• Title/Summary/Keyword: steady shear rheological properties

Search Result 44, Processing Time 0.027 seconds

Rheological, Characterization of Aqueous Poly(Ethylene Oxide) Solutions - Creep and Creep Recovery - (폴리에틸렌옥사이드 수용액의 유변학적 특성 평가 - 크리프 및 크리프 회복 -)

  • 장갑식;김태훈;박영훈;송기원
    • Proceedings of the Korean Fiber Society Conference
    • /
    • 2001.10a
    • /
    • pp.175-178
    • /
    • 2001
  • 일반적으로 점탄성 거동을 나타내는 고분자 액체의 전단유동특성(shear flow properties)을 평가하기 위하여 정상전단(steady shear), 동적전단(dynamic shear), 응력완화(stress relaxation) 그리고 크리프(creep) 및 크리프 회복(creep recovery) 실험 등이 활용되고 있다[1], 이때 영전단점도(zero shear viscosity)와 정상상태 회복 컴플라이언스(steady-state recoverable compliance)는 정상상태(steady state)에서 얻어지는 물리량으로, 각 실험방법으로부터 직접적 또는 간접적으로 측정이 가능하다. (중략)

  • PDF

Rheological Properties of Waxy Rice Starch-Gum Mixtures in Steady and Dynamic Shear

  • Kim, Do-Dan;Lee, Young-Seung;Yoo, Byoung-Seung
    • Preventive Nutrition and Food Science
    • /
    • v.14 no.3
    • /
    • pp.233-239
    • /
    • 2009
  • The effects of guar gum (GG) and xanthan gum (XG) at different concentrations (0, 0.2, 0.4, and 0.6% w/w) on the rheological properties of Korean waxy rice starch (WRS) pastes were evaluated under both steady and dynamic shear conditions. The flow properties of WRS-gum mixtures were determined from the rheological parameters of the power law model. The addition of GG and XG to WRS resulted in an increase in the apparent viscosity ($\eta_{a,100}$) and consistency index (K) values obtained from power law model. The flow behavior index (n) values of the WRS-XG mixtures decreased with an increase in gum concentration while there was only a marginal difference between n values for the WRS-GG mixtures. Dynamic moduli (G', G", and $\eta^*$) values in the WRS-gum mixture systems also increased with an increase in gum concentration. WRS-XG mixtures had higher dynamic moduli and lower tan $\delta$ (ratio of G"/G') values than WRS-GG mixtures, indicating that the higher dynamic rheological properties of WRS-XG can be attributed to an increase in the viscoelasticity of the continuous phase in the starch-gum mixture systems, which was due to the higher viscoleastic properties of XG compared to GG. The dynamic ($\eta^*$) and steady shear ($\eta_a$) viscosities of the WRS-XG paste at a 0.2% gum concentration followed the Cox-Merz superposition rule.

Rheological Differences of Waxy Barley Flour Dispersions Mixed with Various Gums

  • Kim, Chong-Yeon;Yoo, Byoungseung
    • Preventive Nutrition and Food Science
    • /
    • v.22 no.1
    • /
    • pp.56-61
    • /
    • 2017
  • Rheological properties of waxy barley flour (WBF) dispersions mixed with various gums (carboxyl methyl celluleose, guar gum, gum arabic, konjac gum, locust bean gum, tara gum, and xanthan gum) at different gum concentrations were examined in steady and dynamic shear. WBF-gum mixture samples showed a clear trend of shear-thinning behavior and had a non-Newtonian nature with yield stress. Rheological tests indicated that the flow and dynamic rheological parameter (apparent viscosity, consistency index, yield stress, storage modulus, and loss modulus) values of WBF dispersions mixed with gums, except for gum arabic, were significantly higher than those of WBF with no gum, and also increased with an increase in gum concentration. In particular, konjac gum at 0.6% among other gums showed the highest rheological parameter values. Tan ${\delta}$ values of WBF-xanthan gum mixtures were lower than those of other gums, showing that there is a more pronounced synergistic effect on the elastic properties of WBF in the presence of xanthan gum. Such synergistic effect was hypothesized by considering thermodynamic compatibility between xanthan gum and WBF. These rheological results suggest that in the WBF-gum mixture systems, the addition of gums modified the flow and viscoelastic properties of WBF, and that these modifications were dependent on the type of gum and gum concentration.

