• Title/Summary/Keyword: storage function model

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A Numerical Investigation of Hydrogen Absorption Reaction Based on ZrCo for Tritium Storage (I) (삼중수소 저장을 위한 ZrCo 저장재에서의 수소 흡장에 대한 수치해석적 연구 (I))

  • Yoo, Haneul;Yun, Seihun;Chang, Minho;Kang, Hyungoo;Ju, Hyunchul
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.448-454
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    • 2012
  • In this paper, a three-dimensional hydrogen absorption model is applied to a thin double-layered annulus ZrCo hydride bed and validated against the temperature evolution data measured by Kang et al. The present model reasonably captures the bed temperature evolution behavior and the 99% hydrogen charging time. The equilibrium pressure expression for hydrogen absorption on ZrCo is derived as a function of temperature and the H/M atomic ratio based on the pressure-composition isotherm data given by Konishi et al. In addition, this present model provides multi-dimensional contours such as temperature and H/M atomic ratio in the thin doublelayered annulus metal hydride region. This numerical study provides fundamental understanding during hydrogen absorption process and indicates that efficient design of the metal hydride bed is critical to achieve rapid hydrogen charging performance. The present three-dimensional hydrogen absorption model is a useful tool for the optimization of bed design and operating conditions.

Numerical Study of Hydrogen Desorption in a Metal Hydride Hydrogen Storage Vessel (금속수소화물 수소 저장 용기 내부의 수소방출에 대한 수치해석적 연구)

  • Kang, Kyung-Mun;Nam, Jin-Moo;Yoo, Ha-Neul;Ju, Hyun-Chul
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.3
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    • pp.363-371
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    • 2011
  • In this paper, a three-dimensional hydrogen desorption model is developed to precisely study the hydrogen desorption kinetics and resultant heat and mass transport phenomena in metal hydride hydrogen storage vessels. The metal hydride hydrogen desorption model, i.e. governed by the conservation of mass, momentum, and thermal energy is first experimentally validated against the temperature evolution data measured on a cylindrical $LaNi_5$ metal hydride vessel. The equilibrium pressure used for hydrogen desorption simulations is derived as a function of H/M atomic ratio and temperature based on the experimental data in the literature. The numerical simulation results agree well with experimental data and the 3D desorption model successfully captures key experimental trends during hydrogen desorption process. Both the simulation and experiment display an initial sharp decrease in the temperature mainly caused by relatively slow heat supply rate from the vessel external wall. On the other hand, the effect of heat supply becomes influential at the latter stages, leading to smooth increase in the vessel temperature in both simulation and experiment. This numerical study provides the fundamental understanding of detailed heat and mass transfer phenomena during hydrogen desorption process and further indicates that efficient design of storage vessel and heating system is critical to achieve fast hydrogen discharging performance.

Development of Combustion Model for Engine Control Algorithm Design (엔진제어 알고리즘 설계를 위한 연소모델 개발)

  • Park, Young-Kug
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.3
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    • pp.26-36
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    • 2010
  • This paper provides a description of the combustion model to obtain an accurate dynamic engine phenomena that satisfies real-time simulation for model-based engine control. The combustion chamber is modeled as a storage device for mass and energy. The combustion process is modeled in terms of a two-zone model for the burned and unburned gas fractions. The mass fraction burnt is modeled in terms of a Wiebe function. The instantaneous net engine torque is calculated from the engine speed and the instantaneous piston work. The modeling accuracy has been tested with a cylinder pressure data on a test bench and also the ability of real-time simulation has been checked. The results show that combustion model yields sufficiently good performance for the model-based control logic design. However the influence factors effected on model accuracy are some room for improvement.

Development of a Predictive Model Describing the Growth of Staphylococcus aureus in Ready-to-Eat Sandwiches (즉석섭취 샌드위치에서의 Staphylococcus aureus 성장예측모델 개발)

  • Park, Hae-Jung;Bae, Hyun-Joo
    • Journal of the FoodService Safety
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    • v.2 no.2
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    • pp.91-96
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    • 2021
  • This study was performed to provide fundamental data on hygiene and quality control of ready-to-eat sandwiches. Predictive models were developed to the kinetics of Staphylococcus aureus growth in these sandwiches as a function of temperature (10, 15, 25, and 35℃). The result of the primary model that used the Gompertz equation showed that the lag phase duration (LPD) and generation time (GT) decreased and the exponential growth rate (EGR) increased with increasing storage temperature. The secondary model showed an R2 for M and B of 0.9967 and 09916, respectively. A predictive growth model of the growth degree as a function of temperature was developed. L(t)=A+Cexp(-exp(-B(t-M))) (A=Initial contamination level, C=MPD-A, B=0.473166-0.045040*Temp-0.001718*Temp*Temp, M=19.924824-0.627442*Temp-0.004493*Temp*Temp, t=time, Temp=temperature). This model showed an R2 value of 0.9288. All the models developed in this study showed a good fit.

