• 제목/요약/키워드: steel and iron

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사철 제련을 통해 생산된 슬래그와 괴련철의 재료과학적 특성 비교 (Material Characteristic of Slags and Iron Bloom Produced by Smelting Process Using Sand Iron)

  • 조성모;조현경;권인철;조남철
    • 보존과학회지
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    • 제34권1호
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    • pp.39-50
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    • 2018
  • 본 연구에서는 전통 제련법을 토대로 사철을 이용해 괴련철 생산을 재현하고 슬래그 및 괴련철을 분석하여 재료학적 특성을 알아보았다. 원료는 고문헌을 토대로 경주사철과 포항사철을 이용했다. WD-XRF 및 XRD 결과 경주사철은 저티탄사철의 Magnetite이며 포항사철은 고티탄사철의 Magnetite와 Ilmenite가 혼합됨을 확인하였다. 슬래그의 XRD 및 미세조직 분석결과 경주사철 슬래그는 Fayalite와 $W{\ddot{u}stite$, 포항사철 슬래그는 Titanomagnetite와 Fayalite가 확인되어 사철의 Ti 함량에 따른 조직의 차이를 확인하였다. 괴련철의 미세조직의 분석결과 경주사철 괴련철은 표면에 공석강에 가까운 탄소함량을 보이는 Pearlite가 우세하며, 내부는 Ferrite와 Pearlite가 혼재된 아공석강이었다. 포항사철 괴련철은 순철에 가까운 Ferrite이었다. 괴련철의 철물화를 위해서는 내부 불순물 제거, 조직을 치밀하게 하는 정련 및 단접이 필요함을 확인하였다. 향후 다양한 조건의 전통 제철 실험을 통해 제철부산물의 성격을 규명하고 제철 유적의 특징을 알아보는데 중요한 데이터로 활용 가능할 것이다.

Microstructure and Properties of High Nitrogen Sintered Stainless Steel

  • Pieczonka, Tadeusz;Stoytchev, Marin
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.568-569
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    • 2006
  • The use of the nickel free, high nitrogen stainless steel powder and nitriding during sintering of iron based materials have been shown as an alternative way to the conventional PM stainless steels containing nickel. Nitrogen as an alloying element for iron improves in an effective way the properties of sintered alloyed steels. The powder metallurgy route is a suitable way to introduce nitrogen into these alloys and, in particular, to produce high nitrogen (close to the solubility limit) stainless steels. The paper presents and discusses the nitriding behavior of nickel-free stainless steels produced by powder metallurgy method. Alloyed melt was atomized by nitrogen and in this way nitrogen was introduced into the powder. Further nitriding occurred during sintering in a nitrogen atmosphere. For comparison, compacts having the same composition as an alloyed powder were produced from elemental powders mixture. Sintering-nitriding behaviour of investigated materials has been controlled by dilatometry, chemical and X-Ray phase analysis and metallography. Mechanical properties of sintered compacts were also measured.

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가스용 금속 플렉시블 호스의 용접방법 개선에 관한 연구 (An Improvement of Welding Method for the Corrugated Stainless Steel Tubing(CSST))

  • 김완진;이영섭;최진림
    • 한국안전학회지
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    • 제23권5호
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    • pp.79-83
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    • 2008
  • The corrugated stainless steel tubing(CSST) for the fuel gas piping system can be installed easily and quickly. It is often constructed under the ceiling and the wall which has a good flexibility and installation in comparison with iron pipe. However, the quality of the CSST is determined to depend upon the welding skill of stainless steel tubing. In this study, it is tested by controlling jet point of Ar as inert and cooling gas, and also compared with the bead state of welding point and the performance. As a result, it has the best condition when the jet point of Ar is located behind $5{\sim}10mm$ of the welding point.

주철과 Fe-Mn-Al강 이종금속 용접부의 조직변화에 관한 연구 (A study on the microstructure change during the welding of a cast iron with a Fe-Mn-Al steel powder)

  • 김경중;서정현
    • Journal of Welding and Joining
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    • 제8권4호
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    • pp.35-45
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    • 1990
  • Casting are widely used nodays as complicated and diversified forming materials due to its superior castability. However the welding of cast iron has not been accompaniced satisfactory resulting in an microstructure change happened in the heat affected zone (HAZ), especially the graphite are formed and shaped consecutively in the area and it has great impact on the crack occuring and growth together with martensite forming in this area. It case of gray cast iron welding, it is required for pre-heat treatment or specific welding consumables to restrain forming the martensite in the HAZ. In this study, by applying the plasma surface overlaid welding. Fe-Mn-Al steel powder has been used for improvement of anti-crackability in the HAZ and much attention has been paid to establish the overlaid welding method for gray cast iron so that optimum welding conditions may prevent the cracking. With our experiments, we have found that to prevent defects which may occur in the HAZ, the overlaid welding technique for gray cast iron has been developed.

