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A Study of Polychlorinated dibenzo-p-dioxins(PCDDs) and Polychlorinated dibenzofurans(PCDFs) Formation from Phenols in Thermal Process[I] (열공정에서 페놀류로부터 Polychlorinated dibenzo-p-dioxins(PCDDs)과 Polychlorinated dibenzofurans(PCDFs)의 생성에 관한 연구[I])

  • Ryu, Jae-Yong;Suh, Jeong-Min;Park, Jeong-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.5
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    • pp.511-521
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    • 2006
  • Homologue and isomer patterns of polychlorinated dibenzo-p-dioxins(PCDDs) and polychlorinated dibenzofurans(PCDFs) congeners formed from phenols in the gas-phase at $600{\sim}700^{\circ}C$ and via particle-mediated reactions at $400^{\circ}C$ were studied in an isothermal flow reactor. A mixture of 20 phenols in relative concentrations found in a municipal waste incinerator(MWI) stack gas was used for this study. PCDDs and PCDFs homologue and isomer patterns obtained from the phenol. From the phenol experiments, gas-phase formation at $600{\sim}700^{\circ}C$ favors PCDFs formation whereas particle-mediated formation at $400^{\circ}C$ favors PCDDs formation. DD and DF were most abundant homologue groups, PCDDs and PCDFs homologue fraction decreased with increasing number of chlorine substituents. PCDDs and PCDFs homologue and isomer fractions were almost constant from gas-phase formation and particle-mediated formation. Unsubstituted phenol, which was present in high concentration, played a significant role in the formation of PCDD/Fs congeners under both sets of experimental conditions.

Levels of Persistent Organic Pollutants in Waste Paper and Waste Lumber and Evaluation of their Sources (폐지와 폐목재에서의 잔류성 유기오염물질의 농도 및 배출원 추정)

  • Hwang, In-Kyu;Lee, In-Seok;Oh, Kwang-Joong;Kim, Ji-Won;Park, Hung-Suck;Oh, Jeong-Eun
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.9
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    • pp.870-878
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    • 2010
  • We investigated the concentration and the sources of ubiquitous persistent organic pollutants [i.e., 17 toxic polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), 12 coplanar polychlorinated biphenyls (Co-PCBs), and 16 priority polycyclic aromatic hydrocarbons (PAHs)] in waste papers and lumbers from industrial complexes. The total concentrations in waste papers and lumbers ranged from 9.69~176.77 pg/g-dry and 0.14~0.25 pg/g-dry for 17 PCDD/Fs, 109.95~4097.25 pg/g-dry and 28.23~59.88 pg/g-dry for 12 Co-PCBs and 9.30~52.18 ng/g-dry and 0.82~1.82 ng/g-dry for 16 PAHs respectively. Generally, the concentration of these pollutants in waste papers was higher than those in waste lumbers. OCDD was dominant in waste papers and lumbers and the PCDD/F patterns of these samples were similar with that of stack gas. The distribution patterns of Co-PCBs in wastes were related with commercial PCB products, indicating the effect of commercial PCB products on ubiquitous environment. The diagnostic ratios of several PAH compounds in waste paper showed that they were related with pyrogenic sources.

Optimal Rejection of Sea Bottom, Peg-leg and Free-surface Multiples for Multichannel Seismic Data on South-eastern Sea, Korea (동해 남동해역 다중채널 해양탄성파 탐사자료의 해저면, 페그-레그 및 자유해수면 다중반사파 제거 최적화 전산처리)