Analysis of the Different Heated Milks using Electronic Nose (열처리를 달리한 시유의 전자코 분석)

  • Hong, Eun-Jeung;Noh, Bong-Soo;Park, Seung-Yong
    • Food Science of Animal Resources
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    • v.30 no.5
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    • pp.851-859
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    • 2010
  • This study was conducted to investigate the application of a model system using an MS-electronic nose based on the discriminative function analysis on volatile flavors, to prediction of the shelf-life of market milk by preservation temperature and differently-loaded heat treatment. On mass spectrum, the ion fragments of volatile flavors of milk obtained from MS-electronic nose could be distinguished at amu 60, 91, 92, and 93. The response levels of volatile flavors at each amu increased in proportion to the heat treatment loaded to the milk, in the order of LTLT, HTST, and UHT. This study indicated that the discriminative function scores of the volatile flavors seemed to correlate with the preservation temperature, storage period, and heat treatment conditions; DF1 (discriminative function first score) showed a strong relationship to storage periods, with $r^2$ of 0.9965, 0.9965, and 0.9911 at temperatures of 4, 7, and $10^{\circ}C$, respectively, while DF2 was influenced by heat treatment conditions with an $r^2$ of 0.9861 at $4^{\circ}C$. It is suggested that the discriminative function analysis given by an MS-electronic nose could be used to construct a new quality control model system for the evaluation of heat treatment loaded during the processing of milk, and for predicting storage periods of market milk.

TFN model application for hourly flood prediction of small river (소규모 하천의 시간단위 홍수예측을 위한 TFN 모형 적용성 검토)

  • Sung, Ji Youn;Heo, Jun-Haeng
    • Journal of Korea Water Resources Association
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    • v.51 no.2
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    • pp.165-174
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    • 2018
  • The model using time series data can be considered as a flood forecasting model of a small river due to its efficiency for model development and the advantage of rapid simulation for securing predicted time when reliable data are obtained. Transfer Function Noise (TFN) model has been applied hourly flood forecast in Italy, and UK since 1970s, while it has mainly been used for long-term simulations in daily or monthly basis in Korea. Recently, accumulating hydrological data with good quality have made it possible to simulate hourly flood prediction. The purpose of this study is to assess the TFN model applicability that can reflect exogenous variables by combining dynamic system and error term to reduce prediction error for tributary rivers. TFN model with hourly data had better results than result from Storage Function Model (SFM), according to the flood events. And it is expected to expand to similar sized streams in the future.

A Study on Development of Long-Term Runoff Model for Water Resources Planning and Management (수자원의 이용계획을 위한 장기유출모형의 개발에 관한 연구)

  • Cho, Hyeon-Kyeong
    • Journal of the Korean Society of Industry Convergence
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    • v.16 no.3
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    • pp.61-68
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    • 2013
  • Long-term runoff model can be used to establish the effective plan of water reources allocation and the determination of the storage capacity of reservoir. So this study aims at the development of monthly runoff model using artificial neural network technique. For this, it was selected multi-layer neural network(MLN) and radial basis function neural network(RFN) model. In this study, it was applied model to analysis monthly runoff process at the Wi stream basin in Nakdong river which is representative experimental river basin of IHP. For this, multi-layer neural network model tried to construct input 3, hidden 7, and output 1 for each number of layer. As the result of analysis of monthly runoff process using models connected with artificial neural network technique, it showed that these models were effective in the simulation of monthly runoff.

Parameters Estimation of Clark Model based on Width Function (폭 함수를 기반으로 한 Clark 모형의 매개변수 추정)

