• Bulletin of the Korean Chemical Society
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• 제22권9호
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• pp.1015-1018
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• 2001

Vanadium oxide thin films with thickness of about 2000 $\AA$ have been prepared by radio frequency sputter deposition using a V2O5 target in a mixed argon and oxygen atmosphere with different Ar/O2 ratio ranging from 99/1 to 90/10. X-ray diffraction and X-ray absorption near edge structure spectroscopic studies show that the oxygen content higher than 5% crystallizes a stoichiometric V2O5 phase, while oxygen deficient phase is formed in the lower oxygen content. The oxygen content in the mixed Ar + O2 has a significant influence on electrochemical lithium insertion/deinsertion property. The discharge-charge capacity of vanadium oxide film increases with increasing the reactive oxygen content. The V2O5 film deposited at the Ar/O2 ratio of 90/10 exhibits high discharge capacity of 100 ${\mu}Ah/cm2-{\mu}m$ along with good cycle performance.

• 대한기계학회논문집B
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• 제27권7호
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• pp.893-900
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• 2003

Numerical simulations of freely propagating flames burning stoichiometric C $H_4$/CHC1$_3$/ $O_2$/$N_2$ mixtures are performed at atmospheric pressure in order to understand the effect of the $O_2$ enrichment level and the CHC1$_3$/C $H_4$ molar ratio. A chemical kinetic mechanism is developed, which involves 69 gas-phase species and 379 forward and 364 backward reactions. The calculated flame speeds are compared with the experiments for the flames established at several CHC1$_3$/C $H_4$ molar ratio (R<1), the results of which is in excellent agreement. As a results of the increased $O_2$ enrichment level from 0.21 to 1, the flame speed and the temperature in the burned gas are increased. At high CHC1$_3$/C $H_4$ molar ratio two peak values appear on the $O_2$ consumption rate, which are affected by CC1$_2$＋ $O_2$$_{-}$>C1O+CC1O and H＋ $O_2$$_{-}$>O＋OH.＋OH.

• 대한환경공학회지
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• 제32권6호
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• pp.587-592
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• 2010

연소과정 중에 발생하는 질소산화물을 저감하는 기술인 MILD 연소에 대하여 공연비를 변화시키면서 나타나는 연소 특성을 수치해석을 통하여 연구하였다. 작은 크기의 공기분출속도(10 m/s)에서는 공기가 연소로 내 상부영역까지 침투하지 못한다. 반면에 공기분출속도가 30 m/s인 경우에는 공기유동이 연료유동을 억제하고 상부영역까지 흘러간다. 이론공기량에 해당하는 공기분출속도 18 m/s에서는 10 m/s 보다 상대적으로 상부영역까지 침투하였다. 이러한 유동 양상으로 공기분출속도가 작은 10 m/s에서는 연소반응대가 공기노즐 측에 치우쳐 나타나고 30 m/s에서는 연료노즐 측에 형성되었다. 공기분출속도 16, 18, 20 m/s에서는 공기노즐과 연료노즐 중간 영역에서 연소반응대가 형성되었다. 연소로 내 최대온도와 NOx 생성은 공기분출속도가 10 m/s, 30 m/s인 경우 보다 이론공기량이거나 이에 가까운 16, 18, 20 m/s에서 낮게 나타났다. 본 연구로부터 MILD 연소로에서 이론공기량 조건이 NOx를 저감하는 최적의 조건이라는 것을 밝혔다.

• 한국가시화정보학회지
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• 제14권3호
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• pp.51-58
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• 2016

New concept spark plug was developed to study its influence on the combustion characteristics of SI engine. It has pre-ignition chamber at the lower end of spark plug and flame hole, in which fresh mixture gas can be put in through the flame hole without any fuel supply system. This spark plug was tested in a single cylinder engine dynamometer for different air fuel ratio to measure the fuel consumption rate, emission gases, and MBT timing. And constant volume combustion chamber was made to understand flame characteristics of spark plug. New spark plug induced fast burn compared to the conventional spark plug and its effects were increased in lean air fuel ratio. Pre-ignition chamber spark plug with 5 holes which had adjusted size was more stable and effective in combustion performance than pre-ignition chamber spark plug with 1 hole. And its effects showed larger differences in lean air fuel ratio than stoichiometric condition. Flame kernel and flame growth process of conventional spark plug and pre-ignition chamber spark plug studied by flame visualization of schlieren method.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1997년도 춘계학술대회 논문집
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• pp.107-110
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• 1997

LiMn$_2$O$_4$ is prepared by reacting stoichiometric mixture of LiOH . $H_2O$ and MnO$_2$ (mole ratio 1 ; 1) and heating at 80$0^{\circ}C$, $700^{\circ}C$ for 24h, 36h, 48h, 60h and 72h. We obtained through X-ray diffraction that lattice parameter varied as function of calcined temperature and time. Cathode active materials calcined at 80$0^{\circ}C$ for 36h, (111)/(311) peak ratio was 0.37. It showed good charge/discharge characteristics. When (111)/(311) peak ratio was 0.37, it was that crystal structure is formed very well. In the result of charge/discharge test, when heated at 80$0^{\circ}C$ for 36h, charge/discharge characteristics of LiMn$_2$O$_4$ is the best.