  • Cheong, Snons;Koo, Nam-Hyung;Kim, Won-Sik;Lee, Ho-Young;Shin, Won-Chul;Park, Keun-Pil;Kim, Jin-Ho
    • Geophysics and Geophysical Exploration
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    • v.12 no.4
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    • pp.289-298
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    • 2009
  • Optimal data processing parameters were designed to attenuate multiples in seismic data acquired in the south-eastern area of the East Sea, in 2008. Bunch of multiples caused by shallow sea water depth were perceived periodically up to two way travel time of 1,750 ms at every 250 ms over seismic traces. We abbreviated sea bottom multiple as SBM, Peg-leg multiple as PLM, and free-surface multiple as FSM. To attenuate these multiples, seismic data processing flow was constructed including NMO, stack, minimum phase predictive deconvolution filter and wave equation multiple rejections (WEMR). Prevalent multiples were suppressed by predictive deconvolution and remaining multiples were attenuated by WEMR. We concluded that combining deconvolution with WEMR was effective to a seismic data of study area. Derived parameter can be applied to the seismic data processing on adjacent survey area.

Development of a Prestack Generalized-Screen Migration Module for Vertical Transversely Isotropic Media (횡적등방성 매질에 적용 가능한 겹쌓기 전 Generalized-Screen 참반사 보정 모듈 개발)

  • Shin, Sungil;Byun, Joongmoo
    • Geophysics and Geophysical Exploration
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    • v.16 no.2
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    • pp.71-78
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    • 2013
  • The one-way wave equation migration is much more computationally efficient comparing with reverse time migration and it can provide better image than the migration algorithm based on the ray theory. We have developed the prestack depth migration module adopting (GS) propagator designed for vertical transverse isotropic media. Since GS propagator considers the higher-order term by expanding the Taylor series of the vertical slowness in the thin slab of the phase-screen propagator, the GS migration can offer more correct image for the complex subsurface with large lateral velocity variation or steep dip. To verify the validity of the developed GS migration module, we analyzed the accuracy with the order of the GS propagator for VTI media (GSVTI propagator) and confirmed that the accuracy of the wavefield propagation with the wide angles increases as the order of the GS propagator increases. Using the synthetic seismic data, we compared the migration results obtained from the isotropic GS migration module with the anisotropic GS migration module. The results show that the anisotropic GS migration provides better images and the improvement is more evident on steeply dipping structures and in a strongly anisotropic medium.

A Micro Fluxgate Magnetic Sensor with Closed Magnetic Path (폐자로를 형성한 마이크로 플럭스게이트 자기 센서)

  • 최원열;황준식;강명삼;최상언
    • Journal of the Microelectronics and Packaging Society
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    • v.9 no.3
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    • pp.19-23
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    • 2002
  • This paper presents a micro fluxgate magnetic sensor in printed circuit board (PCB). In order to observe the effect of the closed magnetic path, the magnetic cores of rectangular-ring and two bars were each fabricated. Each fluxgate sensor consists of five PCB stack layers including one layer magnetic core and four layers of excitation and pick-up coils. The center layer as a magnetic core is made of a Co-based amorphous magnetic ribbon with extremely high DC permeability of ~100,000. Four outer layers as an excitation and pick-up coils have a planar solenoid and are made of copper foil. In case of the fluxgate sensor having the rectangular-ring shaped core, excellent linear response over the range of -100 $\mu$T to + 100 $\mu$T is obtained with 540 V/Tsensitivity at excitation square wave of 3 $V_{p-p}$ and 360 KHz. The chip size of the fabricated sensing element is $7.3 \times 5.7\textrm{mm}^2$. The very low power consumption of ~8 mW was measured. This magnetic sensor is very useful for various applications such as: portable navigation systems, telematics, VR game and so on.n.

