Removal of HCl Using a Bag-Filter with Addition of Bicarbonate

중탄산나트륨이 첨가된 여과집진기를 이용한 염화수소의 제거

  • Lee, Keon-Joo (Department of environmental Engineering, SangJi University)
  • Received : 2007.09.06
  • Accepted : 2007.09.20
  • Published : 2007.09.30

Abstract

The purpose of this study was to investigate the removal efficiencies of HCl in dry reactor and Bag-Filter system. The bicarbonate was used as adsorbent to measure the HCl removal rate. The performance of bicarbonate was evaluated to investigate the removal efficiency. It was analysed that the best operation condition in using bicarbonate in process. The operating parameters was residence time, stoichiometric ratio, temperature and pressure. The Residence time was 1.5 sec, stoichiometric ratio was 1SR, 1.25SR, temperature was $160^{\circ}C$, $180^{\circ}C$, $200^{\circ}C$ and the bag filter pressure was 210mmAq, 230mmAq, 250mmAq. In this study it was found that the stoichiometric ratio and pressure can be effected in removal of HCl however the removal efficiency do not depends on temperature. The best operating condition was on 1SR, 230mmAq and $180^{\circ}C$ respectively and in this condition the best removal rate was 99.50%.

이 연구의 목적은 배기가스로부터 생성된 신성가스 중 HCl의 제거를 위해 기존의 건식 반응기와 여과집진기를 사용하였다. 흡착제는 중탄산나트륨($NaHCO_3$)를 시용하였으며 흡착제($NaHCO_3$) 의 성능, 효율을 평가한다. 이러한 중탄산나트륨의 성능, 제거효율을 평가하여, 중탄산나트륨이 건식 반응기에서의 최적의 운전조건을 분석하였다. 체류시간, 당량비, 온도, 여과집진기의 압력등을 운전조건으로 하였으며 체류시간은 1.5sec로 고정하였고, 중탄산나트륨 주입비(당량비)를 1SR, 1.25SR으로 조절하였고, 온도는 $160^{\circ}C$, $180^{\circ}C$, $200^{\circ}C$로 하였고, 여과집진기의 압력은 210mmAq, 230mmAq, 250mmAq로 하였다. 이 연구에서는 온도가 큰 영향은 없고, 압력과 당량비가 많은 영향을 끼치는 것을 알 수 있다. 최적의 운전조건은 주입비 1SR에서 $180^{\circ}C$, 230mmAq이다. 이 조건에서의 제거율은 99.50%로 나왔다.

Keywords