• Korean Journal of Metals and Materials
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• v.49 no.5
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• pp.411-418
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• 2011

The current study investigates the electroplating characteristics of Sn-Cu eutectic micro-bumps electroplated on a Si chip for flip chip application. Under bump metallization (UBM) layers consisting of Cr, Cu, Ni and Au sequentially from bottom to top with the aim of achieving Sn-Cu bumps $10\times10\times6$ ${\mu}m$ in size, with 20${\mu}m$ pitch. In order to determine optimal plating parameters, the polarization curve, current density and plating time were analyzed. Experimental results showed the equilibrium potential from the Sn-Cu polarization curve is -0.465 V, which is attained when Sn-Cu electro-deposition occurred. The thickness of the electroplated bumps increased with rising current density and plating time up to 20 mA/$cm^2$ and 30 min respectively. The near eutectic composition of the Sn-0.72wt%Cu bump was obtained by plating at 10 mA/$cm^2$ for 20 min, and the bump size at these conditions was $10\times10\times6$ ${\mu}m$. The shear strength of the eutectic Sn-Cu bump was 9.0 gf when the shearing tip height was 50% of the bump height.

• Steel and Composite Structures
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• v.38 no.1
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• pp.103-120
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• 2021

This research examines the eccentric compression performance of composite columns composed of recycled aggregate concrete (RAC)-filled square steel tube and profile steel. A total of 17 specimens on the composite columns with different recycled coarse aggregate (RCA) replacement percentage, RAC strength, width to thickness ratio of square steel tube, profile steel ratio, eccentricity and slenderness ratio were subjected to eccentric compression tests. The failure process and characteristic of specimens under eccentric compression loading were observed in detail. The load-lateral deflection curves, load-train curves and strain distribution on the cross section of the composite columns were also obtained and described on the basis of test data. Results corroborate that the failure characteristics and modes of the specimens with different design parameters were basically similar under eccentric compression loads. The compression side of square steel tube yields first, followed by the compression side of profile steel. Finally, the RAC in the columns was crushed and the apparent local bulging of square steel tube was also observed, which meant that the composite column was damaged and failed. The composite columns under eccentric compression loading suffered from typical bending failure. Moreover, the eccentric bearing capacity and deformation of the specimens decreased as the RCA replacement percentage and width to thickness ratio of square steel tube increased, respectively. Slenderness ratio and eccentricity had a significantly adverse effect on the eccentric compression performance of composite columns. But overall, the composite columns generally had high-bearing capacity and good deformation. Meanwhile, the mechanism of the composite columns under eccentric compression loads was also analysed in detail, and the calculation formulas on the eccentric compression capacity of composite columns were proposed via the limit equilibrium analysis method. The calculation results of the eccentric compression capacity of columns are consistent with the test results, which verify the validity of the formulas, and the conclusions can serve as references for the engineering application of this kind of composite columns.

• Composites Research
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• v.35 no.3
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• pp.153-160
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• 2022

Cellulose nanofibrils (CNF) based on wood pulp fibers are gained much attention as part of biocompatible hydrogels for biomedical applications such as tissue engineering scaffolds, biomedicine, and drug carrier. However, CNF hydrogels have relatively poor mechanical properties, impeding their applications requiring high mechanical integrity. In this work, we prepare 2,2,6,6-tetramethylipiperidin-oxyl (TEMPO) oxidated cellulose nanofibrils hydrogels mediated with metal cations, which form the metal-carboxylate coordination bonds for enhanced mechanical strength and toughness. We conduct the large amplitude oscillatory shear (LAOS) test and Live/dead cell assay for obtaining nonlinear viscoelastic parameters and cell viability, respectively. In particular, the cell proliferation and viability change depending on the type of metal salt, which also affected the rheological properties of the hydrogels.

• Nuclear Engineering and Technology
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• v.54 no.10
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• pp.3745-3765
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• 2022

The concrete structures related to nuclear safety are threatened by accidental impact loadings, mainly including the low-velocity drop-weight impact (e.g., spent fuel cask and assembly, etc. with the velocity less than 20 m/s) and high-speed projectile impact (e.g., steel pipe, valve, turbine bucket, etc. with the velocity higher than 20 m/s), while the existing studies are still limited in the impact resistant design of nuclear power plant (NPP), especially the primary RC slab. This paper aims to propose the numerical simulation and theoretical approaches to assist the impact-resistant design of RC slab in NPP. Firstly, the continuous surface cap (CSC) model parameters for concrete with the compressive strength of 20-70 MPa are fully calibrated and verified, and the refined numerical simulation approach is proposed. Secondly, the two-degree freedom (TDOF) model with considering the mutual effect of flexural and shear resistance of RC slab are developed. Furthermore, based on the low-velocity drop hammer tests and high-speed soft/hard projectile impact tests on RC slabs, the adopted numerical simulation and TDOF model approaches are fully validated by the flexural and punching shear damage, deflection, and impact force time-histories of RC slabs. Finally, as for the two low-velocity impact scenarios, the design procedure of RC slab based on TDOF model is validated and recommended. Meanwhile, as for the four actual high-speed impact scenarios, the impact-resistant design specification in Chinese code NB/T 20012-2019 is evaluated, the over conservation of which is found, and the proposed numerical approach is recommended. The present work could beneficially guide the impact-resistant design and safety assessment of NPPs against the accidental impact loadings.