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A CFD Study on Unsteady and Steady State of the Hydrogen Leakage for Residential Fuel Cell System (가정용 연료전지 시스템 내부 수소 누출의 비정상 및 정상 상태에 관한 전산 해석)

  • Chung, Tae-Yong;Ahn, Jae-Uk;Nam, Jin-Hyun;Shin, Dong-Hoon;Kim, Young-Gyu
    • Journal of the Korean Institute of Gas
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    • v.11 no.4
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    • pp.41-46
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    • 2007
  • The residential fuel cell system was modeled as a box-shaped chamber with vent openings, filled with various components such as reformer, desulfurizer, fuel cell stack and humidifier. When the vent openings are 1% of the total surface and hydrogen leakage 1%, hydrogen concentration is around 0.1% higher than the other regions from leak points in the chamber at 30 seconds and hydrogen concentration is increased from 0.3% to 0.7% in the upper region of the system after 200 seconds. When the vent openings are 1% of the total surface and hydrogen leakage 1%, 3%, 5%, the steady state result of CFD, 5% of hydrogen leakage is reached the lowest ignition limit in the system. When the vent openings are 2% of the total surface and hydrogen leakage 1%, hydrogen concentration is increased in the bottom of the system for 60 seconds. After 250 seconds, hydrogen concentration is reached the steady state in the system. As the vent opening of the total surface increased from 1% to 2%, averaged hydrogen mole fraction is under 1% in the system, however, upper regions of the system from the hydrogen leakage points are shown over 1% of hydrogen mole fraction.

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Simulation and Control of the Molten Carbonate System using Aspen $Dynamics^{TM}$ and ACM (Aspen $Dynamics^{TM}$와 ACM을 이용한 용융탄산염 연료전지 시스템의 모사 및 제어)

  • Jeon, Kyoung Yein;Kwak, Ha Yeon;Kyung, Ji Hyun;Yoo, Ahrim;Lee, Tae Won;Lee, Gi Pung;Moon, Kil Ho;Yang, Dae Ryook
    • Korean Chemical Engineering Research
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    • v.49 no.4
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    • pp.423-431
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    • 2011
  • Recentincreasing awareness of the environmental damage caused by the $CO_2$ emission of fossil fuelsstimulated the interest in alternative and renewable sources of energy. Fuel cell is a representative example of hydrogen energy utilization. In this study, Molten Carbonate Fuel Cell system is simulated by using $Aspen^{TM}$. Stack model is consisted of equilibrium reaction equations using $ACM^{TM}$(Aspen Custom Modeler). Balance of process of fuel cell system is developed in Aspen $Plus^{TM}$ and simulated at steady-state. Analysis of performance of the system is carried out by using sensitivity analysis tool with main operating parameters such as current density, S/C ratio, and fuel utilization and recycle ratio.In Aspen $Dynamics^{TM}$, dynamics of MCFC system is simulated with PID control loops. From the simulation, we proposed operation range which generated maximum power and efficiency in MCFC power plant.

The Estimation of Emission Factor of N2O and CH4 by Measurement from Stacks in the Waste Incinerators and Cement Production Plants

  • Choi, Sang-Min;Im, Jong-Kwon;Hong, Ji-Hyoung;Lee, Sue-Been;Zoh, Kyung-Duk
    • Journal of Environmental Health Sciences
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    • v.33 no.3
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    • pp.217-226
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    • 2007
  • The purpose of this study is to estimate the emission factor of $non-CO_2$ global warming gases such as $N_2O$ and $CH_4$ by measuring concentrations from stacks of waste incinerators and cement production plants. Based on the established monitoring methods, $N_2O$ concentration measured from stacks in incinerator were between 0.62 and $40.60\;ppm_v$ (ave. $11.50\;ppm_v$). The concentration of $N_2O$ was dependent on the incinerator types. However, the concentrations of $CH_4$ gas were between 2.65 and $5.68\;ppm_v$ (ave. $4.22\;ppm_v$), and did not show the dependency on the incinerator types. In the cement production plant, the concentration ranges of $N_2O$ from the stack were from 6.90 to $10.80\;ppm_v$ (ave. $8.60\;ppm_v$), and $CH_4$ were between 1.80 and $2.20\;ppm_v$ (ave. $2.60\;ppm_v$). Using measured concentrations, the emission amounts of $N_2O$ and $CH_4$ from stacks per year were calculated. The results were is 4.2 ton $N_2O/yr$ in the incinerators, and 53.7 ton $N_2O/yr$ in the cement facilities. The big difference is from the flow rate of flue gas in the cement facilities compared to the incinerators. By the same reason, the $CH_4$ emission amounts in cement plant and incinerator was found to be 339 ton $CO_2/yr$ and 34.1 ton $CO_2/yr$, respectively. Finally, the emission factor of $N_2O$ in the incinerators were calculated using the measured concentration and the amount of incinerated wastes, and was $42.5\sim799.1\;g/ton$ in kiln and stoker type, $11.9\sim79.9\;g/ton$ in stoker type, 90.1 ton/g in rotary kiln type, 174.9 g/ton in fluidized bed type, and 63.8 g/ton in grate type, respectively. Also, the emission factors of $CH_4$ were found to 65.2-91.3 g/ton in kiln/stoker type, 73.9-122 g/ton in stoker type, 109.5 g/ton rotary kiln, and 26.1 g/ton in fluidized bed type. This result indicates that the emission factor in incinerators is strongly dependent on the incinerator types, and matched with result of IPCC (International Panel on Climate Change) guideline.

