• 유기물자원화
• /
• 제15권3호
• /
• pp.121-128
• /
• 2007

이 연구의 목적은 배기가스로부터 생성된 신성가스 중 HCl의 제거를 위해 기존의 건식 반응기와 여과집진기를 사용하였다. 흡착제는 중탄산나트륨($NaHCO_3$)를 시용하였으며 흡착제($NaHCO_3$) 의 성능, 효율을 평가한다. 이러한 중탄산나트륨의 성능, 제거효율을 평가하여, 중탄산나트륨이 건식 반응기에서의 최적의 운전조건을 분석하였다. 체류시간, 당량비, 온도, 여과집진기의 압력등을 운전조건으로 하였으며 체류시간은 1.5sec로 고정하였고, 중탄산나트륨 주입비(당량비)를 1SR, 1.25SR으로 조절하였고, 온도는 $160^{\circ}C$, $180^{\circ}C$, $200^{\circ}C$로 하였고, 여과집진기의 압력은 210mmAq, 230mmAq, 250mmAq로 하였다. 이 연구에서는 온도가 큰 영향은 없고, 압력과 당량비가 많은 영향을 끼치는 것을 알 수 있다. 최적의 운전조건은 주입비 1SR에서 $180^{\circ}C$, 230mmAq이다. 이 조건에서의 제거율은 99.50%로 나왔다.

• 한국환경과학회지
• /
• 제10권1호
• /
• pp.59-64
• /
• 2001

The effect of major operating parameters in spray drying sorber(=SDS) for automatic control for the simultaneous removal of acidic and organic gaseous pollutants from solid waste incinerator was performed. The field experiment was carried out in pilot scale test for the quantification of major operating parameters of hydrophilic and the hydrophobic pollutants. The removal efficiencies of $SO_2$and HCI in the 5wt% slurry condition were being increased with the increase of the stoichiometric ration which is the molecular ratio of lime to the pollutant concentration, and with the decrease of inflow flue gas temperature in the pilot SDS reactor. The removal efficiency along the height of spray drying sorber was closely related to the temperature profile, and more than 90% of total removal efficiency was achieved in an absorption region. For the removal of acidic gas the optimum operating condition considering the economics and a stable operation is the 5wt% of slurry concentration, 1.2 of stoichiometric ratio and 25$0^{\circ}C$ of inflow flue gas temperature. For the organic gases of benzene and toluene the removal efficiencies were 20-60% which is much lower than that of acidic gas. The best removal efficiency was obtained at 1.5 of stoichiometric ratio and 25$0^{\circ}C$ of inflow flue gas temperature. The organic\`s removal efficiency along the height of spray drying sorber was quite different from that of acidic gas, that is, more than 60% of the total removal efficiency for benzene and 90% of the total removal for toluene were achieved in the dried adsorption region, which was formed at the lower or exit part of the reactor.

• Current Photovoltaic Research
• /
• 제7권4호
• /
• pp.103-110
• /
• 2019

Cu(In,Ga)₃Se₅ (β-CIGS) has a band gap of 1.35 eV, which is an optimum value for high solar-energy conversion efficiency. The effects of Cu and Ga content on the cell performance were investigated previously. However, the effect of Se content on the cell performance is not well understood yet. In this work, β-CIGS films were fabricated by three-stage co-evaporation of elemental sources with various Se fluxes at the third stage instead of at all stages. The average composition of five samples was Cu_1.05(In_0.59,Ga_0.41)3Se_y, where the stoichiometric y value is 5.03 and the stoichiometric Se/metal (Se/M) ratio is 1.24. We varied the Se/metal ratio in a range from 1.18 to 1.28. We found that the best efficiency was achieved when the Se/M ratio was 1.24, which is exactly the stoichiometric value where the CIGS grains on the CIGS surface were tightly connected and faceted. With the optimum Se/M ratio, we were able to enhance the cell efficiency of a β-CIGS solar cell from 9.6% to 12.0% by employing a Na₂S post deposition treatment. Our results indicate that Na₂S post deposition treatment is very effective to enhance the cell efficiency to a level on par with that in α-CIGS cell.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2001년도 제23회 KOSCO SYMPOSIUM 논문집
• /
• pp.153-160
• /
• 2001

The combustion test used DTF was performed to obtain the characteristics of NOx emission and reduction. In this test, major factor of NOx emission was a stoichiometric air ratio. At the onset of combustion to be rich oxygen, NOx was produced rapidly. Optimum condition for NOx reduction was formed under about AR:0.7 in the combustion test of Alaska coal. Investigations were undertaken with 200KW(th) test combustor. In combustion test, the major variables were coal feed ratio of center/outer, stoichiometric air ratio at the onset of combustion. The lowest NOx emission, 182ppm(6% O2 base), was achieved at about AR:0.6 of the first combustion stage with low NOx burner. Also, unburned carbon content of char collected in this combustion condition was about 1wt%.

• 한국분무공학회지
• /
• 제23권3호
• /
• pp.114-121
• /
• 2018

FT process is a technology of chemical reactions that converts a mixture of carbon monoxide and hydrogen into liquid hydrocarbons. During the FT process unreacted gas, known as Off-gas which has low-calorie, is discharged. In this study, we developed an engine that utilize simulated Off-gas, and studied the characteristics of the engine. The off-gas composition is assumed to be $H_2$ 70%, CO 15%, $CO_2$ 15% respectively. Under stoichiometric air-fuel ratio, the experiment was conducted at WOT and IMEP 0.3 Mpa changing compression ratio. Ignition timing was applied with MBT timing. Maximum indicated thermal efficiency 37% was achieved at compression ratio 15 under WOT. CO, $CO_2$ and $NO_x$ were influenced by changing compression ratio, and CO emission was satisfied with the US Tier 4 standard for nonroad engine over the entire experimental conditions.