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철부식생성물 저감을 위한 고온 pH(t) 상향 연구 (Study on Increasing High Temperature pH(t) to Reduce Iron Corrosion Products)

  • 신동만;허남용;김왕배
    • Corrosion Science and Technology
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    • 제10권5호
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    • pp.175-179
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    • 2011
  • The transportation and deposition of iron corrosion products are important elements that affect both the steam generator (SG) integrity and secondary system in pressurized water reactor (PWR) nuclear power plants. Most of iron corrosion products are generated on carbon steel materials due to flow accelerated corrosion (FAC). The several parameters like water chemistry, temperature, hydrodynamic, and steel composition affect FAC. It is well established that the at-temperature pH of the deaerated water system has a first order effect on the FAC rate of carbon steels through nuclear industry researches. In order to reduce transportation and deposition of iron corrosion products, increasing pH(t) tests were applied on secondary system of A, B units. Increasing pH(t) successfully reduced flow accelerated corrosion. The effect of increasing pH(t) to inhibit FAC was identified through the experiment and pH(t) evaluation in this paper.

Investigation of shinning Spot Defect on Hot-Dip Galvanized Steel Sheets

  • Liu, Yonggang;Cui, Lei
    • Corrosion Science and Technology
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    • 제13권4호
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    • pp.125-129
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    • 2014
  • Shinning spot defects on galvanized steel sheets were studied by optical microscope, scanning electron microscope(SEM), Energy Dispersive Spectrometer (EDS) and Laser-Induced Breakdown Spectroscopy Original Position Statistic Distribution Analysis (LIBSOPA) in this study. The research shows that the coating thickness of shinning spot defects which caused by the substrate defect is much lower than normal area, and when skin passed, the shinning spot defect area can not touch with skin pass roll which result in the surface of shinning spot is flat while normal area is rough. The different coating morphologies have different effects on the reflection of light, which cause the shinning spot defects more brighter than normal area.

400계열 FSTS의 내식성이 ABS 센서 링에 미치는 영향 (Effect on 400 series Ferrite Stainless Steel Corrosion Resistance of ABS Sensor Ring)

  • 양현수
    • 대한안전경영과학회지
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    • 제2권3호
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    • pp.197-210
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    • 2000
  • In this paper, sensor ring for antilock brake system was studied using the 400 series ferrite stainless steel powder. Because of more excellent corrosion resistance and mechanical characteristics than iron, sensor ring has been manufactured by P/M(Powder Metallurgy) method 400 series ferrite stainless steel. the results are following. 1, Compared with sensor ring made by iron, 400 series ferrite stainless steel has shown a good corrosion resistance without an addition surface treatment. thus the decreasing production process has been obtained. 2. The products before sintering are much more corrodible in the condition of spray test of salt water and ammonia than humidity and nitrogen condition.

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"Buildings Without Walls:" A Tectonic Case for Two "First" Skyscrapers

  • Leslie, Thomas
    • 국제초고층학회논문집
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    • 제9권1호
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    • pp.53-60
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    • 2020
  • "A practical architect might not unnaturally conceive the idea of erecting a vast edifice whose frame should be entirely of iron, and clothing the frame--preserving it--by means of a casing of stone…that shell must be regarded only as an envelope, having no function other than supporting itself..." --Viollet-le-Duc, 1868. Viollet-le-Duc's recipe for an encased iron frame foresaw the separation of structural and enclosing functions into discrete systems. This separation is an essential characteristic of skyscrapers today, but at the time of his writing cast iron's brittle nature meant that iron frames could not, on their own, resist lateral forces in tall structures. Instead, tall buildings had to be braced with masonry shear walls, which often also served as environmental enclosure. The commercial availability of steel after the 1880s allowed for self-braced metal frames while parallel advances in glass and terra cotta allowed exterior walls to achieve vanishingly thin proportions. Two Chicago buildings by D.H. Burnham & Co. were the first to match a frame "entirely of iron" with an "envelope" supporting only itself. The Reliance Building (1895) was the first of these, but the Fisher Building (1896) more fully exploited this new constructive typology, eschewing brick entirely, to become the first "building without walls," a break with millennia of tall construction reliant upon masonry

초고강도급 자동차용 강재 내 ε-carbide (Fe2.4C)가 부식 및 수소확산거동에 미치는 영향 (Effect of ε-carbide (Fe2.4C) on Corrosion and Hydrogen Diffusion Behaviors of Automotive Ultrahigh-Strength Steel Sheet)

  • 박진성;윤덕빈;성환구;김성진
    • Corrosion Science and Technology
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    • 제20권5호
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    • pp.295-307
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    • 2021
  • Effects of ε-carbide (Fe2.4C) on corrosion and hydrogen diffusion behaviors of ultra-strong steel sheets for automotive application were investigated using a number of experimental and analytical methods. Results of this study showed that the type of iron carbide precipitated during tempering treatments conducted at below A1 temperatures had a significant influence on corrosion kinetics. Compared to a steel sample with cementite (Fe3C), a steel sample with ε-carbide (Fe2.4C) showed higher corrosion resistance during a long-term exposure to a neutral aqueous solution. In addition, the diffusion kinetics of hydrogen atoms formed by electrochemical corrosion reactions in the steel matrix with ε-carbide were slower than the steel matrix with cementite because of a comparatively higher binding energy of hydrogen with ε-carbide. These results suggest that designing steels with fine ε-carbide distributed uniformly throughout the matrix can be an effective technical strategy to ensure high resistance to hydrogen embrittlement induced by aqueous corrosion.