• Journal of the Korea Concrete Institute
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• v.23 no.1
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• pp.109-120
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• 2011

This paper presents an experimental study results on the crack control of flexure-dominant reinforced concrete beams repaired with strain-hardening cement composite (SHCC). Five RC beams were fabricated and tested until failure. One unrepaired RC beam was a control specimen (CBN) and remaining four speciemens were repaired with SHCC materials. The test parameters included two types of SHCC matrix ductility and two types of repair method (patching and layering). Test results demonstrated that RC beams repaired with SHCC showed no concrete crushing or spalling until final failure, but numerous hair cracks were observed. The control specimen CBN failed due to crushing. It is important to note that SHCC matrix can improve crack-damage mitigation and flexural behavior of RC beams such as flexural strength, post peak ductility, and energy dissipation capacity. In the perspective of crack width, crack widths in RC beams repaired with SHCC had far smaller crack width than the control specimen CBN under the same deflection. Especially, the specimens repaired with SHCC of PVA0.75%+PE0.75% showed a high durability and ductility. The crack width indicates the residual capacity of the beam since SHCC matrix can delay residual capacity degradation of the RC beams.

• Journal of the Korean GEO-environmental Society
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• v.16 no.5
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• pp.55-66
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• 2015

Big tidal differences, which range from 3.0 m to 8.0 m, exist with regional locations at south and west shores of Korea. Under this ocean circumstance, since a large scour may occur due to multi-directional tidal current and transverse stress of the wind, the scour surrounding the wind turbine structure can make instability of the system due to unexpected system vibration. The hydraulic resistance capacity of soils consolidated under different pressures are evaluated by Erosion Function Apparatus (EFA) under unidirectional and bi-directional flows in this study. It was found that the flow direction change affects significantly on the sour rate and critical shear stress, regardless of soil types while the consolidation pressure affects mainly cohesive soil. Among geotechnical parameters, the undrained shear strength can be well-correlated with the hydraulic resistance capacity, regardless soil type while the shear wave velocity shows the proportional relationships with the hydraulic resistance capacities of fine grained soil and coarse grained soil, respectively.

• Journal of the Korean GEO-environmental Society
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• v.17 no.6
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• pp.23-31
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• 2016

Nowadays abnormal coldness happens frequently in Korea and frost heaving causes unexpected ground deformation which results in severe problems for structures such as roadway, railroad and cutoff slope. 'Frost heave' as one of the primary phenomenon is considered to be an important factor together with 'adfreeze bond-strength' and 'creep deformation' for structural design process in permafrost area. Therefore, the fundamental study for frost heave has to be preceded for design of geo-structures in cold region. While various experimental apparatuses have been developed, there still exist a certain level of limitation to evaluate the frost-heave characteristics as design parameters. There are no standard testing method and criteria for analyzing frost heaving in Korea because temperature controlled testing apparatuses including a freezing chamber are expensive. In this paper, a new standard freezing and thawing testing apparatus is introduced, which simulates various freezing and thawing conditions in a soil specimen by using a temperature controlled triaxial cell. Frost heaving tests were performed to assess the new testing apparatus and experimental procedure to evaluate frost heaving for soils is proposed.

• Journal of the Korean Chemical Society
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• v.54 no.5
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• pp.515-522
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• 2010