  • Park, Sang Hyun;Kim, Joo-Cheol;Jung, Kwansue
    • Journal of Korea Water Resources Association
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    • v.46 no.6
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    • pp.597-611
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    • 2013
  • This paper presents the methodology for construction of time-area curve via the width function and thereby rational estimation of time of concentration and storage coefficient of Clark model within the framework of method of moments. To this end time-area curve is built by rescaling the grid-based width function under the assumption of pure translation and then the analytical expressions for two parameters of Clark model are proposed in terms of method of moments. The methodology in this study based on the analytical expressions mentioned before is compared with both (1) the traditional optimization method of Clark model provided by HEC-1 in which the symmetric time-area curve is used and the difference between observed and simulated hydrographs is minimized (2) and the same optimization method but replacing time-area curve with rescaled width function in respect of peak discharge and time to peak of simulated direct runoff hydrographs and their efficiency coefficient relative to the observed ones. The following points are worth of emphasizing: (1) The optimization method by HEC-1 with rescaled width function among others results in the parameters well reflecting the observed runoff hydrograph with respect to peak discharge coordinates and coefficient of efficiency; (2) For the better application of Clark model it is recommended to use the time-area curve capable of accounting for irregular drainage structure of a river basin such as rescaled width function instead of symmetric time-area curve by HEC-1; (3) Moment-based methodology with rescaled width function developed in this study also gives rise to satisfactory simulation results in terms of peak discharge coordinates and coefficient of efficiency. Especially the mean velocities estimated from this method, characterizing the translation effect of time-area curve, are well consistent with the field surveying results for the points of interest in this study; (4) It is confirmed that the moment-based methodology could be an effective tool for quantitative assessment of translation and storage effects of natural river basin; (5) The runoff hydrographs simulated by the moment-based methodology tend to be more right skewed relative to the observed ones and have lower peaks. It is inferred that this is due to consideration of only one mean velocity in the parameter estimation. Further research is required to combine the hydrodynamic heterogeneity between hillslope and channel network into the construction of time-area curve.

Optimal Forest Management for Improving Economic and Public Functions in Mt.Gari Leading Forest Management Zone (가리산 선도산림경영단지의 경제적·공익적 기능 증진을 위한 산림관리 최적화 방안)

  • Kim, Dayoung;Han, Hee;Chung, Joosang
    • Journal of Korean Society of Forest Science
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    • v.110 no.4
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    • pp.665-677
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    • 2021
  • This study analyzed the optimization method of forest management to enhance economic and public functions, as well as the interrelationship among timber production, carbon storage, and water conservation functions in Mt.Gari leading forest management zone. For these purposes, a forest management planning model was developed using Multi-Objective Linear Programming. The model had an objective function to maximize the total NPV (Net Present Value) of weighted timber production, carbon storage, water conservation, and constraints to limit the rate of change in timber production, percentage of each age-class and tree species area, percentage of conifers and broad-leaved trees area in each management zone, minimum timber production and timber sales amount. Based on the description of forest inventory and the comprehensive plan of Mt.Gari, we analyzed stand information and management constraints of the study area. We compared management alternatives using different weights in the objective function. Therefore, the total NPV was maximized in the alternative considering the three functions in equal proportion, rather than the alternatives of maximizing only one function. When all three functions were considered simultaneously, timber production offset the carbon storage and water conservation, and carbon storage and water conservation interacted synergistically. However, when considering only two of the three functions, all combinations of functions demonstrated tradeoffs with one other. Therefore, we discovered that by considering all three functions equally, rather than only one or two functions, the economic and public values of the study area can be maximized.

Re-Analysis of Clark Model Based on Drainage Structure of Basin (배수구조를 기반으로 한 Clark 모형의 재해석)

  • Park, Sang Hyun;Kim, Joo Cheol;Jeong, Dong Kug;Jung, Kwan Sue
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.6
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    • pp.2255-2265
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    • 2013
  • This study presents the width function-based Clark model. To this end, rescaled width function with distinction between hillslope and channel velocity is used as time-area curve and then it is routed through linear storage within the framework of not finite difference scheme used in original Clark model but analytical expression of linear storage routing. There are three parameters focused in this study: storage coefficient, hillslope velocity and channel velocity. SCE-UA, one of the popular global optimization methods, is applied to estimate them. The shapes of resulting IUHs from this study are evaluated in terms of the three statistical moments of hydrologic response functions: mean, variance and the third moment about the center of IUH. The correlation coefficients to the three statistical moments simulated in this study against these of observed hydrographs were estimated at 0.995 for the mean, 0.993 for the variance and 0.983 for the third moment about the center of IUH. The shape of resulting IUHs from this study give rise to satisfactory simulation results in terms of the mean and variance. But the third moment about the center of IUH tend to be overestimated. Clark model proposed in this study is superior to the one only taking into account mean and variance of IUH with respect to skewness, peak discharge and peak time of runoff hydrograph. From this result it is confirmed that the method suggested in this study is useful tool to reflect the heterogeneity of drainage path and hydrodynamic parameters. The variation of statistical moments of IUH are mainly influenced by storage coefficient and in turn the effect of channel velocity is greater than the one of hillslope velocity. Therefore storage coefficient and channel velocity are the crucial factors in shaping the form of IUH and should be considered carefully to apply Clark model proposed in this study.