• Bulletin of the Korean Chemical Society
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• v.10 no.3
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• pp.262-269
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• 1989

The gas phase thermal decomposition of 1-bromo-3-chloropropane in the presence of radical inhibitor was studied by using the conventional static system. The mechanism of unimolecular elimination channel is shown below. [...] In this scheme, the total molecular dissociation rate constant, ($k_1\;+\;k_2$), for the decomposition of $BrCH_2CH_2CH_2Cl$ was determined by pyrolyzing the $BrCH_2CH_2CH_2Cl$ in the temperature range of $380-420^{\circ}C$ and in the pressure range of 10∼100 torr. To obtain $k_3\;and\;k_4,\;and\;to\;obtain\;k_1\;and\;k_2$ independently, the thermal decompositions of allyl chloride and allyl bromide were also studied. The Arrhenius parameters for each step are as follows; $log\;A_{\infty}\;=\;14.20(sec^{-1}),\;E_a$ = 56.10(kcal/mol) for reaction path 1; $log\;A_{\infty}\;=\;12.54(sec^{-1}),\;E_a$ = 49.75(kcal/mol) for reaction path 2; $log\;A_{\infty}\;=\;13.41(sec^{-1}),\;E_a$ = 50.04(kcal/mol) for reaction path 3; $log\;A_{\infty}\;=\;12.43(sec^{-1}),\;E_a$ = 52.78(kcal/mol) for reaction path 4; Finally, the experimentally observed pressure dependence of the rate constants in each step is compared with the theoretically predicted values that are obtained by the RRKM calculations.

• Structural Engineering and Mechanics
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• v.83 no.6
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• pp.811-824
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• 2022

Despite its disadvantages, soft story can reduce the damage to the upper floors by concentrating drift in that specific story provided that large drifts are avoided. Gapped-Inclined Brace (GIB) with reduced P-delta effects and the control of soft story stiffness makes it possible to take advantage of the soft story in buildings and increase their capacity for energy dissipation. OpenSees software is used in this study to validate and modify the GIB model's shortcomings. Also, the analysis method for this element is changed for design. The modified element is evaluated in 3D analysis. Finally, to retrofit an existing building, this element is used. Based on the Iranian seismic code, a six-story reinforced concrete building is modelled and studied with 3D analysis. In this building, the construction shortcomings and elimination of infills on the ground floor cause the formation of a soft story. Results of nonlinear static analysis, nonlinear dynamic, and incremental dynamic analysis using both components of seismic acceleration applied to the structure at different angles and the fragility curves indicate the improvement of the retrofitted structure's performance using the modified element to reach the required performance level following the retrofit code.

• Journal of KIISE:Software and Applications
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• v.32 no.7
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• pp.683-692
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• 2005

Java specification states that all accesses to an object must be checked at runtime if object refers to null. Since Java is an object-oriented language, object accesses are frequent enough to make null pointer checks affect the performance significantly. In order to reduce the performance degradation, there have been attempts to remove redundant null pointer checks. For example, in a Java environment where a just-in-time (JIT) compiler is used, the JIT compiler removes redundant null pointer check code via code analysis. This paper proposes a technique to remove additional null pointer check code that could not be removed by previous JIT compilation techniques, via early null pointer check using an architectural feature called predication. Generally, null point check code consists of two instructions: a compare and a branch. Our idea is moving the compare instruction that is usually located just before an use of an object, to the point right after the object is defined so that the total number of compare instructions is reduced. This results in reduction of dynamic and static compare instructions by 3.21$\%$ and 1.98$\%$. respectively, in SPECjvm98 bechmarks, compared to the code that has already been optimized by previous null pointer check elimination techniques. Its performance impact on an Itanium machine is an improvement of 0.32$\%$.

• Journal of the Korean Society of Safety
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• v.31 no.5
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• pp.22-27
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• 2016

The Electrostatic Charge Prevention Technology is a core factor that highly influences the yield of Ultra High Resolution Flat Panel Display and high-integrated semiconductor manufacturing processes. The corona or x-ray ionizations are commonly used in order to eliminate static charges during manufacturing processes. To develop such a revolutionary x-ray ionizer that is free of x-ray radiation and has function to control the volume of ion formation simultaneously is a goal of this research and it absolutely overcomes the current risks of x-ray ionization. Under the International Commission on Radiological Protection, it must have a leakage radiation level that should be lower than a recommended level that is $1{\mu}Sv/hour$. In this research, the new generation of x-ray ionizer can easily control both the volume of ion formation and the leakage radiation level at the same time. In the research, the test constraints were set and the descriptions are as below; First, In order not to leak x-ray radiation while testing, the shielding box was fully installed around the test equipment area. Second, Implement the metallic Ring Electrode along a tube window and applied zero to ${\pm}8kV$ with respect to manage the positive and negative ions formation. Lastly, the ion duty ratio was able to be controlled in different test set-ups along with a free x-ray leakage through the metallic Ring Electrode. In the result of experiment, the maximum x-ray radiation leakage was $0.2{\mu}Sv/h$. These outcome is lower than the ICRP 103 recommended value, which is $1{\mu}Sv/h$. When applying voltage to the metallic ring electrode, the positive decay time was 2.18s at the distance of 300 mm and its slope was 0.272. In addition, the negative decay time was 2.1s at the distance of 300 mm and its slope was 0.262. At the distance of 200 mm, the positive decay time was 2.29s and its slope was 0.286. The negative decay time was 2.35s and its slope was 0.293. At the distance of 100 mm, the positive decay time was 2.71s and its slope was 0.338. The negative decay time was 3.07s and its slope was 0.383. According to these research, the observation was shown that these new concept of ionizer is able to minimize the leakage radiation level and to control the positive and negative ion duty ratio while ionization.

