• Bulletin of the Korean Chemical Society
• /
• v.27 no.3
• /
• pp.363-367
• /
• 2006

The structure-property relations of ternary copper chalcogenides, $TlCu_{3-x}S_2$ and $\alpha-BaCu_{2-x}S_2$ are examined. The density of states, band dispersions, and Fermi surfaces of these compounds are investigated to verify the reason of the metal-insulator transitions by extended Huckel tight-binding band calculations. The origin of the metalinsulator transitions of non-stoichiometric $TlCu_{3-x}S_2$ and $\alpha-BaCu_{2-x}S_2$ is thought to be the electronic instability induced by their Fermi surface nesting.

• Journal of Advanced Marine Engineering and Technology
• /
• v.30 no.4
• /
• pp.455-462
• /
• 2006

Natural gas is a promising alternative fuel to meet strict engine emission regulations in many countries. Natural gas engines can operate at lean burn and stoichiometric burn conditions with different combustion and emission characteristics. In this paper, the fuel economy, emissions, misfire, knock and cycle-to-cycle variations in indicated mean effective pressure of lean burn natural gas engines are highlighted. Stoichiometric burn natural gas engines are briefly reviewed. To keep the output power and torque of natural gas engines comparable to that of gasoline engines, high boosting pressure should be used. High activity catalyst for methane oxidation and lean deNOx system or three way catalyst with precisely control strategies should be developed to meet stringent emission standards.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.9 no.5
• /
• pp.23-29
• /
• 2001

This paper is the second of companion papers, which investigate port-masking effects on emission and fuel economy. Port-masking was applied to commercial SOHC 3-valve engine by inserting masking plates between manifold and port. To induce various conditions of stratification, six types of masking plates were applied. In this paper, main interest is focused on the influence of injection timing on emission and fuel economy. Various injection timing was applied to the six cases, under the stoichiometric and lean-limit air-fuel ratio. Under the stoichiometric condition, an explanation about the reason of the change in emission level due to injection timing change is given. It is observed that NOx emission under the LML condition varies significantly when the injection timing changes.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.6 no.2
• /
• pp.32-42
• /
• 1998

Lean burn gasoline engine is recognized as a promising way to meet better fuel economy. Lean burn engine is classified into port injection and direct injection(DI), DI is more active technique for improving fuel economy with ultra-lean operation, Nowadays, port injected lean burn engine has been produced by many Japan maker. Also, DI engine is also possible for production owing to improvement in control technique of spray, flow air fuel ratio. DI engine uses either homogeneous stoichiometric mixture or stratified mixture by controlling injection timing to be early or late respectively. HM(homogeneous mixture) is worse than SM(stratified mixture) in view of ultra-lean operation in partical load and Nox reducion by using EGR control. But, HM has advanteges in cold starting and emission reduction during transient operation, This paper describes experimental variables and bench test results of HM GDI engine.

• Journal of Mechanical Science and Technology
• /
• v.16 no.12
• /
• pp.1710-1718
• /
• 2002

The effect of fuel concentration gradient on the propagation characteristics of tribrachial (or triple) flames has been investigated experimentally in both two-dimensional and axisymmetric counterflows. The gradient at the stoichiometric location was controlled by the equivalence ratios at the two nozzles; one of which is maintained rich, while the other lean. Results show that the displacement speed of tribrachial flames in the two-dimensional counterflow decreases with fuel concentration gradient and has much larger speed than the maximum speed predicted previously in two-dimensional mixing layers. From an analogy with premixed flame propagation, this excessively large displacement speed can be attributed to the flame propagation with respect to burnt gas. Corresponding maximum speed in the limit of small mixture fraction gradient was estimated and the curvefit of the experimental data substantiates this limiting speed. As mixture fraction gradient approaches zero, a transition occurs, such that the propagation speed of tribrachial flame approaches stoichiometric laminar burning velocity with respect to burnt gas. Similar results have been obtained for tribrachial flames propagating in axisymmetric counterflow.