• 한국세라믹학회지
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• 제26권6호
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• pp.737-746
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• 1989

After Ba-ferrite powders synthesized hydrothermally and its heated powders were dissolved partially with HCl treatment time, the BaO/Fe2O3 mole ratio of dissolved solutions and powders were measured by AAS, also, lattice constants, particle morphology and magnetic properties in HCl treated, heated and no-heated Ba-ferrite powders were abtained by means of XRD, SEM and VSM, respectively. From above analysis results, the effect of Ba/Fe mole ration in suspension(as starting material) on the BaO/Fe2O3 composition and particle characteristics of products were investigated, and the effect of heat treatment on magnetic properties of products examined. The composition, lattice constant and crystal phase of products depend on the Ba/Fe mole ratio in suspension. Ba content in surface or outer part of Ba-ferrite powder is higher than inner and heterogeneous, and the excess Ba ions in the inner part of particle move into the outer by heating, so that the mole ratio of BaO/Fe2O3 in the more jinner approaches more to the stoichiometric composition 1 : 6. The crystallinity, coercivity and saturation magnetization of products are increased by heat treatment, and the heat-treated samples synthesized hydrothermally in lower temperature are appreciated to have better powder characteristics.

• 한국분무공학회지
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• 제22권2호
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• pp.96-102
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• 2017

In order to reduce the NOx, SCR technology is most suitable. In this study, we focused on studying the injector part of urea-SCR system. When stoichiometric 1 mole of urea is injected, 2 moles of $NH_3$ are created. $NH_3$ causes a SCR reaction by reacting with NOx. However, urea is decomposed by the side reaction of coming out HNCO, deposit formation is formed. In this study, it was to design a nozzle that can spray the optimal spray flow rate. Test nozzle used in this experiment is efferverscent type. The result of the experiment, liquid flow rate was confirmed to be that they are dominated by the exit orifice diameter. The area ratio is defined by ratio of the area of exit orifice hole and that of aerorator. The droplet size was measured by varying the area ratios. In addition, it was also confirmed that there is no change of the liquid flow rate and air flow rate to change the aerorator at the same exit orifice. Further, It was confirmed that the droplet size was relatively uniform even though the area ratio was different. Finally, there is little change in the SMD that air flow rate increases in 0.3 or more ALR.

• 한국자동차공학회논문집
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• 제1권2호
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• pp.27-33
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• 1993

Using the solenoid driven gas injection valve, Hydrogen fuel supply system was made. It was attached to a single cylinder research engine and intake port injection type hydrogen fueled S.I. engine was constructed. Engine performance, emission characteristics, and abnormal combustion were studied through the engine test performed with the variations of fuel-air equivalence ratio and spark timing. Compared with gasoline, hydrogen burns so fast that cylinder peak pressure and temperature are higher and NO is emitted more at full load condition. IN the case of intake port injection type engine, COVimep becomes lower due to the well-mixing of air and fuel, and engine output is lower owing to the low volumetric efficiency. As fuel-air equivalence ratio goes up, the combustion speed increases, and COVimep decreases. NO emission peaks slightly lean of stoichiometric. As spark timing advances and fuel-air equivalence ratio goes up, the cylinder peak pressure and temperature become higher, so abnormal combustions take place easily.

• Advances in aircraft and spacecraft science
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• 제10권3호
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• pp.203-222
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• 2023

The detonation combustion is a supersonic combustion process follows on shock wave oscillations in detonation tube. In this paper numerical studies are carried out combined effect of blockage ratio and spacing of obstacle on detonation wave propagation of hydrogen-air mixture in pulse detonation combustor. The deflagration to detonation transition of stoichiometric (ϕ=1)fuel-air mixture in channel has been analyzed for effect of blockage ratio (BR)=0.39, 0.51, 0.59, 0.71 with spacing of 2D and 3D. The reactive Navier-Stokes equation is used to solve the detonation wave propagation mechanism in Ansys Fluent platform. The result shows that fully developed detonation wave initiation regime is observed near smaller vortex generator ratio of BR=0.39 inside the combustor. The turbulent rate of reaction has also a great significance role for shock wave structure. However, vortices of rapid detonation wave are appears near thin boundary layer of each obstacle. Finally, detonation combustor demonstrates the superiority of pressure gain combustor with turbulent rate of reaction of 0.6 kg mol/m3 -s inside the detonation tube with obstacle spacing of 12 cm, this blockage enhanced the turbulence intensity and propulsive thrust. The successful detonation wave propagation speed is achieved in shortest possible time of 0.031s with a significance magnitude of 2349 m/s, which is higher than Chapman-Jouguet (C-J) velocity of 1848 m/s. Furthermore, stronger propulsive thrust force of 36.82 N is generated in pulse time of 0.031s.

• Journal of Forest and Environmental Science
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• 제40권1호
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• pp.9-14
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• 2024

Quantitative evaluation of nutrient status and stoichiometry on the forest floor is a good indicator of litter quality in various vegetation types. This study was conducted to determine the effects of vegetation type on the nutrient concentration and stoichiometry of forest floors at a regional scale. Forest floor samples were collected from four vegetation types of evergreen coniferous forests including Cryptomeria japonica, Chamaecyparis obtusa, evergreen broadleaf, and bamboo spp. forests in southern Korea. The dry weight of the forest floor was higher in the C. japonica and C. obtusa forests than in the evergreen broadleaf and bamboo forests. The mean carbon (C) concentrations of the forest floor were highest in the broadleaf forest, followed by the bamboo forest, C. japonica and C. obtusa forests. Mean nitrogen (N) and phosphorous (P) concentrations in the the coniferous forests were lower than those in the broadleaf and bamboo forests. The mean C:N ratio was the highest in C. obtusa forest (118±25), followed by C. japonica (66±6), evergreen broadleaf (41±1), and bamboo (30±1) forests. However, C:P and N:P ratios were lower in the coniferous forests than in the broadleaf forest indicating that the stoichiometry of the forest floor varies across vegetation types. The C, N, and P stocks on the forest floor were higher in the C. obtusa forest than in the broadleaf or bamboo forests. These results highlight that vegetation type-dependent stoichiometric ratio is an useful indicator for understanding interspecific difference in quality and quantity of the forest floor.