• Journal of Korean Society of Steel Construction
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• v.12 no.3 s.46
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• pp.303-315
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• 2000

The main object of this study is to analyze mechanical behaviors as anisotropic three-dimensional body under various static loads. This paper presents the applicability of the finite difference method to three dimensional problem of anisotropic body. The finite difference method as applied here is generalized to anisotropic three-dimensional problem of elastic body where the governing differential equations of equilibrium of such bodies are expressed in terms of the displacement u, v, and w in the coordinates axes x, y and z, care being taken to modify the finite difference expressions to satisfy the appropriate boundary conditions. By adopting a new three dimensional finite difference modelling including elimination of pivotal difference points in the case of free boundary condition, the three dimensional problem of anisotropic body was successfully completed. Several numerical results show quick convergence and numerical validity of finite difference technique in three dimensional problem.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.6
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• pp.3827-3831
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• 2014

This paper aims to solve the problem deterioration of power fuses. The deterioration of a power fuse is a cause of failure misoperation by a normal current flowing reduplicatively to fuse the element. An extension survey of a load feature rerating power fuse examined the power fuse deterioration removal, the cause of the deterioration of the power fuse, the front-after, and the thermal variation of the inside transformer room electric power equipment. The transformer showed an average improvement of $6[^{\circ}C]$. The temperature of the electrical line showed $7{\sim}8[^{\circ}C]$ improvement. The static condenser and direct reactor was $2{\sim}3[^{\circ}C]$ high-state maintenance the temperature and equipment syntonization relationship. In the subject of study $0.5{\sim}1.0[^{\circ}C]$ stabilizing three phase power fuse temperature differential was. Suggestion in the transformer room environment power equipment between the cause temperature happen elimination to deterioration of power fuse and temperature rise control.

• Journal of Internet of Things and Convergence
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• v.5 no.2
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• pp.73-79
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• 2019

Research is underway on services and systems that provide real-time alerts for suffocating gases and potentially explosive materials, but currently smart bend type services are lacking. This study supports real-time identification of explosion hazards due to static electricity in the workplace and immediate elimination of accident occurrence factors, real-time monitoring of worker status and workplace hazards (oxygen, hazardous chemical concentration), and immediate warning and data in case of danger. We propose a method of establishing an accident prevention system through analysis. In this way, various accidents that may occur in industrial sites are monitored using IoT-based intelligent sensor nodes, wireless network technology, data processing middleware, and integrated control system, and real-time risk information at the industrial sites is prevented and accidents are prevented. By supporting a safe working environment, the company can significantly reduce costs compared to post-procurement costs.

• Journal of Power Electronics
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• v.16 no.3
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• pp.1110-1121
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• 2016

The mathematical model of a three phase PWM converter under the stationary αβ reference frame is deduced and constructed based on a Proportional-Resonant (PR) regulator, which can replace trigonometric function calculation, Park transformation, real-time detection of a Phase Locked Loop and feed-forward decoupling with the proposed accurate calculation of the inductance voltage vector. To avoid the parallel resonance of the LCL topology, the active damping method of the proportional capacitor-current feedback is employed. As to current vector error elimination, an optimized PR controller of the inner current loop is proposed with the zero-pole matching (ZPM) and cancellation method to configure the regulator. The impacts on system's characteristics and stability margin caused by the PR controller and control parameter variations in the inner-current loop are analyzed, and the correlations among active damping feedback coefficient, sampling and transport delay, and system robustness have been established. An equivalent model of the inner current loop is studied via the pole-zero locus along with the pole placement method and frequency response characteristics. Then, the parameter values of the control system are chosen according to their decisive roles and performance indicators. Finally, simulation and experimental results obtained while adopting the proposed method illustrated its feasibility and effectiveness, and the inner current loop achieved zero static error tracking with a good dynamic response and steady-state performance.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.19 no.6
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• pp.1515-1524
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• 2015

Recently, for the purpose of preventing the corrosion of a vessel, the electrical corrosion protection device that prevents the corrosions of the hull and the propeller is widely used. However, the electrical corrosion protection method artificially emits the current into the seawater around the hull using the power supply in order to make the hull and propeller be in the state of not being corrosion, so that electromagnetic field is generated outside the hull by the current emitted into the seawater. In this paper, the static and alternating constituents of the electromagnetic field generated in underwater outside the hull are analyzed and a countermeasure is investigated to reduce the strength of the electromagnetic field. In conventional shaft grounding system, the shaft potential is maintained above at least 100mV and the alternating current component constitutes more than 10% of the total current. However, in this paper, a control system was designed in order that the alternating current component and the shaft potential which generate electromagnetic field are maintained within 1% and 2mV respectively, and the performance was verified by simulation.

• The Korean Journal of Pesticide Science
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• v.11 no.4
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• pp.217-221
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• 2007

In order to elucidate the behavior of the fungicide hexaconazole (1-(6-chloro-3-pyrldyhnethyl)N-nitroimidazolidin-2-ylideneamine) in carp (Cyprinus carpio L.), carps were exposed to [$^{14}C$]hexaconazole at a predicted environmental concentration (PEC) of 0.32 mg $L^{-1}$ for 4 days under static conditions. Hexaconazole in water was absorbed into carps to reach the maximum concentration 2 days after exposure. The amounts of the [$^{14}C$]hexaconazole and its metabolites absorbed in gall were much higher than those in the other organs and especially those in gall 2 days after exposure were 25 and 67 times higher than those in liver and kidney, respectively, strongly suggesting that biliary excretion involving enterohepatic recirculation could be an import route for the elimination of hexaconazole absorbed in carps.