• Advances in concrete construction
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• v.13 no.1
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• pp.71-81
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• 2022

Aluminosilicate materials as precursors are heterogenous in nature, consisting of inert and partially reactive portion, and have varying proportions depending upon source materials. It is essential to assess the reactivity of precursor prior to synthesize geopolymers. Moreover, reactivity may act as decisive factor for setting molar concentration of NaOH, curing temperature and setting proportion of different precursors. In this experimental work, the reactivities of two precursors, low calcium (fly ash (FA)) and high calcium (ground granulated blast furnace slag (GGBS)), were assessed through the dissolution of aluminosilicate at (i) three molar concentrations (8, 12, and 16 M) of NaOH solution, (ii) 6 to 24 h dissolution time, and (iii) 20-100℃. Based on paratermeters influencing the reactivity, different proportions of ternary binders (two precursors and ordinary cement) were activated by the combined NaOH and Na2SiO3 solutions with two alkaline activators to precursor ratios, to synthesize the geopolymer. Reactivity results revealed that GGBS was 20-30% more reactive than FA at 20℃, at all three molar concentrations, but its reactivity decreased by 32-46% with increasing temperature due to the high calcium content. Setting time of geopolymer paste was reduced by adding GGBS due to its fast reactivity. Both GGBS and cement promoted the formation of all types of gels (i.e., C-S-H, C-A-S-H, and N-A-S-H). As a result, it was found that a specified mixing proportion could be used to improve the compressive strength over 30 MPa at both the ambient and hot curing conditions.

• Geomechanics and Engineering
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• v.25 no.3
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• pp.233-243
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• 2021

Rib spalling is a major issue affecting the safety of steeply inclined coal seam. And the failure coal face and support system can be affected with each other to generate a vicious cycle along with inducing large-scale collapse of surrounding rock in steeply inclined coal seam. In order to analyze failure mechanism and propose the corresponding prominent control measures of steeply inclined coal working face, mechanical model based on coal face-support-roof system and mechanical model of coal face failure was established to reveal the disaster mechanism of rib spalling and the sensitive analysis of related factors was performed. Furthermore, taking 3402 working face of Chen-man-zhuang coal mine as engineering background, numerical model by using FLAC3D was built to illustrate the propagation of displacement and stress fields in steeply inclined coal seam and verify the theory analysis as mentioned in this study. The results show that the coal face slide body in steeply inclined working face can be observed as the failure height of upper layer smaller than that of lower layer exhibiting with an irregular quadrilateral pyramid shape. Moreover, the cracks were originated from the upper layer of sliding body and gradually developed to the lower layer causing the final rib spalling. The influence factors on the stability of coal face can be ranked as overlying strata pressure (P) > mechanical parameters of coal body (e.g., cohesion (c), internal fraction angle (φ)) > support strength (F) > the support force of protecting piece (F') > the false angle of working face (Θ). Moreover, the corresponding control measures to maintain the stability of the coal face in the steeply inclined working face were proposed.

• Structural Engineering and Mechanics
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• v.80 no.6
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• pp.645-655
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• 2021

Performance-based reliability analysis is a practical approach to investigate the seismic performance and stochastic nonlinear response of structures considering a random process. This is significant due to the uncertainties involved in every aspect of the analysis. Therefore, the present study aims to evaluate the performance-based reliability within a stochastic finite element (FE) framework for reinforced concrete (RC) shear walls that are considered as one of the most essential elements of structures. To accomplish this purpose, deterministic FE analyses are conducted for both squat and slender shear walls to validate numerical models through experimental results. The presented numerical analysis is performed by using the ABAQUS FE program. Afterwards, a random-effects investigation is carried out to consider the influence of different random variables on the lateral load-top displacement behavior of RC members. Using these results and through utilizing the Monte-Carlo simulation method, stochastic nonlinear analyses are also performed to generate random FE models based on input parameters and their probabilistic distributions. In order to evaluate the reliability of RC walls, failure probabilities and corresponding reliability indices are calculated at life safety and collapse prevention levels of performance as suggested by FEMA 356. Moreover, based on reliability indices, capacity reduction factors are determined subjected to shear for all specimens that are designed according to the ACI 318 Building Code. Obtained results show that the lateral load and the compressive strength of concrete have the highest effects on load-displacement responses compared to those of other random variables. It is also found that the probability of shear failure for the squat wall is slightly lower than that for slender walls. This implies that 𝛽 values are higher in a non-ductile mode of failure. Besides, the reliability of both squat and slender shear walls does not change significantly in the case of varying capacity reduction factors.

