• Title/Summary/Keyword: starches

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Structural Characteristics of Kidney Bean Starch (강낭콩 전분의 분자구조적 특성)

  • Kim, Kwan;Kang, Kil-Jin;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.28 no.3
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    • pp.521-527
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    • 1996
  • Some structural characteristics of kidney bean starches (3 varieties : Pink kidney bean, Red kidney bean and White kidney bean) were investigated. The amylose content and the ${\beta}$-amylolysis limit of kidney bean starches were $32.6{\sim}34.5%$ and $69.9{\sim}71.0%$, respectively. The kidney bean amylopectin was composed of super long chain of ${\overline{DP}}$ above 60 ($5.28{\sim}12.62%$), B chain of ${\overline{DP}}$ $45{\sim}60\;(29.85{\sim}33.65%)$ and A chain of ${\overline{DP}}\;10{\sim}20(22.94{\sim}29.85%).$ The chain distribution of kidney bean starches were different from variety to variety. The acid (2.2 NHCI) hydrolysis of kidney bean starches showed, as hydrolysis time increased, the patterns of three stages. The acid hydrolysis rate and iodine reaction of acid treated starches were different from variety to variety As acid hydrolysis time increased, the amylose and the ${\alpha}$-1.6-glucosidic linkage of amylopectin of amorphous state were gradually hydrolyzed. Finally, the chain of ${\overline{DP}}$ 20 of crystalline state was left in the acid treated starches.

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Influence of Crosslinking on Gelatinization Behavior and Morphological Change of Potato Starch (가교결합 감자 전분의 호화특성과 형태학적 변화)

  • Kim, Hyang-Sook;Lee, Young-Eun
    • Korean Journal of Food Science and Technology
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    • v.28 no.3
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    • pp.580-586
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    • 1996
  • Gelatinization behavior and morphology of epichlorohydrin-crosslinked potato starches (XPs) were investigated. Native potato starch showed a very steep single stage swlling pattern, but crosslinked starches showed various patterns with the degree of crosslinking. Swelling power, solubility and light transmittance were reduced drastically as the degree of crosslinking increased. Brabender initial pasting temperature and peak temperature of crosslinked starches increased because the crosslinking reinforces the intermolecular net work of the starches. Although the swelling of the potato starch granule was inhibited by crosslinking as compared to that of the native one, Brabender peak viscosities (6.5% w/v, db) were on the order of 2,500 units for the native potato starch, 3,700 for the XP with 2.300 anhydroglucose units per crosslinking (AGU/CL) and 3,400 for the XP with 2,100 AGU/CL, due to the decreased breakdown of the swollen granule resulting from the resistance to heat and shear. The XP with 1,900 AGU/CL, however, did not show the peak viscosity and the viscosity was on the order of 500 units because of the excessive unhibition of the swelling. Unlike the native potato starch, 6.5%(m/v, db) pastes of the crosslinked potato starches could form gels, which could be predicted from the Brabender setback and consistency index. When the degree of crosslinking is low, random contraction and radial swelling of the granule was possible. As the degree of crosslinking increased, morphological change became similar to the single dimensional tangential swelling observed from the lenticular wheat starch. These morphological change during heating in excess water explained the gelatinization behaviors of crosslinked starches tested.

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Properties of Hot-water Extracts and Extract-gels of Starches for Mook (묵제조용 전분에서 분리한 열수추출물의 이화학적성질과 추출물겔의 특성)