A study on Monitoring the Inner Structure of Dam Body Using High Resolution Seismic Reflection Method (고분해능 탄성파 반사법을 이용한 댐체 내부구조 모니터링 연구)

  • Kim, Jung-Yul;Kim, Hyoung-Soo;Oh, Seok-Hoon;Kim, Yoo-Sung
    • Journal of the Korean Geophysical Society
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    • v.8 no.1
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    • pp.1-6
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    • 2005
  • Defects of dam body which can be induced in seepage or leakage procedure can directly affect dam safety. Therefore, a proper inspection method should be carried out in the first place to find out their positions and sizes. After that, some reinforcement works such as grouting and the corresponding assessment could be taken in a proper way. The dam(center core type earth dam) issued in this study has been in need for intensive diagnosis and reinforcement work, because a lot of slumps similar to cracks, seepage and some boggy area have been observed on the downstream slope. High resolution seismic reflection method was performed on the crest profile twice before and after grouting work(Aug. 2001 and Nov. 2004) aimed at the dam inspection and the assessment of grouting efficiency as well. To enhance the data resolution, P-beam energy radiation technique which can reduce the surface waves and hence to reinforce the reflection events was used. Strong reflection events were recognized in the stack section before grouting work, It seems that the events would be caused by e.g. horizontal cracks with a considerable aperture. Meanwhile such strong reflection events were not observed in the section after grouting. That is, the grouting work was dear able to reinforce the defects of dam body. Hence, the section showed an well arranged picture of dam inner structure. In this sense, seismic reflection method will be a desirable technique for dam inspection and for monitoring dam inner structure as well.

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The Sub-Peres Functions for Random Number Generation (무작위수생성을 위한 부 페레즈 함수)

  • Pae, Sung-Il
    • Journal of the Korea Society of Computer and Information
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    • v.18 no.2
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    • pp.19-30
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    • 2013
  • We study sub-Peres functions that are defined recursively as Peres function for random number generation. Instead of using two parameter functions as in Peres function, the sub-Peres functions uses only one parameter function. Naturally, these functions produce less random bits, hence are not asymptotically optimal. However, the sub-Peres functions runs in linear time, i.e., in O(n) time rather than O(n logn) as in Peres's case. Moreover, the implementation is even simpler than Peres function not only because they use only one parameter function but because they are tail recursive, hence run in a simple iterative manner rather than by a recursion, eliminating the usage of stack and thus further reducing the memory requirement of Peres's method. And yet, the output rate of the sub-Peres function is more than twice as much as that of von Neumann's method which is widely known linear-time method. So, these methods can be used, instead of von Neumann's method, in an environment with limited computational resources like mobile devices. We report the analyses of the sub-Peres functions regarding their running time and the exact output rates in comparison with Peres function and other known methods for random number generation. Also, we discuss how these sub-Peres function can be implemented.