• 대한기계학회논문집
• /
• 제17권6호
• /
• pp.1556-1571
• /
• 1993

본 연구에서는 소규모 실험장치(6.6kW)를 이용하여 $NO_x$ 저감방법 중에 가장 효율적인 방법이라 알려진 공기 및 연료의 단계적 연소법 (air and fuel staged combustion)을 이용하여, Fuel-N을 함유하고 있는 연료의 $NO_x$ 의 배출특성을 규명함 은 물론 최적 저 $NO_x$ 연소기술 향상방안을 제시하고자 한다.

• 자원리싸이클링
• /
• 제30권6호
• /
• pp.61-67
• /
• 2021

이리듐이 함유된 염산 침출액으로부터 시멘테이션법을 이용한 이리듐 회수 연구를 실시하였다. 환원제로는 아연을 사용하였으며, 환원제 투입량, 이리듐 초기 농도, 초기 pH, 반응 시간 변화 및 초음파 처리에 따른 이리듐 회수율 특성 실험을 실시하였다. 교반기만 사용한 조건에서는 아연 투입량 증가에 따라 이리듐의 회수율이 지속적으로 증가하였으나, 아연 당량이 40 조건에서 70% 수준의 이리듐 회수율을 나타냈다. 초음파 처리에 따른 시멘테이션 조건에서는 아연 투입량이 20 당량 이하 조건에서 이리듐의 회수율이 감소하였고, 40 당량 조건에서는 이리듐 회수율이 급격히 증가하는 특성을 나타났다. 이는 초음파 처리에 따른 아연의 이온화 및 이리듐 재용해되어 나타난 결과로 판단된다. 초음파 장치를 교반기와 함께 사용한 조건에서 교반기만 사용한 동일 조건에 비해 27% 이상 이리듐 회수율이 증가함을 확인하였고, 99%의 이리듐 회수가 가능하였다(아연 40 당량, 초기 pH 0.01, 100 ml, 이리듐 초기 농도 1770 ppm, 60 min.).

• 한국전기전자재료학회논문지
• /
• 제18권10호
• /
• pp.909-916
• /
• 2005

The structural and electrical property of RF magnetron sputtered ZnO thin film have been studied as a function of RF power, substrate temperature, oxygen/argon gas ratio and film thickness at constant sputtering power, sputtering working pressure and target-substrate distance. To analyze a crystallo-graphic properties of the films, $\theta$/2$\theta$ mode X-ray diffraction, SEM, and AFM analyses. C-axis preferred orientation, resistivity and surface roughness highly depended on oxygen/argon gas ratio. The resistivity of ZnO thin film(6000 ${\AA}$) rapidly increased with increasing oxygen ratio and the resistivity value of $9 {\ast} 10^7 {\Omega}cm$ was obtained at a working pressure of 10 mTorr with the same oxygen/argon gas ratio. The surface roughness was also improved with increasing oxygen ratio and the ZnO films deposited with the same oxygen/argon gas ratio showed the excellent roughness value of 28.7 ${\AA}$. With increase of the substrate temperature, The C-axis preferred orientation of ZnO thin film increases and the resistivity decreases due to deviation from the stoichiometric ZnO due to oxygen deficiency.

• 대한기계학회논문집B
• /
• 제31권6호
• /
• pp.539-546
• /
• 2007

An experimental study was performed to investigate the characteristics of chemiluminescence in a radiant burner, varying the excess air ratio from 0.91 to 1.67 at firing rate 80.5 to 134.2 kW/m2 on $OH^*,\;CH^*,\;{C_2}^*$ in LNG-Air premixed flames. The signals from electronically excited states of $OH^*,\;CH^*,\;{C_2}^*$ were detected using a Intensified Couple Charged Detector (ICCD) camera. The measurements of exhausted emission were made to investigate the correlation between chemiluminescence and emissions. The chemiluminescence intensity was increased with increase of firing rate like characteristics of $NO_x$ emission. $NO_x$ also increased with increase of firing rate and excess air ratio. It is found that offset of firing rate is more dominant excess air ratio $NO_x$ emission. The maximum chemiluminescence intensity occurs near the stoichiometric excess air ratio or lean conditions in case of high firing rate and the maximum intensity occurs rather than rich conditions in case of relatively low firing rate. Amount of $NO_x$ emission is maximum at near stoichiometric excess air ratio, which is chemiluminescence intensity is maximum.

• 한국가스학회지
• /
• 제12권3호
• /
• pp.13-19
• /
• 2008

열병합발전용으로 사용되는 여러 가지 원동기 중 천연가스 엔진은 1 MW 이하의 발전용량을 갖는 원동기로 가장 널리 사용되고 있다. 이론공연비 연소방식과 삼원촉매를 채택한 300 kW급 천연가스 엔진은 강화된 배기규제를 만족시킬 수 있지만 이론공연비 연소방식은 희박 연소방식에 비해 효율이 대체적으로 낮기 때문에 최적 점화시기(MBT) 제어가 필요하다. 그러나 MBT 운전조건은 노킹이 발생되기 쉬워 높은 흡기온도 조건에서 운전되는 엔진에 대해서는 노킹제어가 이루어져야 한다. 본 연구에서는 높은 흡기온도가 요구되는 열병합발전용 천연가스엔진을 대상으로 흡기온도에 따른 엔진성능과 노킹특성에 대하여 실험한 결과를 제시하였다.