A relation between antimicrobial activities and the formation constants of solid complexes of Cu(II), Ni(II), Co(II), Mn(II) and Fe(III) with tridentate Schiff base ligand, 4-hydroxy-3(1-{2-(benzylideneamino)-phenylimino}-ethyl)-6-methyl-2Hpyran-2-one (HL) derived from o-phenylene diamines, dehydroacetic acid (DHA) and p-chloro benzaldehyde have been studied. The ligand and metal complexes were characterized by elemental analysis, conductivity, magnetic susceptibility, thermal analysis, X-ray diffraction, IR, $^1H$-NMR, UV-vis and mass spectra. From the analytical data, the stiochiometry of the complexes was found to be 1:2 (metal:ligand) with octahedral geometry. The molar conductance values suggest the nonelectrolytic nature of metal complexes. The X-ray diffraction data suggests monoclinic crystal system for Ni(II) and orthorhombic crystal system for Cu(II) and Co(II) complexes. The IR spectral data suggest that the ligand behaves as tridentate ligand with ONN donor atoms sequence towards central metal ion. Thermal behavior (TG/DTA) and kinetic parameters calculated by Coats-Redfern method suggests more ordered activated state in complex formation. The protonation constants of the complexes were determined potentiometrically in THF:water (60:40) medium at $25^{\circ}C$ and ionic strength ${\mu}=0.1\;M$ ($NaClO_4$). Antibacterial activities in vitro were performed against Staphylococcus aureu and Escherichia coli. Antifungal activities were studied against Aspergillus Niger and Trichoderma. The effect of the metal ions and stabilities of complexes on antimicrobial activities are discussed.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.27 no.6
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• pp.615-624
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• 2014

It has been well known the sloshing pressure has complex shape and various patterns. The pattern of sloshing pressure is variously characterized by the pressure amplitude, duration time and skewness. The structural response induced by the sloshing pressure is also affected by the pattern of sloshing pressure and the type of structural members. In order to understand the structural response by the perspective view of categorized pattern, it is more efficient to make simple sloshing pressure pattern than to reflect the complex pressure history. In this study, the sloshing pressures obtained by the small scale model test are simplified with respect to their duration and skewness. Dynamic analyses of Mark-III LNG CCS are then parametrically performed with the consideration of various types of sloshing impact. Meanwhile, the failure pressures given the duration and skewness are investigated after parametric calculations are conducted to investigate the effect of pressure parameters on the structural response.

• Journal of the Korean Chemical Society
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• v.18 no.4
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• pp.223-238
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• 1974

CNDO/2 MO theoretical studies and kinetic studies of halide exchange reactions for alkylchloroformates have been carried out in order to investigate structure-reactivity relationship of alkylchloroformates. From the result of energetics, it was concluded that the most stable configuration of alkylchloroformate is that in which alkyl group and chlorine are trans to each other, and that the hindered rotation about the bond between the carbonyl carbon and alkoxy-oxygen bond is attributed to the ${\pi}-$electron delocalization. It has been found that the large charge separation is due to -M effect of carbonyl and alkoxy oxygens and-I effect of chlorine. The order of rates in solvents studied was $(CH_3)_2 > CO > CH_3CN{\gg}MeOH.$$I^->Br^->Cl^-$ in protic solvent, and of Cl^->Br^- >I^-$ in dipolar aprotic solvents. Alkyl group contribution has the decreasing order of $CH_3-> C_2H-{\gg}i-C_3H_7-.$ The solvent effect has been interpreted on the basis of initial and final state contribution. A transition state model has been suggested, and it has been proposed that the most favorable mechanism is the addition-elimination. From the results of activation parameters and electronic properties, an energy profile has been proposed. Structural factors determining reactivities of alkylchloroformates have been shown to be charge, energy level of ${\alpha}^*LUMO$ to C-Cl bond and ${\alpha}^{\ast} $antibonding strength with respect to C-Cl bond in this MO. Charge and polarizability of nucleophile, and the interaction of these effects with solvent structures are also found to be important.