Rheological and Pasting Properties of Naked Barley Flour as Modified by Guar, Xanthan, and Locust Bean Gums

  • Yoon, Sung-Jin;Lee, Youngseung;Yoo, Byoungseung
    • Preventive Nutrition and Food Science
    • /
    • v.21 no.4
    • /
    • pp.367-372
    • /
    • 2016
  • To understand the effects of adding different gums (guar, xanthan, and locust bean gums) on naked barley flour (NBF), the rheological and pasting properties of NBF-gum mixtures were measured at different gum concentrations (0, 0.3, and 0.6% w/w). Steady shear rheological properties were determined by rheological parameters for power law and Casson models. All samples showed a clear trend of shear-thinning behavior (n=0.16~0.48) and had a non-Newtonian nature with yield stress. Consistency index, apparent viscosity, and yield stress values increased with an increase in gum concentration. Storage modulus values were more predominant than loss modulus values with all concentrations of gums. There is a more pronounced synergistic effect of elastic properties of NBF in the presence of xanthan gum. Rapid visco analyser pasting properties showed that the addition of gums resulted in a significant increase in the peak, breakdown, setback, and final viscosities, whereas the pasting temperature decreased.

Constitutive Equations for Dilute Bubble Suspensions and Rheological Behavior in Simple Shear and Uniaxial Elongational Flow Fields

  • Seo Dongjin;Youn Jae Ryoun
    • Fibers and Polymers
    • /
    • v.6 no.2
    • /
    • pp.131-138
    • /
    • 2005
  • A theoretical model is proposed in order to investigate rheological behavior of bubble suspension with large deformation. Theoretical constitutive equations for dilute bubble suspensions are derived by applying a deformation theory of ellipsoidal droplet [1] to a phenomenological suspension theory [2]. The rate of deformation tensor within the bubble and the time evolution of interface tensor are predicted by applying the proposed constitutive equations, which have two free fitting parameters. The transient and steady rheological properties of dilute bubble suspensions are studied for several capillary numbers (Ca) under simple shear flow and uniaxial elongational flow fields. The retraction force of the bubble caused by the interfacial tension increases as bubbles undergo deformation. The transient and steady relative viscosity decreases as Ca increases. The normal stress difference (NSD) under the simple shear has the largest value when Ca is around 1 and the ratio Of the first NSD to the second NSD has the value of 3/4 for large Ca but 2 for small Ca. In the uniaxial elongational flow, the elongational viscosity is three times as large as the shear viscosity like the Newtonian fluid.

Flow Rate-Pressure Drop Characteristics of Dispersive ER Fluid According to Change of Electric Field Strength in Clearance between Parallel Plates (평행평판 간극에서 전기장의 강도변화에 따른 분산계 ER유체의 유량-압력강하 특성)

  • 장성철;염만오;김도태
    • Transactions of the Korean Society of Machine Tool Engineers
    • /
    • v.12 no.1
    • /
    • pp.78-83
    • /
    • 2003
  • Electro-rheological(ER) fluids are suspensions in which rheological properties show an abrupt change with variation of electric fields. We modeled the parallel-plates relating to ER-Valve system and yielded shear stress according to the strength of electric field. The purpose of the present study is to examine the flow characteristics of ER fluids according to the strength of electric field between parallel-plates. Then the steady relationship between pressure drop and flow rate of the ER fluids between parallel-plates under application of an electric fields was measured. The pressure drop and flow rates of ER fluids under the application of electric fields for steady flow were measured. For the experiment, we used the ER fluids, 35w% zeolite having hydrous particles and differential pressure gauge. This test reviewed experiment for the special changes of ER fluids in the steady flow condition.