• Journal of Advanced Marine Engineering and Technology
• /
• v.32 no.3
• /
• pp.394-403
• /
• 2008

The effects of water injection (WI) and urea injection for NOx on a 4-cylinder Direct Injection (DI) diesel engine were investigated experimentally. For water injection, it was installed at the intake pipe and the water quantity was controlled at the intake manifold and Manifold Air Flow (MAF) temperatures while the urea injection was located at the exhaust pipe and the urea quantity was controlled by NOx quantity and MAF. The effects of WI system, urea-SCR system and the combined system were investigated with and without exhaust gas recirculation (EGR). Several experiments were performed to characterize the urea-SCR system, using engine operating points of varying raw NOx emissions. The results of the Stoichiometric Urea Flow (SUF) and NOx map were obtained. In addition, NOx results were illustrated according to the engine speed and load. It is concluded that the NOx reduction effects of the combined system without the EGR were better than those with the EGR-based engine.

• 한국연소학회:학술대회논문집
• /
• 2000.12a
• /
• pp.160-167
• /
• 2000

We investigated a uniform temperature zone, produced by double flame structure of a coflow CH4/air partially premixed flame, to be used as a temperature calibration source for laser diagnostics. A broadband N2 CARS(coherent anti-Stokes Raman spectroscopy) system with a modeless laser was used for temperature measurement. When the stoichiometric ratio was 1.5, we found the uniform temperature zone in radial direction of the flame of which the averaged temperature was 2110 K with standard deviation 24 K. In the stoichiometric ratio range between 2.0 and 2.5, we found very stable temperature-varying zones in vertical direction at the center of the flame. The size of the zone was approximately 15 mm and it covered a temperature range from 300 K to 1900 K. We also suggest that this zone can be used as a calibration source for 2-D PLIF(planar laser induced flurescence) temperature measurement.

• Current Photovoltaic Research
• /
• v.4 no.3
• /
• pp.87-92
• /
• 2016

The effects of selenization pressure on the structural, optical and electrical properties of the CIGS thin films prepared by RF magnetron sputtering using a single quaternary target were investigated. At selenization pressures lower than atmospheric pressure, CIGS thin films formed non-stoichiometric compounds due to deficiencies of Se vapor. In contrast, when selenization process was conducted at above atmospheric pressure, the residence time of Se vapor inside the tube increased so that the Se element could be incorporated within vacant sites of the CIGS structure, resulting in the formation of stoichiometric CIGS thin films. High quality CIGS thin films could be obtained when the selenization process was performed at pressures greater than atmospheric and $550^{\circ}C$.

• Proceedings of the Korean Powder Metallurgy Institute Conference
• /
• 2000.11a
• /
• pp.11-12
• /
• 2000

Non-stoichiometric ceramics of $Ni_{x}ZnO_{1-x}Fe_{2}O_{4}$ were prepared by self-propagating high temperature synthesis reaction with various processing conditions and their stoichometric numbers were determined by neutron diffraction. The neutron diffraction patterns were measured at room temperature using monochromatic neutrons with a wave length of 0.18339 nm from a Ge(331) mocochromator at a 90 degree take off angle. The Rietveld refinement of each pattern converged to good agreement (x2=1.88-2.24). The neutron diffraction analysis revealed the final stoichiometries of the ferrites were $Ni_{0.38}Zn_{0.62}Fe_{2}O_{4}$ and $Ni_{0.33}Zn_{0.67}Fe_{2}O_{4]$, respectively. This supports that final stoichiometric number of the self-propagating high temperature synthesis product can be controlled by the processing parameters during the combustion reaction.

• 한국연소학회:학술대회논문집
• /
• 2001.11a
• /
• pp.153-160
• /
• 2001

The combustion test used DTF was performed to obtain the characteristics of NOx emission and reduction. In this test, major factor of NOx emission was a stoichiometric air ratio. At the onset of combustion to be rich oxygen, NOx was produced rapidly. Optimum condition for NOx reduction was formed under about AR:0.7 in the combustion test of Alaska coal. Investigations were undertaken with 200KW(th) test combustor. In combustion test, the major variables were coal feed ratio of center/outer, stoichiometric air ratio at the onset of combustion. The lowest NOx emission, 182ppm(6% O2 base), was achieved at about AR:0.6 of the first combustion stage with low NOx burner. Also, unburned carbon content of char collected in this combustion condition was about 1wt%.