• Food Science and Preservation
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• v.14 no.3
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• pp.239-246
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• 2007

The effects of gamma irradiation on the physiochemical and physical characteristics of apples were investigated during post-irradiation storage at $4^{\circ}C\;and\;25^{\circ}C$. The contents of total and reducing sugars were analyzed and the results indicated that apples receiving 1 kGy of gamma irradiation did not show significant differences in sugar contents compared to non-irradiated controls. Important physiological characteristics were evaluated by measurement of total phenolic content and total flavonoid content, reducing power, and radical scavenging ability, and the results indicated that gamma irradiation at a dose of 1 kGy did not affect physiological activities. Changes in physical parameters such as weight loss, strength, cohesiveness and hardness, during post-irradiation storage, were temperature-dependent, whether the apples were irradiated or not The color and sensory acceptance of the apples were not affected by irradiation during cold storage. However, minor deterioration in color quality and sensory acceptance of irradiated apples was noted under ambient temperature storage. We conclude that gamma irradiation(1 kGy) does not affect apple nutritional content stability, functional properties, or physical characteristics, especially upon cold storage after radiation treatment.

• Journal of the Korean Geotechnical Society
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• v.33 no.7
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• pp.5-16
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• 2017

Soil nailing is the most general method to reinforce the slope by taking pullout and shear resistance force of the nail for stabilizing the slope. Domestic soil nailing design method considers only pullout resistance and does not consider the shear resistance sufficiently. In case of nail, the effect of tensile stress is dominant, but it is desirable to design by considering shear stress as well as tensile stress in case of slope where circle failures occur. Recently, studies on the shear resistance effect of nails have been carried out in the geotechnical field. However, many researches on the shear reinforcement effect of soil nailing have not been conducted until now. Most of the studies are about increasing pullout resistance by improving material, shape and construction method of nail. Therefore, it is necessary to the study on shear resistance of soil nailing and development of new methods to increase the shear force. In this study, large shear test and limit equilibrium analysis have been performed for a new soil nailing method to increase the shear resistance by forming protrusions through pressurized grouting after installing a packer on the outside of deformed bar. The study results showed that shear resistance of protrusion type soil nailing increased compared to soil nailing and it is more effective when applied to the ground with large strength parameters.

• Journal of the Korean Society of Hazard Mitigation
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• v.8 no.1
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• pp.1-7
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• 2008

When historical or cultural buildings need to be repaired or reinforced, the changes of original features should be minimized, and the strengths of structures should be improved. Among the existing methods to reinforce historical wood structures, the carbon fiber reinforcement polymer (CFRP) installation method is one of the best ones to achieve the afore-mentioned requirements. Therefore, this study aims at investigating the reinforcing effects and failure modes of timber beams reinforced with the inserted CFRP, a part of roof trusses in modern wood structures, and at providing the fundamental test data to estimate the CFRP rein-forced timber beam in the application of this reinforcing method. The primary parameters in this study were the layout and amount of CFRP. It was observed that, when $0.3{\sim}0.7%$ of CFRP were installed, the strengths of reinforced timber beams increased up to 173% compared to its original strength, but their strengthening effects were heavily influenced by the characteristics of timber such as burls. In order to improve the applicability of this strengthening method, fundamental understandings on the characteristics of wood would be necessary, and there would be in need of researches on the non-destructive test for wood structures as well.

• Korean Journal of Agricultural and Forest Meteorology
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• v.11 no.4
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• pp.213-220
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• 2009

In order to predict the risk of freeze injury for 'Changhowon Hwangdo' peach trees, we used the dormancy depth (i.e., the daily chill unit accumulation during the overwintering period) as a proxy for the short-term, physiological tolerance to freezing temperatures. A Chill-days model was employed and its parameters such as base temperature and chilling requirement were optimized for peach trees based on the 12 observational experiments during the 2008-2009 winter. The model predicted the flowering dates much closer to the observations than other models without considering dormancy depth, showing the strength of employing dormancy depth into consideration. To derive empirical equations for calculating the probabilistic freeze risk, the dormancy depth was then combined with the browning ratio and the budburst ratio of frozen peach fruit branches. Given the exact date and the predicted minimum temperature, the equations calculate the probability of freeze damages such as a failure in budburst or tissue browning. This method of employing dormancy depth in addition to freezing temperature would be useful in locating in advance the risky areas of freezing injury for peach trees production under the projected climate change.