chlorogenic acid with a molecular mass of 354 Da and a molecular formula of $C_{16}H_{18}O_9$ based on UV spectrophotometry, $^1H$ and $^{13}C$ NMRs, and mass spectrometry. Chlorogenic acid inhibited the squalene synthase of pig liver with an $IC_{50}$ level of 100 nM. Since chlorogenic acid was an effective inhibitor against the squalene synthase of an animal source, it may be a potential therapeutic agent for hypercholesterolemia.

• Journal of Korean Society of Steel Construction
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• v.12 no.5 s.48
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• pp.527-535
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• 2000

Accurate determination of the relative restraint of beam-to-column connections is important for both the strength and the serviceability of structural frames. But steel frame analysis is carried out under the assumption that the connections are either fixed or pinned. Overestimating the connection restraint can result in underestimating lateral sway and underestimating the connection restraint can lead to underestimating forces developed in the beams and columns. This implies that the exact stiffness of connections as well as the geometric effects should be considered in the frame analysis and the overall behavior of connections could be described adequately. Therefore, the stiffness matrix which is able to consider the moment-rotation of connection was derived previously and the modified exponential model, power model and the proposed log model are adopted for modeling the semi-rigid connections. The main purpose of this study is to examine the feasibility of the derived stiffness matrix and to show the validity of log model proposed.

• Interaction and multiscale mechanics
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• v.5 no.3
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• pp.229-265
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• 2012

Hygroexpansion of wood is a known and undesired characteristic in civil engineering. When wood is exposed to changing environmental humidity, it adsorbs or desorbs moisture and warps. The resulting distortions or - at restrained conditions - cracks are a major concern in timber engineering. We herein present a multiscale model for prediction of the macroscopic hygroexpansion behavior of individual pieces of softwood from their microstructure, demonstrated for spruce. By applying poromicromechanics, we establish a link between the swelling pressure, driving the hygroexpansion of wood at the nanoscale, and the resulting macroscopic dimensional changes. The model comprises six homogenization steps, which are performed by means of continuum micromechanics, the unit cell method and laminate theory, all formulated in a poromechanical framework. Model predictions for elastic properties of wood as functions of the moisture content closely approach corresponding experimental data. As for the hygroexpansion behavior, the swelling pressure has to be back-calculated from macroscopic hygroexpansion data. The good reproduction of the anisotropy of wood hygroexpansion, based on only a single scalar calibration parameter, underlines the suitability of the model. The multiscale model constitutes a valuable tool for studying the effect of microstructural features on the macroscopic behavior and for assessing the hygroexpansion behavior at smaller length scales, which are inaccessible to experiments. The model predictions deliver input parameters for the analysis of timber at the structural scale, therewith enabling to optimize the use of timber and to prevent moisture-induced damage or failure.

• Structural Engineering and Mechanics
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• v.30 no.6
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• pp.713-732
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• 2008

Serviceability and durability of the concrete members can be seriously affected by the corrosion of steel rebar. Carbonation front and or chloride ingress can destroy the passive film on rebar and may set the corrosion (oxidation process). Depending on the level of oxidation (expansive corrosion products/rust) damage to the cover concrete takes place in the form of expansion, cracking and spalling or delamination. This makes the concrete unable to develop forces through bond and also become unprotected against further degradation from corrosion; and thus marks the end of service life for corrosion-affected structures. This paper presents an analytical model that predicts the weight loss of steel rebar and the corresponding time from onset of corrosion for the known corrosion rate and thus can be used for the determination of time to cover cracking in corrosion affected RC member. This model uses fully the thick-walled cylinder approach. The gradual crack propagation in radial directions (from inside) is considered when the circumferential tensile stresses at the inner surface of intact concrete have reached the tensile strength of concrete. The analysis is done separately with and without considering the stiffness of reinforcing steel and rust combine along with the assumption of zero residual strength of cracked concrete. The model accounts for the time required for corrosion products to fill a porous zone before they start inducing expansive pressure on the concrete surrounding the steel rebar. The capability of the model to produce the experimental trends is demonstrated by comparing the model's predictions with the results of experimental data published in the literature. The effect of considering the corroded reinforcing steel bar stiffness is demonstrated. A sensitivity analysis has also been carried out to show the influence of the various parameters. It has been found that material properties and their inter-relations significantly influence weight loss of rebar. Time to cover cracking from onset of corrosion for the same weight loss is influenced by corrosion rate and state of oxidation of corrosion product formed. Time to cover cracking from onset of corrosion is useful in making certain decisions pertaining to inspection, repair, rehabilitation, replacement and demolition of RC member/structure in corrosive environment.