  • Song, Young-Me;Chung, Koo-Min;Lee, Won-Jong
    • Korean Journal of Food Science and Technology
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    • v.27 no.4
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    • pp.625-630
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    • 1995
  • In order to know the effects of hot-water extracts of starches on gel formation and gel properties, some physicochemical properties and molecular distribution of the extracts were measured. Also, after acid-hydrolysis of starch gels and extract gels, extent of hydrolysis and $\overline{D.P}._n$, and molecular distribution of hydrolysis-residue were measured. Extraction ratio of grain starches (buckwheat, corn, rice, and wheat) were $4.0{\sim}6.6%$. The ratio of acorn and mungbean starches were 11.7 and 13.5%, respectively. Iodine affinity of the extracts was $17.2{\sim}17.7%$ in starches using for Mook, SM(acorn, buckwheat, and mungbean), $13.7{\sim}14.9%$ in starches not using for Mook, SNM(corn, rice, and wheat). Blue value was also higher in SM than in SNM. $\overline{D.P}._n$. of extracts of SM were bigger than those of SNM. In molecular distribution experiment, amylopectin fraction was not found from the extracts except rice starch extract. The extent of acid hydrolysis of the starch gels were $70{\sim}84%$ after 60 days, and the extent of the extract gels were $22{\sim}35%$. The extent of hydrolysis of starch gels and extract gels made with SM were lower than those of SNM.

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Characteristics of Defatted and Lipid-reintroduced Sweet Potato Starches (탈지와 지방질 첨가에 따른 고구마 전분의 특성)

  • Lee, Shin-Kyung;Shin, Mal-Shick
    • Korean Journal of Food Science and Technology
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    • v.23 no.3
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    • pp.341-348
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    • 1991
  • Physicochemical properties and gelatinization patterns of defatted and lipid-reintroduced moist (Hwangmi) and dry (Suwon 147) type sweet potato starches were investigated. Starch granules of sweet potato were polygonal and round, and the sizes of starch granules ranged $5{\sim}13\;{\mu}m$. All starches showed Ca type in X-ray diffraction but relative crystallinity was decreased by defatting and reintroduction. The amylose content of defatted starches increased, but that of lipid-reintroduced starches decreased. The swelling power and solubility at each temperature increased by defatting, but decreased by reintroduction. Transmittance of Hwangmi and Suwon 147 showed a rapid increase at $60,\;65^{\circ}C$, respectively. The initial pasting temperature by amylograph of Hwangmi and Suwon 147 were $67.5^{\circ}C\;and\;72.7^{\circ}C$, respectively. The peak viscosity and the height at $50^{\circ}C$ on amylogram of Hwangmi were lower than those of Suwon 147. Hot paste viscosity and setback decreased by defatting but setbak and consistency drastically increased by reintroduction. The peak temperature for gelatinization by the DSC was $65.7^{\circ}C$ for Hwangmi and $68.5^{\circ}C$ for Suwon 147. The gelatinization temperature and enthalpy of the DSC decreased and amylose-lipid melting peak was lost by defatting. The gelatinization temperature and enthalpy decreased by reintroduction.

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Physicochemical and pasting properties of rice starches from soft rice varieties developed by endosperm mutation breeding (배유 돌연변이처리로 개발된 연질미 전분의 이화학적 특성)

  • Kim, Jae Suk;No, Junhee;Shin, Malshick
    • Korean Journal of Food Science and Technology
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    • v.51 no.2
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    • pp.109-113
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    • 2019
  • The soft rice varieties, Hangaru and Singil, were developed via mutation breeding using N-methyl-N-nitrosourea treatment to obtain dry-milled rice flours. The physicochemical, morphological, and pasting properties of these starches were compared with those of Seolgaeng and Chuchung starches. Singil starch was found to exhibit the highest amylose content and initial pasting temperature, whereas Hangaru starch exhibited the highest water binding capacity and swelling power. Hangaru starch's granule size at $d_{50}$ was the largest among the four different starch types. Some Seolgaeng, Hangaru, and Singil granules were observed to have a round-faced polygon shape. Furthermore, the crystallinity of all four starch types was type A. The peak, trough, and final viscosities of the soft rice starches were also lower than those of normal starches. Notably, Hangaru starch showed the highest breakdown viscosity, but the lowest total setback viscosity among the four starches. From these results, the starch characteristics of the soft rice flours were discovered to be different based on the rice variety.

Physicochemical Properties of Starch Affected by Molecular Composition and Structures: A Review

  • Srichuwong, Sathaporn;Jane, Jay-Iin
    • Food Science and Biotechnology
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    • v.16 no.5
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    • pp.663-674
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    • 2007
  • Starches from different botanical sources differ in the ratio of amylose to amylopectin contents, molecular structures of amylose and amylopectin, granule morphology, and minor-component contents. These structural features result in different gelatinization, pasting, retrogradation properties, and enzyme digestibility of starch granules. In this review, compositions and molecular structures of starches and their effects on the physicochemical properties are summarized and discussed.