Rheological properties of chitosan solutions

  • Hwang, Jae-Kwan;Shin, Hae-Hun
    • Korea-Australia Rheology Journal
    • /
    • v.12 no.3_4
    • /
    • pp.175-179
    • /
    • 2000
  • Rheological properties of chitosan solutions were investigated as a function of polymer concentration. The viscosity curves for chitosan solutions consisted of two distinct viscosity regions, the Newtonian zero-shear viscosity (η$_{0}$) region and the shear rate dependent apparent viscosity (η$_{app}$) region. The shear rate dependence of viscosity was more clearly observed at higher chitosan concentrations. The critical coil overlap parameter (C*〔η〕) was determined to be approximately 3.2 from a plot of zero-shear specific viscosity η$_{sp,0}$ vs coil overlap parameter (C〔η〕), which was lower than C〔η〕4.0 reported for other random coil polysaccharides. It was also found that the slope of η$_{sp,0}$ vs C〔η〕 was 3.9 at concentrated C〔η〕>C*〔η〕domain, while 1.2 at dilute C〔η〕$_{0}$ ${\gamma}$/${\gamma}$$_{0.8}$ relation.ion.n.n.

  • PDF

Emulsion rheology and properties of polymerized high internal phase emulsions

  • Lee, Seong-Jae
    • Korea-Australia Rheology Journal
    • /
    • v.18 no.4
    • /
    • pp.183-189
    • /
    • 2006
  • High internal phase emulsions are highly concentrated emulsion systems consisting of a large volume of dispersed phase above 0.74. The rheological properties of high internal phase water-in-oil emulsions were measured conducting steady shear, oscillatory shear and creep/recovery experiments. It was found that the yield stress is inversely proportional to the drop size with the exponent of values between 1 and 2. Since the oil phase contains monomeric species, microcellular foams can easily be prepared from high internal phase emulsions. In this study, the microcellular foams combining a couple of thickeners into the conventional formulation of styrene and water system were investigated to understand the effect of viscosity ratio on cell size. Cell size variation on thickener concentration could be explained by a dimensional analysis between the capillary number and the viscosity ratio. Compression properties of foam are important end use properties in many practical applications. Crush strength and Young's modulus of microcellular foams polymerized from high internal phase emulsions were measured and compared from compression tests. Of the foams tested in this study, the foam prepared from the organoclay having reactive group as an oil phase thickener showed outstanding compression properties.

Rheological Properties of Freeze Dried $\alpha$-Rice Powder (동결건조 $\alpha$-미분의 물성에 관하여)

  • 김관유
    • The Korean Journal of Food And Nutrition
    • /
    • v.4 no.2
    • /
    • pp.199-206
    • /
    • 1991
  • Rheological properties of $\alpha$-rice powder were investigated in comparison with those of polished rice powder. Flow behavior for cooked solutions of two powdered samples(5~11%) were Binghampseudo plastic. Consistency index and yield stress of cooked solution of powdered a-rice were much lower than those of polished rice powder while flow behavior index was nearly similar. 9% cooked solution of powdered $\alpha$ -rice showed slightly weaker thixotrophic behavior and more ease tendency to relax under the steady shear than those of polished rice powder.

  • PDF

Studies on the Steady Shear Flow Properties of Sea Mustard Aqueous Extracts (열수 추출 미역액의 정상유동특성에 관한 연구)

  • 최희숙;오성훈
    • The Korean Journal of Food And Nutrition
    • /
    • v.13 no.1
    • /
    • pp.78-82
    • /
    • 2000
  • For the purpose of investigation of the food processing fittness of the sea mustard aqueous extracts, the steady shear flow have been measured over a wide range of shear rate using a Brookfield digital viscometer(SPDL21). The rheological behaviors of the sea mustard aqueous extracts which were extracted at 10$0^{\circ}C$ for 2 hours exhibited pseudoplastic behavior with yield stress. In the test of the relationship between temperature and apparent viscosity of samples at 10 rpm decreased along with the increment of temperature. The sea mustard aqueous extracts appeared greatly temperature dependent characteristics(Ea=1.51 ㎉/mole).

  • PDF