• Geomechanics and Engineering
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• v.27 no.5
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• pp.527-535
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• 2021

The creep characteristics of rock is of great significance for the study of long-term stability of engineering, so it is necessary to carry out indoor creep test and creep model of rock. First of all, in different water-bearing state and different positive pressure conditions, the granite is graded loaded to conduct indoor shear creep test. Through the test, the shear creep characteristics of granite are obtained. According to the test results, the stress-strain isochronous curve is obtained, and then the long-term strength of granite under different conditions is determined. Then, the fractional-order calculus software element is introduced, and it is connected in series with the spring element and the nonlinear viscoplastic body considering the creep acceleration start time to form a nonlinear viscoplastic creep model with fewer elements and fewer parameters. Finally, based on the shear creep test data of granite, using the nonlinear curve fitting of Origin software and Levenberg-Marquardt optimization algorithm, the parameter fitting and comparative analysis of the nonlinear creep model are carried out. The results show that the test data and the model curve have a high degree of fitting, which further explains the rationality and applicability of the established nonlinear visco-elastoplastic creep model. The research in this paper can provide certain reference significance and reference value for the study of nonlinear creep model of rock in the future.

• Earthquakes and Structures
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• v.22 no.2
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• pp.121-135
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• 2022

Many public buildings such as schools, hospitals, etc., where partial infill walls are present in reinforced concrete (RC) structures, have undergone undesirable damage/failure attributed to captive column effect during a moderate to severe earthquake shaking. Often, the situation gets worsened when these RC frames are non-ductile in nature, thus reducing the deformable capability of the frame. Also, in many parts of the Indian subcontinent, it is mandatory to use fly-ash bricks for construction so as to reduce the burden on the disposal of fly-ash produced at thermal power plants. In some scenario, when the non-ductile RC frame, partially infilled by fly-ash bricks, suffers major structural damage, the challenge remains on how to retrofit and restore it. Thus, in this study, two full-scale one-bay, one-story non-ductile RC frame models, namely, bare frame and RC partially infilled frame with fly-ash bricks in 50% of its opening area are considered. In the previous experiments, these models were subjected to slow-cyclic displacement-controlled loading to replicate damage due to a moderate earthquake. Now, in this study these damaged frames were retrofitted and an experimental investigation was performed on the retrofitted specimens to examine the effectiveness of the proposed retrofitting scheme. A hybrid retrofitting technique combining epoxy injection grouting with an innovative and easy-to-implement steel jacketing technique was proposed. This proposed retrofitting method has ensured proper confinement of damaged concrete. The retrofitted models were subjected to the same slow cyclic displacement-controlled loading which was used to damage the frames. The experimental study concluded that the hybrid retrofitting technique was quite effective in enhancing and regaining various seismic performance parameters such as, lateral strength and lateral stiffness of partially fly-ash brick infilled RC frame. Thus, the steel jacketing retrofitting scheme along with the epoxy injection grouting can be relied on for possible repair of the structural members which are damaged due to the captive column effect during the seismic shaking.

• International Journal of Industrial Entomology and Biomaterials
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• v.45 no.2
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• pp.56-69
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• 2022

Silk is a unique natural biopolymer with outstanding biocompatibility, high mechanical strength, and superior optical transparency. Due to its excellent properties, silk has been widely reported as an ideal biomaterial for several biomedical applications. Recently, fluorescent silk protein, a variant of native silk, has been reported as a biophotonic material with the potential for bioimaging and biosensing. Despite the realization of fluorescent silk, the traditional degumming process of fluorescence silk is crude and often results in fluorescence loss. The loss of fluorescent properties is attributed to the sensitivity of silk fibroin to temperature and solvent concentration during degumming. However, there is no comprehensive information on the influence of these processing parameters on fluorescence evolution and decay during fluorescent silk processing. Therefore, we conducted a spectroscopic study on fluorescence decay as a function of temperature, concentration, and duration for fluorescent silk cocoon degumming. Sodium carbonate solution was tested for degumming the fluorescent silk cocoons with different concentrations and temperatures; also, sodium carbonate solution is combined with Alcalase enzyme and triton x-100 to find optimal degumming conditions. Additionally, we conducted a molecular dynamics study to investigate the fundamental effect of temperature on the stability of the fluorescent protein. We observed degumming temperature as the prime source of fluorescent intensity reduction. From the MD study, fluorescence degradation originated from the thermal agitation of fluorescent protein Cα atoms and fluctuations of amino acid residues located in the chromophore region. Overall, degumming fluorescent silk with sodium carbonate and Alcalase enzyme solution at 25 ℃ preserved fluorescence.