Alkali Gelatinization of Rice, Corn, Arrow Root and Ginger Root Starches (쌀, 옥수수, 칡 및 생강 전분의 알카리 호화)

  • Kim, Sung-Kon;Chung, Hye-Min;Cho, Man-Hee
    • Applied Biological Chemistry
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    • v.27 no.3
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    • pp.214-216
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    • 1984
  • Alkali gelatinization of rice, corn, arrow root and ginger root starches at various sodium hydroxide concentrations was investigated. Critical concentrations of alkali for starch gelatinization ranged from 2.33 to 3.17 meq NaOH per gram of starch. Ginger root starch was most resistant to alkali gelatinization and arrow root starch was least stable to alkali.

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Effect of annealing treatment on gelatinization of upland and lowland waxy brown rice starches (아닐링 처리가 밭벼와 논벼 찹쌀 전분의 호화에 미치는 영향)

  • Kim, Sung-Kon
    • Applied Biological Chemistry
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    • v.34 no.2
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    • pp.187-189
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    • 1991
  • Gelatinization temperatures of upland and lowland waxy brown rice starches annealed at $25^{\circ}C$ and $60^{\circ}C$ for 24hr were investigated with differential scanning calorimetry No annealing effect was observed at low temperature. The upland rice starch showed narrower range of gelatinization temperature upon annealing treatment at $60\circ}C$ compared with the lowland rice starch. The enthalpy of gelatinization was not changed in case of the upland rice starch but was increased in case of the lowland one upon annealing.

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Gelatinization properties of heat-moisture treated waxy rice starches (수분-열처리한 찹쌀 전분의 호화 성질)

  • Chang, Myung-Sook;Kim, Sung-Kon
    • Applied Biological Chemistry
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    • v.33 no.3
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    • pp.223-230
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    • 1990
  • Gelatinization properties of heat-moisture treated Olchal(japonica) and Hankangchalbyeo(j x indica) waxy rice starches were compared. The blue value, light transmittance of starch suspension and viscosity in sodium hydroxide solution were similar between two starches. Olchal starch showed lower water binding capacity, swelling power md peak viscosity by amylograph than Hankangchalbyeo starch. Upon heat-moisture treatments all above parameters were decreased. The critical sodium hydroxide concentration for gelatinization was increased by treatments. The initial pasting temperature of Olchal starch was higher than that of Hankarlgchalbyeo. All amylograph reference points increased by the treatments, except the maximum viscosity or 2l% moisture-treated Olchal starch. Starches treated at 18% moisture level showd the highest value of consistency index. The activation energy of consistency index for gelatinized Olchal starch was lower than that for Hankangchalbyeo starch. The heat-moisture treatments had no effect on activation energy.

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Effects of RS-3 type resistant starches on breadmaking and quality of white pan bread (RS-3형태의 저항전분 첨가가 제빵 및 빵의 품질에 미치는 영향)

  • 송지영;이신경;신말식
    • Korean journal of food and cookery science
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    • v.16 no.2
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    • pp.188-194
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    • 2000
  • Effects of native and RS-3 type resistant starches prepared from autoclaved-cooled amylomaize VII(AVII) and normal maize starches(NMS) on the rheological and baking properties of wheat flour dough and quality of breads were investigated. In farinogram, water absorption and dough development time were increased, but stability was reduced by the addition of RS. The addition of native starches or resistant starch made from AVII to wheat flour improved the total volume and specific loaf volume of bread compared with the control(no addition), but the addition of NMS-RS reduced those. During the storage of bread at room temperature, the moisture content of control was decreased but those of native starch- or RS-added breads remained constantly. AVII-RS- or NMS-RS-added bread was evaluated to have good overall acceptability compared with control by elementary school students. The addition of enzyme-resistant starch to bread regardless of botanical sources of starch not only improved the overall acceptability and nutritional benefits but also improved the sensory acceptability.

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